Influence of Solvent Type on Acceleration of Phase Transition from Phase Ⅱ to Phase I of Polybutene-1 <italic style="font-style: italic">via</italic> Solvent Vapor Treatment

Ji-chao Jiang; Xin-yue Song; Yu-dong Mao; Guang-feng Wu; Ji-dong Zhang

doi:10.11777/j.issn1000-3304.2021.21267

您当前的位置：

首页 >

文章列表页 >

Influence of Solvent Type on Acceleration of Phase Transition from Phase Ⅱ to Phase I of Polybutene-1 via Solvent Vapor Treatment

Research Article | 更新时间：2024-10-08

- Influence of Solvent Type on Acceleration of Phase Transition from Phase Ⅱ to Phase I of Polybutene-1 via Solvent Vapor Treatment
- ACTA POLYMERICA SINICA Vol. 53, Issue 3, Pages: 254-260(2022)
- 作者机构：
  
  1.中国科学院长春应用化学研究所高分子物理与化学国家重点实验室长春 130022
  2.中国科学技术大学应用化学与工程学院合肥 230026
  3.长春工业大学化学与工程学院长春 130012
- 作者简介：
  
  Ji-dong Zhang, E-mail: jdzhang@ciac.ac.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2021.21267
  CLC：
- Published：20 March 2022，
  
  Published Online：23 December 2021，
  
  Received：10 September 2021，
  
  Revised：03 December 2021，
- 稿件说明：
移动端阅览
姜继超,宋新月,毛禹东等.溶剂性质对溶剂蒸气加速等规聚丁烯-1相转变的影响[J].高分子学报,2022,53(03):254-260.

Jiang Ji-chao,Song Xin-yue,Mao Yu-dong,et al.Influence of Solvent Type on Acceleration of Phase Transition from Phase Ⅱ to Phase I of Polybutene-1 via Solvent Vapor Treatment[J].ACTA POLYMERICA SINICA,2022,53(03):254-260.
姜继超,宋新月,毛禹东等.溶剂性质对溶剂蒸气加速等规聚丁烯-1相转变的影响[J].高分子学报,2022,53(03):254-260. DOI： 10.11777/j.issn1000-3304.2021.21267.

Jiang Ji-chao,Song Xin-yue,Mao Yu-dong,et al.Influence of Solvent Type on Acceleration of Phase Transition from Phase Ⅱ to Phase I of Polybutene-1 via Solvent Vapor Treatment[J].ACTA POLYMERICA SINICA,2022,53(03):254-260. DOI： 10.11777/j.issn1000-3304.2021.21267.

摘要

以50 ℃等温结晶后的等规聚丁烯-1 (PB-1)为研究对象，利用X射线衍射(XRD)和示差扫描量热技术(DSC)对不同溶剂蒸气处理的PB-1进行分析，并用原位XRD在线研究了溶剂熏蒸聚丁烯-1的 Ⅱ-Ⅰ 相转变过程. XRD与DSC结果表明除了水和醇类溶剂，其他大多数溶剂如正己烷、三氯甲烷、1

2-二氯乙烷、苯、甲苯、二甲苯、氯苯、乙酸乙酯、四氢呋喃、丙酮溶剂对Ⅱ-Ⅰ相转变过程均有明显的促进作用，可以使常规条件下4~5天的相转变加速到几十分钟. 通过原位XRD表征发现，溶剂熏蒸过程中聚丁烯-1的晶型转变过程为晶型Ⅱ消失的同时晶型I生成. 溶剂进入样品内部促进晶型转变主要分为两步：吸附和扩散. 吸附主要受溶解度参数和极性影响，水和乙醇等不良溶剂没有促进相变的效果；而扩散主要取决于溶剂分子的几何尺寸：单一方向的小尺寸更有利于进入样品内部，促进晶型转变. 通过这个研究我们认为正己烷或石油醚是加速PB-1的Ⅱ-I相转变的高效低毒溶剂，具有潜在的应用前景.

Abstract

A series of isotactic polybutene-1 (PB-1) in phase Ⅱ obtained

via

isothermal crystallization at 50 ℃ were treated with different solvent vapors. Wide-anlge X-ray diffraction (WAXD) and differential scanning calorimetry (DSC) techniques were used to evaluate such samples before and after treatment. Meanwhile

in situ

XRD was used to study the phase transition process of PB-1 annealed in different solvent vapors. Solvents

except water and alcohol solvents

such as

-hexane

chloroform

2-dichloroethane

benzene

toluene

xylene

chlorobenzene

ethyl acetate

tetrahydrofuran

acetone have obvious accelerating effect on the phase transition process

which can shorten the phase transition time from more than 4-5 days under normal conditions to tens of minutes. Through

in situ

XRD characterization

it was found that during the solvent annealing process

the crystal form Ⅱ of PB-1 disappeared while the crystal form I was formed. The entrance of solvents

which promotes the crystal form transformation

can be

divided into two steps: adsorption and diffusion. Adsorption is affected by solubility parameters and polarity

while diffusion mainly depended on the geometric size of solvent molecules: a small size in any direction will lead to a faster spread and larger promotion effect. Through this research

we found that

-hexane or petroleum ether is an efficient and low-toxic solvent that accelerates the Ⅱ-I phase transition of PB-1

and has good application prospects.

关键词

等规聚丁烯-1晶型转变溶剂蒸气退火X射线衍射

Keywords

Isotactic polybutene-1Crystal transformationSolvent vapor annealingX-ray diffraction

references

Luciani L, Seppala J, Lofgren B. Prog Polym Sci, 1988, 13: 37-62

Boor J, Youngman E A. J Polym Sci, Part B: Polym Lett, 1964, 2: 903-907. doi:10.1002/pol.1964.110020916http://dx.doi.org/10.1002/pol.1964.110020916

Miller R L, Holland V F. J Polym Sci, Part B: Polym Lett, 1964, 2: 519-521. doi:10.1002/pol.1964.110020509http://dx.doi.org/10.1002/pol.1964.110020509

Zhang G, Zhai X, Ma Z, Jin L, Zheng P, Wang W, Cheng S Z D, Lotz B. ACS Macro Lett, 2012, 1: 217-221. doi:10.1021/mz2001109http://dx.doi.org/10.1021/mz2001109

Azzurri F, Flores A, Alfonso G C, Calleja F J B. Macromolecules, 2002, 35: 9069-9073. doi:10.1021/ma021005ehttp://dx.doi.org/10.1021/ma021005e

Azzurri F, Flores A, Alfonso G C, Sics I, Hsiao B S, Calleja F J B. Polymer, 2003, 44: 1641-1645. doi:10.1016/s0032-3861(02)00864-9http://dx.doi.org/10.1016/s0032-3861(02)00864-9

Rubin I D. J Polym Sci, Part B: Polym Lett, 1964, 2: 747-749. doi:10.1002/pol.1964.110020717http://dx.doi.org/10.1002/pol.1964.110020717

Danusso F, Gianotti G. Makromolekul Chem, 1965, 88: 149-158. doi:10.1002/macp.1965.020880110http://dx.doi.org/10.1002/macp.1965.020880110

Boor J, Mitchell J C. J Polym Sci, 1962, 62: S70-S73. doi:10.1002/pol.1962.1206217427http://dx.doi.org/10.1002/pol.1962.1206217427

Powers J, Hoffman J D, Weeks J J, Quinn F A, Jr. J Res Natl Bur Stand A Phys Chem, 1965, 69A: 335-345. doi:10.6028/jres.069a.034http://dx.doi.org/10.6028/jres.069a.034

di Lorenzo M L, Androsch R, Righetti M C. Eur Polym J, 2015, 67: 264-273. doi:10.1016/j.eurpolymj.2015.04.002http://dx.doi.org/10.1016/j.eurpolymj.2015.04.002

Qiao Y, Wang Q, Men Y. Macromolecules, 2016, 49: 5126-5136. doi:10.1021/acs.macromol.6b00862http://dx.doi.org/10.1021/acs.macromol.6b00862

Cavallo D, Kanters M J W, Caelers H J M, Portale G, Govaert L E. Macromolecules, 2014, 47: 3033-3040. doi:10.1021/ma500281fhttp://dx.doi.org/10.1021/ma500281f

Chen W, Li X Y, Li H L, Su F M, Zhou W M, Li L B. J Mater Sci, 2013, 48: 4925-4933. doi:10.1007/s10853-013-7273-1http://dx.doi.org/10.1007/s10853-013-7273-1

Liu Y P, Cui K P, Tian N, Zhou W Q, Meng L P, Li L B, Ma Z, Wang X L. Macromolecules, 2012, 45: 2764-2772. doi:10.1021/ma2026513http://dx.doi.org/10.1021/ma2026513

Tanaka A, Sugimoto N, Asada T, Onogi S. Polym J, 1975, 7: 529-537. doi:10.1295/polymj.7.529http://dx.doi.org/10.1295/polymj.7.529

Nakafuku C, Miyaki T. Polymer, 1983, 24: 141-148. doi:10.1016/0032-3861(83)90124-6http://dx.doi.org/10.1016/0032-3861(83)90124-6

Li L, Liu T, Zhao L, Yuan W K. Macromolecules, 2009, 42: 2286-2290. doi:10.1021/ma8025496http://dx.doi.org/10.1021/ma8025496

Shi J Y, Wu P Y, Li L, Liu T, Zhao L. Polymer, 2009, 50: 5598-5604. doi:10.1016/j.polymer.2009.09.078http://dx.doi.org/10.1016/j.polymer.2009.09.078

Xu Y, Liu T, Li L, Li D C, Yuan W K, Zhao L. Polymer, 2012, 53: 6102-6111. doi:10.1016/j.polymer.2012.10.049http://dx.doi.org/10.1016/j.polymer.2012.10.049

Jones A T. J Polym Sci Pol Sym, 1967, 16: 393-404. doi:10.1002/polc.5070160136http://dx.doi.org/10.1002/polc.5070160136

Liao Y L, Liu L, Ma Z, Li Y S. Macromolecules, 2020, 53: 2088-2100. doi:10.1021/acs.macromol.0c00078http://dx.doi.org/10.1021/acs.macromol.0c00078

Qiu X, Azhar U, Li J Q, Huang D H, Jiang S C. Chinese J Polym Sci, 2019, 37: 633-636. doi:10.1007/s10118-019-2273-5http://dx.doi.org/10.1007/s10118-019-2273-5

Shao H F, Ma Y P, Nie H R, He A H. Chinese J Polym Sci, 2016, 34: 1141-1149. doi:10.1007/s10118-016-1823-3http://dx.doi.org/10.1007/s10118-016-1823-3

Qiu X, Hu C L, Li J Q, Huang D H, Jiang S C. CrysEngComm, 2019, 21: 4661. doi:10.1039/c9ce90116ghttp://dx.doi.org/10.1039/c9ce90116g

Views

105

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Study on the Interface Structure and Bond Properties Between Isotactic Polybutene-1 and Isotactic Polypropylene

Related Author

Xin-yue Song

Yu-dong Mao

Guang-feng Wu

Ji-dong Zhang

Ji-chao Jiang

Hua-rong Nie

Ai-hua He

Yong-jia Liu

Related Institution

University of Science and Technology of China

College of Chemical Engineering, Changchun University of Technology

School of Polymer Science and Engineering, Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization, Key Laboratory of Rubber-plastics of Ministry of Education, Qingdao University of Science and Technology

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰

Influence of Solvent Type on Acceleration of Phase Transition from Phase Ⅱ to Phase I of Polybutene-1 via Solvent Vapor Treatment

DOI：10.11777/j.issn1000-3304.2021.21267

摘要

Abstract

关键词

Keywords

references