Synthesis of Phospholipidated Starch and Its Application for Flame-retardant Poly(lactic acid) with Ammonium Polyphosphate

Jin-hao Sun; Jin-ping Ni; Dan Lu; Zhao-bin Tang

doi:10.11777/j.issn1000-3304.2021.21285

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Synthesis of Phospholipidated Starch and Its Application for Flame-retardant Poly(lactic acid) with Ammonium Polyphosphate

Research Article | 更新时间：2024-10-08

- Synthesis of Phospholipidated Starch and Its Application for Flame-retardant Poly(lactic acid) with Ammonium Polyphosphate
- ACTA POLYMERICA SINICA Vol. 53, Issue 3, Pages: 227-235(2022)
- 作者机构：
  
  1.中国科学院宁波材料技术与工程研究所生物基高分子材料与应用技术重点实验室宁波 315201
  2.浙江新力新材料股份有限公司温州 325000
- 作者简介：
  
  Dan Lu, E-mail: ludan09@126.com
  Zhao-bin Tang, E-mail: tangzhb04@nimte.ac.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2021.21285
  CLC：
- Published：20 March 2022，
  
  Published Online：23 December 2021，
  
  Received：24 September 2021，
  
  Revised：19 November 2021，
- 稿件说明：
移动端阅览
孙晋皓,倪金平,路丹等.磷化淀粉的合成及其与聚磷酸铵协效阻燃聚乳酸的性能研究[J].高分子学报,2022,53(03):227-235.

Sun Jin-hao,Ni Jin-ping,Lu Dan,et al.Synthesis of Phospholipidated Starch and Its Application for Flame-retardant Poly(lactic acid) with Ammonium Polyphosphate[J].ACTA POLYMERICA SINICA,2022,53(03):227-235.
孙晋皓,倪金平,路丹等.磷化淀粉的合成及其与聚磷酸铵协效阻燃聚乳酸的性能研究[J].高分子学报,2022,53(03):227-235. DOI： 10.11777/j.issn1000-3304.2021.21285.

Sun Jin-hao,Ni Jin-ping,Lu Dan,et al.Synthesis of Phospholipidated Starch and Its Application for Flame-retardant Poly(lactic acid) with Ammonium Polyphosphate[J].ACTA POLYMERICA SINICA,2022,53(03):227-235. DOI： 10.11777/j.issn1000-3304.2021.21285.

摘要

利用9

10-二氢-9-氧杂-10-磷杂菲-10-氧化物(DOPO)和马来酸酐(MA)对淀粉进行改性得到磷化淀粉(DOPOMASt)，通过红外光谱(FTIR)、核磁共振谱(

H-NMR)和X射线光电子能谱(XPS)确定其结构. 利用DOPOMASt作为碳源，与聚磷酸铵(APP)复配后通过熔融共混制备了阻燃聚乳酸(PLA)复合材料. 采用垂直燃烧(UL-94)、极限氧指数(LOI)、热重分析(TGA)研究DOPOMASt对PLA的阻燃性能和热性能的影响. 利用扫描电子显微镜(SEM)观察阻燃剂在PLA中的分散和燃烧后残炭的微观形貌，同时采用TG-IR联用技术对PLA复合材料热降解气相产物进行分析. 结果表明，DOPOMASt促进APP在PLA中分散均匀，当DOPOMASt和APP质量比为1∶1，总质量为10%时，LOI达到26.0%且通过UL-94 V0测试. DOPOMASt与APP协效阻燃促进PLA树脂成碳，形成更加致密的炭层并减少可燃气体的产生，赋予PLA良好的阻燃性能.

Abstract

Phospholipidated starch was synthesized according to the reaction between hydroxyl of starch and anhydride prepared by 9

‍10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and maleic anhydride (MA)

which was characterized by Fourier infrared spectroscopy (FTIR)

nuclear magnetic resonance

(

H-NMR)

and X-ray photoelectron spectrometry (XPS). Melt-blended with ammonium polyphosphate (APP)

the phosphorous-containing starch (DOPOMASt) was used in intumescent flame retardancy of poly(lactic acid) (PLA) as carbon source. The thermal stability and flame retardancy of PLA composites were measured by vertical burning test (UL-94)

limiting oxygen index (LOI) and thermogravimetric analysis (TGA). Dispersion of flame retardants in PLA and morphology of char residues after UL-94 test were observed by scanning electron microscopy (SEM). The gases released during thermal degradation of PLA composites were analyzed by TG-IR. The results showed that the uniform distribution of DOPOMASt and APP in PLA matrix was observed. When the mass ratio of DOPOMASt/APP is equal to 1/1

the LOI value of 26.0% and a UL-94 V0 rating were achieved with 10% total flame retardants. Synergistic effect of DOPOMASt and APP resulted in a compact cross-linked char layer and reduction of the retardant-induced smoke release.

关键词

聚乳酸磷化淀粉聚磷酸铵协效阻燃

Keywords

Poly(lactic acid)Phospholipidated starchAmmonium polyphosphateFlame retardant

references

Chen Xuesi(陈学思), Chen Guoqiang(陈国强), Tao Youhua(陶友华), Wang Yuzhong(王玉忠), Lv Xiaobin(吕小兵), Zhang Liqun(张立群), Zhu Jin(朱锦), Zhang Jun(张军), Wang Xianhong(王献红). Acta Polymerica Sinica(高分子学报), 2019, 50(10): 1068-1082. doi:10.11777/j.issn1000-3304.2019.19124http://dx.doi.org/10.11777/j.issn1000-3304.2019.19124

Castro-Aguirre E, Iniguez-Franco F, Samsudin H, Fang X. Adv Drug Deliv Rev, 2016, 107: 333-336. doi:10.1016/j.addr.2016.03.010http://dx.doi.org/10.1016/j.addr.2016.03.010

Liu S, Qin S, He M, Zhou D, Qin Q, Wang H. Compos Part B-Eng, 2020, 199: 108238. doi:10.1016/j.compositesb.2020.108238http://dx.doi.org/10.1016/j.compositesb.2020.108238

Benvenuta-Tapia J J, Vivaldo-Lima E. React Funct Polym, 2020, 153: 104628. doi:10.1016/j.reactfunctpolym.2020.104628http://dx.doi.org/10.1016/j.reactfunctpolym.2020.104628

Mngomezulu M E, John M J, Jacobs V, Luyt A S. Carbohydr Polym, 2014, 111: 149-182. doi:10.1016/j.carbpol.2014.03.071http://dx.doi.org/10.1016/j.carbpol.2014.03.071

Liu L B, Xu Y, Di Y F, Xu M J, Pan Y, Li B. Compos Part B-Eng, 2020, 202: 180407. doi:10.1016/j.compositesb.2020.108407http://dx.doi.org/10.1016/j.compositesb.2020.108407

Yin W, Chen L, Lu F, Song P, Dai J, Meng L. ACS Omega, 2018, 3: 5615-5626. doi:10.1021/acsomega.8b00540http://dx.doi.org/10.1021/acsomega.8b00540

Wu Cong(伍聪), Yang Dandan(杨丹丹), Wu Gang(吴刚), Chen Sichong(陈思翀). Acta Polymerica Sinica(高分子学报), 2021, 52(2): 176-185. doi:10.11777/j.issn1000-3304.2020.20161http://dx.doi.org/10.11777/j.issn1000-3304.2020.20161

Jia Y W, Zhao X, Fu T, Li D F, Guo Y, Wang X L, Wang Y Z. Compos Part B-Eng, 2020, 197: 108192. doi:10.1016/j.compositesb.2020.108192http://dx.doi.org/10.1016/j.compositesb.2020.108192

Zhao X, Chen L, Li D F, Fu T, He L, Wang X L, Wang Y Z. Chem Eng J, 2021, 412: 128737. doi:10.1016/j.cej.2021.128737http://dx.doi.org/10.1016/j.cej.2021.128737

Lim K S, Bee S T, Sin L T, Tee T T, Ratnam C T, Hui D, Rahmat A R. Compos Part B-Eng, 2016, 84: 155-174. doi:10.1016/j.compositesb.2015.08.066http://dx.doi.org/10.1016/j.compositesb.2015.08.066

Feng J X, Su S P, Zhu J. Polym Adv Technol, 2011, 22: 1115-1122. doi:10.1002/pat.1954http://dx.doi.org/10.1002/pat.1954

Zhu T, Guo J, Fei B, Feng Z Y, Gu X Y, Li H F, Sun J, Zhang S. Cellulose, 2019, 27: 2309-2323. doi:10.1007/s10570-019-02931-xhttp://dx.doi.org/10.1007/s10570-019-02931-x

Cayla A, Rault F, Giraud S, Salaun F, Fierro V, Celzard A. Polymers, 2016, 8(9): 331-346. doi:10.3390/polym8090331http://dx.doi.org/10.3390/polym8090331

Wang J J, Ren Q, Zheng W G, Zhai W T. Ind Eng Chem Res, 2014, 53: 1422-1430. doi:10.1021/ie403041hhttp://dx.doi.org/10.1021/ie403041h

Chen C, Gu X, Jin X, Sun J, Zhang S. Carbohydr Polym, 2017, 157: 1586-1593. doi:10.1016/j.carbpol.2016.11.035http://dx.doi.org/10.1016/j.carbpol.2016.11.035

Villadiego K M, Tapia M J A, Useche J, Macías D E. J Polym Environ, 2021, Doi: 10.1007/s10924-021-02207-1http://dx.doi.org/10.1007/s10924-021-02207-1

Réti C, Casetta M, Duquesne S, Bourbigot S, Delobel R. Polym Adv Technol, 2008, 19: 628-635. doi:10.1002/pat.1130http://dx.doi.org/10.1002/pat.1130

Maqsood M, Seide G. Polymers, 2019, 11(1): 48-63. doi:10.3390/polym11010048http://dx.doi.org/10.3390/polym11010048

Chapple S, Anandjiwala R, Ray S S. J Therm Anal Calorim, 2012, 113: 703-712. doi:10.1007/s10973-012-2776-6http://dx.doi.org/10.1007/s10973-012-2776-6

Zhang Tong(张通), Long Lijuan(龙丽娟), He Wentao(何文涛), He Min(何敏), Qin Shuhao(秦舒浩), Yu Jie(于杰). Acta Polymerica Sinica(高分子学报), 2019, 50(1): 71-81. doi:10.11777/j.issn1000-3304.2018.18148http://dx.doi.org/10.11777/j.issn1000-3304.2018.18148

Pack S, Bobo E, Muir N, Yang K, Swaraj S, Ade H, Cao C H , Korach C S, Kashiwagi T, Rafailovich M H. Polymer, 2012, 53: 4787-4799. doi:10.1016/j.polymer.2012.08.007http://dx.doi.org/10.1016/j.polymer.2012.08.007

Zhang Y, Han P Y, Fang Z P. J Appl Polym Sci, 2018, 135: 46054. doi:10.1002/app.46054http://dx.doi.org/10.1002/app.46054

Costes L, Laoutid F, Aguedo M, Richel A, Brohez S, Delvosalle C, Dubois P. Eur Polym J, 2016, 84: 652-667. doi:10.1016/j.eurpolymj.2016.10.003http://dx.doi.org/10.1016/j.eurpolymj.2016.10.003

Liu P, Liu M M, Gao C, Wang F, Ding Y F, Wen B, Zhang S M, Yang M S. J Appl Polym Sci, 2013, 130(2): 1301-1307. doi:10.1002/app.39318http://dx.doi.org/10.1002/app.39318

Kucharczyk P, Zednik J, Sedlarik V. Macromol Res, 2017, 25(2): 180-189. doi:10.1007/s13233-017-5014-zhttp://dx.doi.org/10.1007/s13233-017-5014-z

Bishai M, De S, Banerjee R. Food Sci Biotechanol, 2013, 22(1): 73-77. doi:10.1007/s10068-013-0051-7http://dx.doi.org/10.1007/s10068-013-0051-7

Braun U, Balabanovich A I, Schartel B, Knoll U, Artner J, Ciesielski M, Döring M, Perez R, Sandler J K W, Altstädt V,Hoffmann T, Pospiech D. Polymer, 2006, 47: 8495-8508. doi:10.1016/j.polymer.2006.10.022http://dx.doi.org/10.1016/j.polymer.2006.10.022

Salmeia K A, Gaan S. Polym Degrad Stabil, 2015, 113: 119-134. doi:10.1016/j.polymdegradstab.2014.12.014http://dx.doi.org/10.1016/j.polymdegradstab.2014.12.014

Bourbigot S, Le Bras M, Delobel R, Trémillon J M. J Chem Soc, Faraday Trans, 1996, 18: 3435-3444. doi:10.1039/ft9969203435http://dx.doi.org/10.1039/ft9969203435

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