
Citation: Jing Gao, Wei-qi Wang and Hai-jun Yu. A Simulation Study of Enhancing the Compatibility in Block Copolymer AB/Homopolymer C Blends by Solvents[J]. Acta Polymerica Sinica, 2019, (11): 1220-1228. doi: 10.11777/j.issn1000-3304.2019.19072

溶剂对嵌段共聚物AB/均聚物C共混体系增容效果的模拟研究
English
A Simulation Study of Enhancing the Compatibility in Block Copolymer AB/Homopolymer C Blends by Solvents
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Key words:
- Block copolymer /
- Homopolymer /
- Blend /
- Solvent /
- Compatibilization
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[1]
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Figure 1. Typical morphologies occurring in our simulations, color scheme in the snapshots: A (red), B (green) and C (blue). In the figure, L2: B-lamellae; L2C: B-cylinders, A-curved lamellae, B/C packed curved lamellae; G: B-similar gyroid in A/C mixed matrix; C1: B-cylinders in A-matrix, C-block at interface of the A/B; C2: B-cylinders in A/C mixed matrix; M: Macro phase separation between homopolymer and copolymer. (The online version is colorful.)
Figure 2. Phase diagrams in the concentration, Φ, and the volume fraction of homopolymer, fc, space for X = 1/6 in solutions with εAB =1.0, εBC = 0.2, εAC = 0.2, εAS = −1.0, εBS = −0.1, εCS = −1.0. The typical phases are shown in Fig. 1, where Φ = 1.0 refers to the melt state.
Figure 4. Phase diagrams in the fc and Φ space for symmetric diblock copolymer/homopolymer in solutions with εAB = 1.0, εBC = 0.2, εAC = 0.2, εAS = – 1.0, εBS = – 0.1, εCS = – 1.0. (a) X = 1/3, (b) X = 1/2, the typical phases are shown in Fig. 1.
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