聚亚苯基乙烯衍生物中溶剂诱导的共轭聚合物高分子线团与可逆超分子凝胶

张冬莲; 何矩新; 周学宏; 郑楠; 刘琳琳; 解增旗; 马於光

doi:10.11777/j.issn1000-3304.2019.19103

您当前的位置：

首页 >

文章列表页 >

聚亚苯基乙烯衍生物中溶剂诱导的共轭聚合物高分子线团与可逆超分子凝胶

研究论文 | 更新时间：2021-01-26

- 聚亚苯基乙烯衍生物中溶剂诱导的共轭聚合物高分子线团与可逆超分子凝胶
  增强出版
- Solvent-induced Conjugated Polymer Coils and Reversible Supramolecular Gels in Polyphenylene Ethylene Derivatives
- 高分子学报 2019年50卷第12期页码：1280-1289
- 作者机构：
  
  发光材料与器件国家重点实验室华南理工大学材料科学与工程学院　广州 510640
- 作者简介：
  
  E-mail: zhengn@scut.edu.cn Nan Zheng, E-mail: zhengn@scut.edu.cn
  E-mail: msliull@scut.edu.cn Linlin Liu, E-mail: msliull@scut.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 51873068，213334002，51573055，51521002)和科技部国家科技计划(项目号 2013CB834705，2015CB655003，2016YFB0401004)资助项目()
- DOI：10.11777/j.issn1000-3304.2019.19103
  中图分类号：
- 纸质出版日期：2019-12，
  
  网络出版日期：2019-7-24，
  
  收稿日期：2019-5-17，
  
  修回日期：2019-6-7，
扫描看全文
张冬莲, 何矩新, 周学宏, 郑楠, 刘琳琳, 解增旗, 马於光. 聚亚苯基乙烯衍生物中溶剂诱导的共轭聚合物高分子线团与可逆超分子凝胶[J]. 高分子学报, 2019,50(12):1280-1289.

Dong-lian Zhang, Ju-xin He, Xue-hong Zhou, Nan Zheng, Lin-lin Liu, Zeng-qi Xie, Yu-guang Ma. Solvent-induced Conjugated Polymer Coils and Reversible Supramolecular Gels in Polyphenylene Ethylene Derivatives[J]. Acta Polymerica Sinica, 2019,50(12):1280-1289.
张冬莲, 何矩新, 周学宏, 郑楠, 刘琳琳, 解增旗, 马於光. 聚亚苯基乙烯衍生物中溶剂诱导的共轭聚合物高分子线团与可逆超分子凝胶[J]. 高分子学报, 2019,50(12):1280-1289. DOI： 10.11777/j.issn1000-3304.2019.19103.

Dong-lian Zhang, Ju-xin He, Xue-hong Zhou, Nan Zheng, Lin-lin Liu, Zeng-qi Xie, Yu-guang Ma. Solvent-induced Conjugated Polymer Coils and Reversible Supramolecular Gels in Polyphenylene Ethylene Derivatives[J]. Acta Polymerica Sinica, 2019,50(12):1280-1289. DOI： 10.11777/j.issn1000-3304.2019.19103.

摘要

通过引入与聚(2-(4-(3'

7'-二甲基辛氧基苯)-1

4-亚苯基乙烯) (P-PPV)主链亚苯基乙烯结构类似的R-limonene作为辅助溶剂，有效地实现聚合物链段的充分溶解和解缠结，并在此基础上成功制备了P-PPV的共轭高分子线团和可逆超分子凝胶. 通过P-PPV的稀溶液旋涂薄膜的AFM图像，可以清晰地观察到纳米纤维形成的高分子线团及线团内部的精细结构. P-PPV在R-limonene的作用下，分子链从相互纠缠的状态发生解缠结作用，形成相互孤立的卷曲团，增强PLQY与荧光寿命. 通过不同溶剂条件，得到了不同曲率的聚集体，对共轭高分子柔顺性有了进一步的认识. 浓溶液下，P-PPV形成可逆的超分子凝胶，并具有良好的温度响应特性，凝胶生成区间在55 ~ 35 °C. 凝胶化的P-PPV是一种均匀的物理交联网络，使P-PPV的结构更为稳定，可以有效提升器件的稳定性、亮度和寿命.

Abstract

Good solubility is the premise in solution processing of conjugated polymers while strong

interaction in the main chain is generally the main cause for bad dissolution. In this paper

our strategy is intruducing the auxiliary solvent and repeat unit with the similar structure as solvent in the main chain for good solubility of conjugated polymer. Based on the well dissolution between the auxiliary solvent and polymer repeat units induce a quasi-single polymer chain and advanced self-assembly

conjugated polymer coils and reversible supramolecular gels were acheived. R-limonene was added into chlorobenzene as the auxiliary solvent for the well solubility of poly(2-(4-(3'

7'-dimethyloctylo-xyphenyl)-1

4-pheny-lene-vinylene (P-PPV). Atomic force microscopy (AFM) images of the spin-coated films with solutions of low concentration showed the isolated P-PPV polymer coils and the fine structure inside the coils in chlorobenzene/R-limonene mixture; while with the absence of R-limonene

the packing of sub-polymer chain was clearly observed. In concentrated solution

P-PPV formed a reversible supramolecular gel at the concentration of 2 mg mL

−1

with good temperature response characteristics in chlorobenzene/R-limonene mixture

and the gel temperature of P-PPV is in the range of 55 °C to −35 °C. Aggregations with different curvatures were obtained in different solvents

which made us further understand the pliability of conjugated polymer. P-PPV molecular chains were dissolved by the enhanced solubility of alkyl sidechain and phenylene ethylene

that made it became pliable and then entangled

which allowed the assembly of polymer coils with high curvature and supramolecular gel with high ratio of solvent wrap. The fluorescence quantum yield and fluorescence lifetime were both improved in conjugated polymer coils and reversible supramolecular gels

but the physical cross-linking points by

interaction showed low energy level as those of charge trap sites

where the mobility became lower. In the organic light emitting diodes (OLED)

the uniform physical cross-linking network made the structure of P-PPV more stable and could effectively improve the stability

brightness

and lifetime of the device.

关键词

凝胶共轭聚合物聚合物发光二极管链缠结

Keywords

GelConjugated polymerPolymer light-emitting diodeChain entanglement

references

Xu J, Tan X, Chen L, Li X, Xie F. Carbohyd Polym , 2019 . 215 ( 1 ): 151 - 159.

Sakaguchi K, Arai T, Shimizu T, Umezu S. Jpn J Appl Phys , 2017 . 56 ( 5S2 ): 05EB06 DOI:10.7567/JJAP.56.05EB06http://doi.org/10.7567/JJAP.56.05EB06 .

Feng L, Wang K, Zhang X, Sun X. Adv Funct Mater , 2018 . 28 ( 4 ): 1704463 DOI:10.1002/adfm.201704463http://doi.org/10.1002/adfm.201704463 .

Shofarul W, Achilleas S, Ruofan S, Eloise B, Sahika I. Adv Mater Interfaces , 2018 . 6 1800928 .

Marullo S, Rizzo C, Dintcheva N T, Giannici F, D’Anna F. J Colloid Interf Sci , 2018 . 517 182 - 193 . DOI:10.1016/j.jcis.2018.01.111http://doi.org/10.1016/j.jcis.2018.01.111 .

Xu Jiangfei(徐江飞), Zhang Xi(张希). Acta Polymerica Sinica(高分子学报) , 2017 . ( 1 ): 37 - 49 . DOI:10.11777/j.issn1000-3304.2017.16262http://doi.org/10.11777/j.issn1000-3304.2017.16262 .

Gu Wenjuan(顾文娟), Lu Yaming(陆亚明), Zhang Youwei(张幼维), Zhao Jiongxin(赵炯心). Acta Polymerica Sinica(高分子学报) , 2016 . ( 8 ): 1072 - 1078.

Lee H Y, Park S H, Kim J H, Kim M S. Polym Chem , 2017 . 8 ( 43 ): 6606 - 6616 . DOI:10.1039/C7PY01460Khttp://doi.org/10.1039/C7PY01460K .

Wang Tianyu(王天宇), Shen Zhaocun(沈兆存), Liu Minghua(刘鸣华). Acta Polymerica Sinica(高分子学报) , 2017 . ( 1 ): 50 - 62 . DOI:10.11777/j.issn1000-3304.2017.16319http://doi.org/10.11777/j.issn1000-3304.2017.16319 .

Gao H, Xu D, Wang Y, Wang Y, Liu X, Han A, Zhang C. Dyes Pigments , 2018 . 150 59 - 66 . DOI:10.1016/j.dyepig.2017.11.018http://doi.org/10.1016/j.dyepig.2017.11.018 .

Hopkins C C, Bruyn J R. J Rheol , 2019 . 63 ( 1 ): 191 - 201 . DOI:10.1122/1.5054598http://doi.org/10.1122/1.5054598 .

Xue P, Ding J, Jin M, Lu R. J Mater Chem C , 2017 . 5 ( 22 ): 5299 - 5303 . DOI:10.1039/C7TC01028Ahttp://doi.org/10.1039/C7TC01028A .

Khan S, Akhtar N, Minhas M U, Badshah S F. AAPS PharmSciTech , 2019 . 20 ( 3 ): 119 DOI:10.1208/s12249-019-1328-9http://doi.org/10.1208/s12249-019-1328-9 .

Marlen E, Steffen R, Carsten S, Voskuhl J. Soft Matter , 2018 . 14 ( 30 ): 6166 - 6170 . DOI:10.1039/C8SM01190Ghttp://doi.org/10.1039/C8SM01190G .

Tamesue S, Abe S, Mitsumata T, Tsubokawa N, Yamauchi T. J Polym Sci, Part A: Polym Chem , 2016 . 54 ( 10 ): 1317 - 1322 . DOI:10.1002/pola.v54.10http://doi.org/10.1002/pola.v54.10 .

Zhao Z, Lam J W Y, Tang B Z. Soft Matter , 2013 . 9 ( 18 ): 4564 - 4579 . DOI:10.1039/c3sm27969chttp://doi.org/10.1039/c3sm27969c .

Kim B G, Jeong E J, Park H J, Bilby D, Guo L J, Kim J. ACS Appl Mater Interfaces , 2011 . 3 ( 3 ): 674 - 680 . DOI:10.1021/am101067xhttp://doi.org/10.1021/am101067x .

Zhao K, Khan H U, Li R, Su Y. Amassian A. Adv Funct Mater , 2013 . 23 ( 48 ): 6024 - 6035 . DOI:10.1002/adfm.v23.48http://doi.org/10.1002/adfm.v23.48 .

Mao S, Ni S, Du Y, Shen L. Polymer , 1995 . 36 ( 17 ): 3409 - 3411 . DOI:10.1016/0032-3861(95)99444-Yhttp://doi.org/10.1016/0032-3861(95)99444-Y .

Duan P, Cao H, Zhang L, Liu M. Soft Matter , 2014 . 10 ( 30 ): 5428 - 5448 . DOI:10.1039/C4SM00507Dhttp://doi.org/10.1039/C4SM00507D .

Li B, Zhu Y, Liu H, Lu Z. Phys Chem Chem Phys , 2012 . 14 ( 14 ): 4964 - 4970 . DOI:10.1039/c2cp23932ahttp://doi.org/10.1039/c2cp23932a .

Schwalm T, Wiesecke J, Immel S, Rehahn M. Macromol Rapid Commum , 2010 . 30 ( 15 ): 1295 - 1322.

更多指标>

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

基于3，6-二氯噻吩并［3，2-b］噻吩的共轭聚合物的直接芳基化缩聚合成及其半导体性质

凝固浴温度对再生纤维素材料结构与性能的影响研究

主链为咔唑-吖啶给体/侧基为三联吡啶受体的热诱导延迟荧光共轭聚合物合成及发光性质

侧基可脱除共轭聚合物的合成及其在光电探测器中的应用

基于导电高分子-叶绿体杂化材料活性氧增强策略的肿瘤治疗