State-of-the-art and Research Progress of Block-type Thermoplastic Elastomers

Li-qian Zhu; Yang-ke Xiao; Wen-Jun Wang; Ping-wei Liu; Qing-yue Wang; Su-yun Jie; Ji-jiang Hu; Zhen Yao; Bo-Geng Li

doi:10.11777/j.issn1000-3304.2025.25036

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State-of-the-art and Research Progress of Block-type Thermoplastic Elastomers

更新时间：2025-06-20

- State-of-the-art and Research Progress of Block-type Thermoplastic Elastomers
- Acta Polymerica Sinica Pages: 1-17(2025)
- 作者机构：
  
  1.浙江大学化学工程与低碳技术全国重点实验室杭州 310058
  2.浙江大学衢州研究院衢州 324000
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2025.25036
  CLC：
- CSTR：32057.14.GFZXB.2025.7388
- Received：14 February 2025，
  
  Accepted：25 March 2025，
  
  Published Online：20 June 2025，
- 稿件说明：
移动端阅览
朱丽倩, 肖扬可, 王文俊, 刘平伟, 王青月, 介素云, 胡激江, 姚臻, 李伯耿. 嵌段型热塑性弹性体——现状与进展. 高分子学报, doi: 10.11777/j.issn1000-3304.2025.25036

Zhu, L. Q.; Xiao, Y. K.; Wang, W. J.; Liu, P. W.; Wang, Q. Y.; Jie, S. Y.; Hu, J. J.; Yao, Z.; Li, B. G. State-of-the-art and research progress of block-type thermoplastic elastomers. Acta Polymerica Sinica, doi: 10.11777/j.‍issn1000-3304.2025.25036
朱丽倩, 肖扬可, 王文俊, 刘平伟, 王青月, 介素云, 胡激江, 姚臻, 李伯耿. 嵌段型热塑性弹性体——现状与进展. 高分子学报, doi: 10.11777/j.issn1000-3304.2025.25036 DOI： CSTR： 32057.14.GFZXB.2025.7388.

Zhu, L. Q.; Xiao, Y. K.; Wang, W. J.; Liu, P. W.; Wang, Q. Y.; Jie, S. Y.; Hu, J. J.; Yao, Z.; Li, B. G. State-of-the-art and research progress of block-type thermoplastic elastomers. Acta Polymerica Sinica, doi: 10.11777/j.‍issn1000-3304.2025.25036 DOI： 10.11777/j.issn1000-3304.2025.25036. CSTR： 32057.14.GFZXB.2025.7388.

摘要

热塑性弹性体具有独特的微相分离结构，使其既具备橡胶弹性，又能够在高温下重塑. 嵌段型热塑性弹性体是热塑性弹性体中最典型的品种，其链结构具有多样性，这不仅丰富了嵌段型热塑性弹性体的宏观性能，还使其得到了广泛应用. 本文综述了已工业化的几种嵌段型热塑性弹性体，以及多年来人们为改善它们耐热性、耐化学性和力学性能，在硬段和软段物理改性、化学修饰以及动态共价交联等方面所做的工作；介绍了研究者在物理与化学双重交联的热塑性弹性体构建中发现的形状记忆和自修复功能，以及嵌段型热塑性弹性体的介电性能；展望了嵌段型热塑弹性体在智能电子、仿生机器人等高端领域中的应用前景. 进一步介绍了生物基和生物降解热塑性弹性体，以及以废弃高分子为原料的热塑性弹性体的制备研究.

Abstract

The unique microphase-separated structure of thermoplastic elastomers endows them with rubber elasticity and remolding ability at high temperatures. Block-type thermoplastic elastomers are the most typical types of thermoplastic elastomers. Due to the diversity of tunable chain structures

the materials exhibit abundant macroscopic properties and wide applications. This article reviews several kinds of industrialized block-type thermoplastic elastomers and the various efforts in improving the heat resistance

chemical resistance

and mechanical properties through the physical modification and chemical modification of hard and soft segments

as well as dynamic covalent cross-linking. This article also describes the shape memory and self-healing functions of thermoplastic elastomers with dual physical and chemical cross-links

as well as the dielectric properties of block-type thermoplastic elastomers

demonstrating their application prospects in high-end fields such as smart electronics and bionic robots. This article further introduces the preparation of bio-based and bio-degradable thermoplastic elastomers

as well as the thermoplastic elastomers from waste or even waste polymers.

关键词

Keywords

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