Phototransistor Based on Organic Cocorystals

Chun Zhen; Shu-yu Li; Yi-han Zhang; Fei Li; Meng-jia Jiang; Xiao-tao Zhang; Wen-ping Hu

doi:10.11777/j.issn1000-3304.2021.21329

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Phototransistor Based on Organic Cocorystals

Research Article | 更新时间：2024-10-08

- Phototransistor Based on Organic Cocorystals
  增强出版
- ACTA POLYMERICA SINICA Vol. 53, Issue 4, Pages: 396-404(2022)
- 作者机构：
  
  1.天津市分子光电科学重点实验室天津大学理学院天津 300072
  2.天津大学分子聚集态科学研究院天津 300072
  3.青藏高原资源化学与生态环境保护国家民委重点实验室青海民族大学西宁 810007
  4.天津大学-新加坡国立大学福州联合学院天津大学国际校区福州 350207
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2021.21329
  CLC：
- Published：20 April 2022，
  
  Published Online：20 January 2022，
  
  Received：30 October 2021，
  
  Revised：09 December 2021，
- 稿件说明：
移动端阅览
甄淳,李舒豫,张伊晗等.一种基于有机共晶的光控晶体管[J].高分子学报,2022,53(04):396-404.

Zhen Chun,Li Shu-yu,Zhang Yi-han,et al.Phototransistor Based on Organic Cocorystals[J].ACTA POLYMERICA SINICA,2022,53(04):396-404.
甄淳,李舒豫,张伊晗等.一种基于有机共晶的光控晶体管[J].高分子学报,2022,53(04):396-404. DOI： 10.11777/j.issn1000-3304.2021.21329.

Zhen Chun,Li Shu-yu,Zhang Yi-han,et al.Phototransistor Based on Organic Cocorystals[J].ACTA POLYMERICA SINICA,2022,53(04):396-404. DOI： 10.11777/j.issn1000-3304.2021.21329.

摘要

以9

10-二苯乙炔基蒽(BPEA)作为给体分子，均苯四甲酸二酰亚胺(PMD)作为受体分子，通过溶液法制备了一种新型的电荷转移共晶BPEA-PMD. 共晶结构中，给受体分子以2:1的摩尔比呈现混合堆积模式. 通过一系列的表征，发现了其独特的光电性质，BPEA-PMD共晶分子表现出红色荧光发射特性并且兼具P型传输性能，其空穴迁移率可达8.33×10

-2

·V

-1

·s

-1

. 基于其优异的电学性能，制备了共晶光响应晶体管器件，其光响应度(

)为1.67×10

A·W

-1

，这证明了有机共晶在光电探测器方面的巨大应用潜力.

Abstract

A novel charge transfer cocrystal BPEA-PMD was prepared by

solution method using 9

‍10-diphenylacetylene anthracene (BPEA) as donor molecule and pyromellitic diimide (PMD) as acceptor molecule. The D-A cocrystals show a mixed stacking mode with a molar ratio of 2:1. A series of spectral analyses prove that there is a charge transfer characteristic in the BPEA-PMD cocrystals

which narrows the band gap of the cocrystals and further makes the cocrystals system show excellent photoelectric properties. BPEA-PMD cocrystals exhibit red fluorescence emission

and the PL lifetime is 1.14 ns

showing a single exponential decay process

which indicates that the luminescence process of BPEA-PMD cocrystals is derived from only one excited state. In addition

BPEA-PMD cocrystals display p-type transport properties with hole mobility up to 8.33×10

-2

·V

-1

·s

-1

. Based on its excellent electrical properties

photoresponsive transistors device was prepared. Under the illumination of 450 nm light

the source-drain current of the phototransistors based on BPEA-PMD increases significantly. Moreover

photosensitivity (

)

photoresponsivity (

)

and detectivity (

) are several key parameters for evaluating the photoelectric detection capability. The phototransistors for BPEA-PMD cocrystals demonstrate the

max

of 37.38

max

of 1.67×10

A·W

-1

and

max

of 2.06×10

Jones

which proves the great potential of the organic cocrystals in the application of photoelectric detectors.

关键词

有机共晶电荷转移红色荧光P型传输光响应

Keywords

Organic cocrystalsCharge transferRed fluorescenceP-type transportPhotoresponse

references

Clark J, Lanzani G. Nat Photon, 2010, 4: 438-446. doi:10.1038/nphoton.2010.160http://dx.doi.org/10.1038/nphoton.2010.160

Dong Huanli(董焕丽), Yan Qingqing(燕青青), Hu Wenping(胡文平). Acta Polymerica Sinica(高分子学报), 2017, (8): 1246-1260. doi:10.11777/j.issn1000-3304.2017.17127http://dx.doi.org/10.11777/j.issn1000-3304.2017.17127

Wang C, He K, Li J F, Chen X D. Smart Mat, 2021, 2: 252-262. doi:10.1002/smm2.1068http://dx.doi.org/10.1002/smm2.1068

Wang W B, Zhang F J, Du M D, Li L L, Zhang M, Wang K, Wang Y S, Hu B, Fang Y, Huang J S. Nano Lett, 2017, 17: 1995-2002. doi:10.1021/acs.nanolett.6b05418http://dx.doi.org/10.1021/acs.nanolett.6b05418

Deng X, Yu X H, Xiao J C, Zhang Q C. Aggregate, 2021, 2: e35. doi:10.1002/agt2.35http://dx.doi.org/10.1002/agt2.35

Ye H Q, Liu G F, Liu S, Casanova D, Ye X, Tao X T, Zhang Q C, Xiong Q H. Angew Chem Int Ed, 2018, 57: 1928-1932. doi:10.1002/anie.201712104http://dx.doi.org/10.1002/anie.201712104

Zhu W G, Zheng R H, Zhen Y G, Yu Z Y, Dong H L, Fu H B, Shi Q, W P. J Am Chem Soc, 2015, 137: 11038-11046. doi:10.1021/jacs.5b05586http://dx.doi.org/10.1021/jacs.5b05586

Zhu W G, Zhu L Y, Zou Y, Wu Y S, Zhen Y G, Dong H L, Fu H B, Wei Z X, Shi Q, Hu W P. Adv Mater, 2016, 28: 5954-5962. doi:10.1002/adma.201600280http://dx.doi.org/10.1002/adma.201600280

Park S K, Cho I, Gierschner G, Kim J H, Kim J H, Kwon J E, Kwon O K, Whang D R, Park J H, An B K, Park S Y. Angew Chem Int Ed, 2016, 55: 203-207. doi:10.1002/anie.201508210http://dx.doi.org/10.1002/anie.201508210

Wang Z R, Yu F, Chen W Q, Wang J F, Liu J Y, Yao C J, Zhao J F, Dong H L, Hu W P, Zhang Q C. Angew Chem Int Ed, 2020, 59: 17580-17586. doi:10.1002/anie.202005933http://dx.doi.org/10.1002/anie.202005933

Sun Y Q, Lei Y L, Dong H L, Zhen Y G, Hu W P. J Am Chem Soc, 2018, 140: 6186-6189. doi:10.1021/jacs.8b00772http://dx.doi.org/10.1021/jacs.8b00772

Liu G F, Liu J, Ye X, Nie L, Gu P Y, Tao X T, Zhang Q C. Angew Chem Int Ed, 2017, 56: 198-202. doi:10.1002/anie.201609667http://dx.doi.org/10.1002/anie.201609667

Yu P P, Li Y, Zhao H J, Zhu L Y, Wang Y S, Xu W, Zhen Y G, Wang X R, Dong H L, Zhu D B, Hu W P. Small, 2021, 17: 2006574. doi:10.1002/smll.202006574http://dx.doi.org/10.1002/smll.202006574

Qin Y K, Cheng C L, Geng H, Wang C, Hu W P, Xu W, Shuai Z G, Zhu D B. Phys Chem Chem Phys, 2016, 18: 14094-14103. doi:10.1039/c6cp01509chttp://dx.doi.org/10.1039/c6cp01509c

Zhang J, Jin J Q, Xu H X, Zhang Q C, Huang W. J Mater Chem C, 2018, 6: 3485-3498. doi:10.1039/c7tc04389ahttp://dx.doi.org/10.1039/c7tc04389a

Huang Y J, Wang Z R, Chen Z, Zhang Q C. Angew Chem Int Ed, 2019, 58: 9696-9711. doi:10.1002/anie.201900501http://dx.doi.org/10.1002/anie.201900501

Park S K, Varghese S, Kim J H, Yoon S J, Kwon O K, An B K, Gierschner J, Park S Y. J Am Chem Soc, 2013, 135: 4757-4764. doi:10.1021/ja312197bhttp://dx.doi.org/10.1021/ja312197b

Park S K, Kim J H, Ohto T, Yamada R, Jones A O F, Whang D R, Cho I, Oh S, Hong S H, Kwon J E, Kim J H, Olivier Y, Fischer R, Resel R, Gierschner J, Tada H, Park S Y. Adv Mater, 2017, 29: 1701346. doi:10.1002/adma.201701346http://dx.doi.org/10.1002/adma.201701346

Zhang H T, Jiang L, Zhen Y G, Zhang J, Han G C, Zhang X T, Fu X L, Yi Y P, Xu W, Dong H L, Chen W, Hu W P, Zhu D B. Adv Electron Mater, 2016, 2: 1500423. doi:10.1002/aelm.201500423http://dx.doi.org/10.1002/aelm.201500423

Xu B B, Li Z, Chang S Q, Li C N, Ren S Q. ACS Appl Electron Mater, 2019, 1(9): 1735-1739. doi:10.1021/acsaelm.9b00337http://dx.doi.org/10.1021/acsaelm.9b00337

Wu H N, Sun Y J, Sun L J, Wang L W, Zhang X T, Hu W P. Chin Chem Lett, 2021, 32: 3007-3010. doi:10.1016/j.cclet.2021.03.045http://dx.doi.org/10.1016/j.cclet.2021.03.045

Liang Y Y, Qin Y K, Chen J, Xing W L, Zou Y, Sun Y M, Xu W, Zhu D B. Adv Sci, 2020, 7: 1902456. doi:10.1002/advs.201902456http://dx.doi.org/10.1002/advs.201902456

Fan C C, Zoombelt A P, Jiang H, Fu W F, Wu J K, Yuan W T, Wang Y, Li H Y, Chen H Z, Bao Z N. Adv Mater, 2013, 25(40): 5762-5766. doi:10.1002/adma.201302605http://dx.doi.org/10.1002/adma.201302605

Sun L J, Wang Y, Yang F X, Zhang X T, Hu W P. Adv Mater, 2019, 31: 1902328. doi:10.1002/adma.201902328http://dx.doi.org/10.1002/adma.201902328

Wakahara T, Nagaoka K, Nakagawa A, Hirata C, Matsushita Y, Miyazawa K, Ito O, Wada Y, Takagi M, Ishimoto T, Tachikawa M, Tsukagoshi K. ACS Appl Mater Interfaces, 2020, 12(2): 2878-2883. doi:10.1021/acsami.9b18784http://dx.doi.org/10.1021/acsami.9b18784

Wang Z R, Yu F, Xie J, Zhao J F, Zou Y, Wang Z P, Zhang Q C. Chem Eur J, 2020, 26: 3578-3585. doi:10.1002/chem.201904901http://dx.doi.org/10.1002/chem.201904901

Wang Y, Wu H, Zhu W G, Zhang X T, Liu Z Y, Wu Y S, Feng C F, Dang Y F, Dong H L, Fu H B, Hu W P. Angew Chem Int Ed, 2021, 60: 6344-6350. doi:10.1002/anie.202015326http://dx.doi.org/10.1002/anie.202015326

Zhu W G, Yi Y P, Zhen Y G, Hu W P. Small, 2015, 11(18): 2150-2156. doi:10.1002/smll.201402330http://dx.doi.org/10.1002/smll.201402330

Huang Y J, Wang Z R, Chen Z, Zhang Q C. Angew Chem Int Ed, 2019, 58: 9696-9711. doi:10.1002/anie.201900501http://dx.doi.org/10.1002/anie.201900501

Geng H, Zheng X Y, Shuai Z G, Zhu L Y, Yi Y P. Adv Mater, 2015, 27: 1443-1449. doi:10.1002/adma.201404412http://dx.doi.org/10.1002/adma.201404412

Jin J Q, Wu S Y, Ma Y D, Dong C Q, Wang W, Liu X T, Xu H X, Long G K, Zhang M T, Zhang J, Huang W. ACS Appl Mater Interfaces, 2020, 12: 19718-19726. doi:10.1021/acsami.9b23590http://dx.doi.org/10.1021/acsami.9b23590

Liu Y, Hu H P, Xu L, Qiu B, Liang J, Ding F, Wang K, Chu M M, Zhang W, Ma M, Chen B, Yang X Z, Zhao Y S. Angew Chem Int Ed, 2020, 59: 4456-4463. doi:10.1002/anie.201913441http://dx.doi.org/10.1002/anie.201913441

Wang W, Luo L X, Sheng P, Zhang J, Zhang Q C. Chem Eur J, 2020, 26: 1-28. doi:10.1002/chem.202002640http://dx.doi.org/10.1002/chem.202002640

SagadeA A, Rao K V, George S J, Dattac A, Kulkarni G U. Chem Commun, 2013, 49: 5847-5849. doi:10.1039/c3cc41841chttp://dx.doi.org/10.1039/c3cc41841c

Tao J W, Liu D, Qin Z S, Shao B, Jing J B, Li H X, Dong H L, Xu B, Tian W J. Adv Mater, 2020, 32: 1907791. doi:10.1002/adma.201907791http://dx.doi.org/10.1002/adma.201907791

Zhu W G, Zheng R H, Fu X L, Fu H B, Shi Q, Zhen Y G, Dong H L, Hu W P. Angew Chem, 2015, 127: 6889-6893. doi:10.1002/ange.201501414http://dx.doi.org/10.1002/ange.201501414

Zhang Y W, Zhang D D, Huang T Y, Gillett A J, Liu Y, Hu D P, Cui L S, Bin Z Y, Li G M, Wei J B, Duan L. Angew Chem Int Ed, 2021, 60: 20498-20503. doi:10.1002/anie.202107848http://dx.doi.org/10.1002/anie.202107848

Liu Y Z, Lei Y X, Li F, Chen J X, Liu M C, Huang X B, Gao W X, Wu H Y, Ding J C, Cheng Y X. J Mater Chem C, 2016, 4: 2862-2870. doi:10.1039/c5tc02932ehttp://dx.doi.org/10.1039/c5tc02932e

Baeg K J, Binda M, Natali D, Caironi M, Noh Y Y. Adv Mater, 2013, 25: 4267-4295. doi:10.1002/adma.201204979http://dx.doi.org/10.1002/adma.201204979

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