Synthesis of Fluorine-substituted Poly(aryl ether ketone)s under Low Temperature and Its Structure

Da-lin Dong; Yue-zhen Bin; Xi-gao Jian

doi:10.11777/j.issn1000-3304.2021.21260

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Synthesis of Fluorine-substituted Poly(aryl ether ketone)s under Low Temperature and Its Structure

Research Article | 更新时间：2024-10-08

- Synthesis of Fluorine-substituted Poly(aryl ether ketone)s under Low Temperature and Its Structure
- ACTA POLYMERICA SINICA Vol. 53, Issue 3, Pages: 261-272(2022)
- 作者机构：
  
  1.大连理工大学高分子材料系
  2.辽宁省高性能树脂工程技术研究中心大连 116024
- 作者简介：
  
  Yue-zhen Bin, E-mail: binyz@dlut.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2021.21260
  CLC：
- Published：20 March 2022，
  
  Published Online：23 December 2021，
  
  Received：02 September 2021，
  
  Accepted：26 November 2021
- 稿件说明：
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董大林,宾月珍.氟取代聚芳醚酮低温合成及其结构研究[J].高分子学报,2022,53(03):261-272.

Dong Da-lin,Bin Yue-zhen.Synthesis of Fluorine-substituted Poly(aryl ether ketone)s under Low Temperature and Its Structure[J].ACTA POLYMERICA SINICA,2022,53(03):261-272.
董大林,宾月珍.氟取代聚芳醚酮低温合成及其结构研究[J].高分子学报,2022,53(03):261-272. DOI： 10.11777/j.issn1000-3304.2021.21260.

Dong Da-lin,Bin Yue-zhen.Synthesis of Fluorine-substituted Poly(aryl ether ketone)s under Low Temperature and Its Structure[J].ACTA POLYMERICA SINICA,2022,53(03):261-272. DOI： 10.11777/j.issn1000-3304.2021.21260.

摘要

通过傅克酰基化反应合成4

4'-二(4-氟苯甲酰基)二苯醚、4

4'-二(五氟苯甲酰基)二苯醚、4

4'-二(4-氟苯甲酰基)二苯硫醚以及4

4'-二(五氟苯甲酰基)二苯醚4种长链双卤单体，并进一步制备了含二氮杂萘酮聚芳醚酮聚合物. 通过多氟取代双卤单体在含二氮杂萘酮聚芳醚酮聚合物主链中引入氟原子. 多氟取代双卤单体具有多个反应位点，低温反应以及两步投料的聚合路线保证了溶液缩聚反应在多氟取代双卤单体的指定位点进行，保证了氟取代含二氮杂萘酮聚芳醚酮聚合物的线形结构并具有一定的分子量. 讨论了氟原子的引入对于含二氮杂萘酮聚芳醚酮聚合物合成路线、分子结构、数均分子量、热性能以及序列结构的影响.

Abstract

Poly(aryl ether ketone)s are high performance engineering plastics with excellent comprehensive performance. They are usually prepared by solution polycondensation at high temperature with bisphenol monomers and dihalogen monomer. Polycondensation at high temperature makes it difficult to prepare and raises production costs. As a result

preparation of poly(aryl ether ketone)s at low temperature is significant in scientific research and industrial production. On the other hand

introduction of fluorine atoms into poly(aryl ether ketone)s with phthalazinone can optimize comprehensive properties. Here

fluorine atoms are introduced in dihalogen monomers to prepare fluorine substituted poly(aryl ether ketone)s at low temperature. Long-chain dihalogenated monomers are obtained by Friedel-Crafts acylation reaction with pentafluorobenzoic acid instead of p-fluorobenzoic acid. Fluorine substituted long-chain dihalogenated monomers are used in preparation of poly(aryl ether ketone)s with phthalazinone at low temperature. Fluorine atoms were introduced into main chain of poly(aryl ether ketone)s containing phthalazinone. Polyfluorosubstituted dihalogenated monomers have multiple reaction sites. Low temperature reaction and two-step feeding polymerization route ensure that solution polycondensation reaction is carried out at certain position of polyfluorosubstituted dihalogenated monomers and that fluorine substituted poly(aryl ether ketone)s with phthalazinone are linear polymers. The introduction of fluorine atoms has an impact on synthetic route

molecular structure

number average molecular weight

thermal properties and sequence structure of poly(aryl ether ketone)s with phthalazinone. Two kinds of fluorine substituted poly(aryl ether ketone)s with phthalazinone synthesised with long-chain dihalogenated monomers are amorphous polymers. With the introduction of fluorine atoms

glass transition temperatures of the corresponding poly(aryl ether ketone)s with phthalazinone are improved; while number-average molecule weight and thermal decomposition temperature of fluorine substituted poly(aryl ether ketone)s with phthalazinone are reduced

due to the low-temperature reaction. Otherwise

fluorine substituted poly(aryl ether ketone)s with phthalazinone have potential for further post functionalization. It's expected that this study could provide reference for other researchers.

关键词

二氮杂萘酮聚芳醚酮氟取代序列结构

Keywords

PhthalazinonePoly(aryl ether ketone)Fluoro-substitutionSequence structure

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Related Institution

Key Laboratory of Low-carbon Chemistry & Energy Conservation of Guangdong Province, School of Materials Science and Engineering, Sun Yat-sen University

大连理工大学高分子材料系

辽宁省高性能树脂工程技术研究中心

Department of Polymer Science &amp&nbsp

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