Synthesis of Azobenzene Grafted Poly(ionic liquid)s and Its Multifunctional Optical Applications

Shen-jian Xu; Si-qing Yang; Han Miao; Xi Yang; Shao-liang Lin

doi:10.11777/j.issn1000-3304.2024.24143

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Synthesis of Azobenzene Grafted Poly(ionic liquid)s and Its Multifunctional Optical Applications

Research Article | 更新时间：2025-01-10

- Synthesis of Azobenzene Grafted Poly(ionic liquid)s and Its Multifunctional Optical Applications
  增强出版
- Acta Polymerica Sinica Vol. 55, Issue 12, Pages: 1696-1705(2024)
- 作者机构：
  
  1.上海市先进聚合物材料重点实验室华东理工大学材料科学与工程学院上海 200237
  2.上海交通大学口腔医学院上海交通大学医学院附属第九人民医院上海 200011
- 作者简介：
  
  Han Miao, E-mail: hmiao@ecust.edu.cn
  Shao-liang Lin, E-mail: slin@ecust.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2024.24143
  CLC：
- CSTR：32057.14.GFZXB.2024.7273
- Published：20 December 2024，
  
  Published Online：14 October 2024，
  
  Received：29 May 2024，
  
  Accepted：2024-07-29
- 稿件说明：
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许神剑, 杨思卿, 缪涵, 杨溪, 林绍梁. 偶氮苯接枝的聚离子液体的合成及其多功能光学应用. 高分子学报, 2024, 55(12), 1696-1705

Xu, S. J.; Yang, S. Q.; Miao, H; Yang, X; Lin, S. L. Synthesis of azobenzene grafted poly(ionic liquid)s and its multifunctional optical applications. Acta Polymerica Sinica, 2024, 55(12), 1696-1705
许神剑, 杨思卿, 缪涵, 杨溪, 林绍梁. 偶氮苯接枝的聚离子液体的合成及其多功能光学应用. 高分子学报, 2024, 55(12), 1696-1705 DOI： 10.11777/j.issn1000-3304.2024.24143. CSTR： 32057.14.GFZXB.2024.7273.

Xu, S. J.; Yang, S. Q.; Miao, H; Yang, X; Lin, S. L. Synthesis of azobenzene grafted poly(ionic liquid)s and its multifunctional optical applications. Acta Polymerica Sinica, 2024, 55(12), 1696-1705 DOI： 10.11777/j.issn1000-3304.2024.24143. CSTR： 32057.14.GFZXB.2024.7273.

摘要

采用传统的自由基聚合和聚合后修饰相结合的策略，设计并合成了一种具有不同偶氮苯接枝率的新型聚离子液体(PIL-Azo-

)，并系统地研究了其物理化学性质和光学性能. 利用紫外-可见分光光度计(UV-Vis)对聚离子液体薄膜的光致异构化、透射光谱、散射光谱和透射雾度进行了详细表征. 结果表明，通过简单的浇铸法制备的薄膜具有强紫外屏蔽性能(200~400 nm)、光诱导的透过率可调谐性能(400~600 nm)、高透明度(600~800 nm)、良好的热稳定性和极佳的酸碱稳定性等优点. 进一步，结合掩膜版法，该薄膜还可以重复定制不同的透明图案. 这种偶氮苯接枝的聚离子液体薄膜有望推动多功能光学涂层、智能窗户等领域的发展.

Abstract

Three kinds of poly(ionic liquid)s (PIL-Azo-

) with different grafting ratios of azobenzene (10%

30%

and 50%) were successfully synthesized by using conventional free radical polymerization and post-polymerization modification strategies. The initial decomposition temperatures of PIL-Azo-

were higher than 300 ℃

indicating good thermal stability. The films prepared by simple casting method exhibited excellent UV shielding performance in the 200-400 nm band

which can block almost all UV rays; in the 400-600 nm band

they have tunable transmittance performance

which can be reversibly changed under the irradiation of 365 nm UV and 450 nm visible light

and the transmittance decreases accordingly with the increase of the content of azobenzene; in the 600-800 nm band

they show a high transmittance performance

which can be reversed with an increase in the content of azobenzene. In addition

the pure PIL-Azo-

casted films have excellent acid and alkali resistance

and the transmission spectra of the films remain almost unchanged after immersion in a pH=2 HCl solution or pH=12 NaOH solution for 6 h

which makes them suitable for the more severe environments. Finally

its application in the field of pattern writing and erasing is demonstrated in combination with the mask plate method

in which the transparent film can be repeatedly customized with different patterns under the irradiation of 365 nm UV light and 450 nm visible light. These poly(ionic liquid) films with strong UV shielding

tunable

transmittance

high transparency

good thermal stability

and excellent acid-base stability are expected to contribute to the development of multifunctional optical coatings

smart windows

and other fields.

关键词

聚离子液体偶氮苯紫外屏蔽光响应高透过率

Keywords

Poly(ionic liquid)sAzobenzeneUV-shieldingPhoto-responseHigh-transparency

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Related Institution

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