ISSN 1000-3304CN 11-1857/O6

聚合原位合成含螺吡喃组装体及其光响应研究

叶齐全 郑明心 陈曦 李丹 田卫国 张军 袁金颖

引用本文: 叶齐全, 郑明心, 陈曦, 李丹, 田卫国, 张军, 袁金颖. 聚合原位合成含螺吡喃组装体及其光响应研究[J]. 高分子学报, 2019, 50(4): 344-351. doi: 10.11777/j.issn1000-3304.2018.18256 shu
Citation1:  Qi-quan Ye, Ming-xin Zheng, Xi Chen, Dan Li, Wei-guo Tian, Jun Zhang and Jin-ying Yuan. Photo-responsive Spiropyrane-containing Block Copolymer Assemblies Prepared by Polymerization-induced Self-assembly[J]. Acta Polymerica Sinica, 2019, 50(4): 344-351. doi: 10.11777/j.issn1000-3304.2018.18256 shu

聚合原位合成含螺吡喃组装体及其光响应研究

    通讯作者: 袁金颖, E-mail: yuanjy@mail.tsinghua.edu.cn
  • 基金项目: 国家自然科学基金(基金号 21871162,51573086)资助项目

摘要: 具有光响应性的采用乙醇相分散共聚的方法将螺吡喃基团引入聚合原位自组装体系,合成了具有光响应性的聚甲基丙烯酸N,N-二甲基氨基乙酯-b-聚(甲基丙烯酸苄酯-co-甲基丙烯酸螺吡喃酯)(PDMA-b-P(BzMA-co-SPMA))共聚物组装体. 通过调节BzMA、SPMA和PDMA的投料比,制备了球形胶束、蠕虫状胶束、“章鱼”状组装体、囊泡、实心粒子等不同形貌的组装体. 所得组装体分散液具备良好的紫外响应显色性:在交替的UV(紫外)/可见光照射下,组装体分散液发生无色-蓝色的可逆转变. 使用光响应组装体墨水绘制的文字和图案可以实现在UV/可见光照射(或升温)下的可逆显示与隐藏. 这种方法可拓展应用于文字和图案的打印,实现精细图案的大批量快速制备. 二维光响应图案具备良好的稳定性,且光响应过程具备良好的可循环性.

English

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  • Figure 1.  Preparation and isomerization of photo-responsive copolymers

    Figure 2.  1H-NMR spectra of (a) PDMA32 and (b) PDMA32-b-P(BzMA40-co-SPMA6) (solvent: CDCl3)

    Figure 3.  TEM images of (a) D32-B40-S6, (b) D32-B34-S9, (c) D32-B24-S15, (d) D32-B272-S13, (e) D32-B173-S51, (f) D32-B157-S205 assemblies, and (g) DLS profiles of copolymers

    Figure 4.  Optical photos of D32-B40-S6 assemblies after (a) UV irradiation and (b) visible light irradiation for different time; UV-Vis spectra during (c) UV irradiation and (d) visible light irradiation

    Figure 5.  Optical photos of (a) characters and (b) the snowflake pattern before and after UV irradiation, using the D32-B162-S42 assembly dispersion as ink

    Figure 6.  Optical photos of Chinese characters “Gao Fen Zi” after selectivity UV irradiation at (a) “Gao” or (b) “Fen Zi”, separately; Optical photos of a scrap of A4 paper covered by D32-B162-S42 assembly dispersion as ink (c) before and (d) after soaked in water for 14 days

    Figure 7.  Optical photos of (a) the logo of Tsinghua university before and after UV irradiation and (b) the quick response code before and after UV irradiation, printed by epson L130 ink-jet printer

    Table 1.  Summary of feed ratios, DPs of monomers and ωSPMA of various diblock copolymer assemblies prepared by RAFT dispersion copolymerization in ethanol at 70 °C

    Feed aConversion (%)GPCDLSωSPMAd
    (wt%)
    BzMASPMABzMASPMAMn (g mol−1)Ð bDhc (nm) Dispersity
    D32-B40-S61501526.437.5124001.52370.14317
    D32-B34-S91503022.930.3146001.79900.18825
    D32-B24-S151506016.025.6152001.621730.17640
    D32-B272-S133001590.786.7415001.422650.18710
    D32-B173-S513006057.785.0401001.671740.31338
    D32-B157-S20530030052.368.3981001.811600.05372
    a FeedAIBN = 0.3, FeedPDMA = 1 and solids content = 20%; b Ð = Mw,GPC/Mn,GPC; c Dh means the average hydrodynamic diameter measured by DLS; d ωSPMA means the weight fraction (wt%) of PSPMA in copolymers.
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  • 通讯作者:  袁金颖, yuanjy@mail.tsinghua.edu.cn
  • 收稿日期:  2018-11-27
  • 修稿日期:  2019-01-16
  • 网络出版日期:  2019-02-25
  • 刊出日期:  2019-04-01
通讯作者: 陈斌, bchen63@163.com
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