近红外响应性可复写光子凝胶的构筑与性能调控

肖鑫; 张菱素; 施冬健; 李小杰; 东为富; 陈明清

doi:10.11777/j.issn1000-3304.2022.22038

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近红外响应性可复写光子凝胶的构筑与性能调控

研究论文 | 更新时间：2024-10-08

- 近红外响应性可复写光子凝胶的构筑与性能调控
- Fabrication of Near-infrared Responsive Rewritable Photonic Hydrogel and Property Control
- 高分子学报 2022年53卷第8期页码：933-941
- 作者机构：
  
  合成与生物胶体教育部重点实验室江南大学化学与材料工程学院无锡 214122
- 作者简介：
  
  E-mail: mqchen@jiangnan.edu.cn
- 基金信息：
  
  国家自然科学基金(基金号 21571084);江苏省自然科学基金(基金号 BK20181349)
- DOI：10.11777/j.issn1000-3304.2022.22038
  中图分类号：
- 纸质出版日期：2022-08-20，
  
  网络出版日期：2022-06-12，
  
  收稿日期：2022-02-13，
  
  录用日期：2022-03-17
- 稿件说明：
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肖鑫,张菱素,施冬健等.近红外响应性可复写光子凝胶的构筑与性能调控[J].高分子学报,2022,53(08):933-941.

Xiao Xin,Zhang Ling-su,Shi Dong-jian,et al.Fabrication of Near-infrared Responsive Rewritable Photonic Hydrogel and Property Control[J].ACTA POLYMERICA SINICA,2022,53(08):933-941.
肖鑫,张菱素,施冬健等.近红外响应性可复写光子凝胶的构筑与性能调控[J].高分子学报,2022,53(08):933-941. DOI： 10.11777/j.issn1000-3304.2022.22038.

Xiao Xin,Zhang Ling-su,Shi Dong-jian,et al.Fabrication of Near-infrared Responsive Rewritable Photonic Hydrogel and Property Control[J].ACTA POLYMERICA SINICA,2022,53(08):933-941. DOI： 10.11777/j.issn1000-3304.2022.22038.

摘要

设计合成了一种以聚苯乙烯光子晶体为模板的聚(

-异丙基丙烯酰胺-甲基丙烯酸羟乙酯)光子凝胶，引入不同长径比的金纳米棒赋予凝胶近红外致变色能力. 响应时间及变色性能随凝胶中甲基丙烯酸羟乙酯的含量变化，其含量为30%时凝胶结构色变化达到峰值(34 nm). 通过改变聚苯乙烯微球直径可以调控光子凝胶变色范围，颜色变化可覆盖从红色到蓝色. 以聚对苯二甲酸乙二醇酯包覆可制得近红外响应性器件，在近红外光照射下区域会发生颜色变化，循环稳定性良好，有望应用于显示器、近红外检测器和彩色复写纸等领域.

Abstract

Photonic crystals (PCs) are a kind of optical material composed of periodic arranged refractive medias. Different with traditional chemical pigments

PCs' structural colors a

re produced by the physical interaction between refraction media and light

which makes PCs bleach resistant. Thus PCs show a great potential application in the field of rewritable paper

but the lack of light induced-color change ability limited its application. We design a Near-infrared (NIR) response photonic crystals hydrogel based on poly(

-isopropyl acrylamide-

-2-hydroxyethyl methacrylate) and gold nanorods. The incorporated gold nanorods endow hydrogel with NUR induced color change. The swelling of the polymer chain expands the spacing distance between polystyrene microspheres in the photonic crystal

resulting in the red-shift of structural color change and providing the possibility for NIR response. After NIR irradiation

the temperature of photonic hydrogel would increase due to the LSPR effect of Au NRs. Then

the NIPAm segment shrinks and reduces the spacing between polystyrene microspheres

resulting in the blue shift of structural color. The NIPAm chains would swell once NIR removed

leading to photonic hydrogel's structural color restore. The response time and displaying performance could be regulated by changing the content of hydroxyethyl methacrylate. A significant color change (34 nm) appeared in the 30% content of hydroxyethyl methacrylate

resulting the hydrogel could cover a range from red to blue by changing the diameter of the polystyrene templates. The photonic hydrogel could fabricate NIR responsive devices

via

polyethene terephthalate encapsulate. The color of the irradiated area would change under the NIR light irradiation. Moreover

the device shows excellent reversibility in the loop test. This strategy would pave a new route for smart displays

NIR detectors

and rewritable paper applications.

关键词

金纳米棒复合光子水凝胶复写纸近红外响应

Keywords

Gold nanorodsHybrid photonic hydrogelRewritable paperNear-infrared responsiveness

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