High Performance Near-infrared Organic Photodetectors Based on Narrow-bandgap Diketopyrrolopyrrole-based Polymer

Ming-cong Qin; Qing-yuan Li; Fan Zhang; Jun-hua Kuang; Kai Liu; Yan-wei Liu; Ming-liang Zhu; Zhi-yuan Zhao; Zhi-chao Pan; Yang-shuang Bian; Yun-long Guo; Yun-qi Liu

doi:10.11777/j.issn1000-3304.2021.21334

您当前的位置：

首页 >

文章列表页 >

High Performance Near-infrared Organic Photodetectors Based on Narrow-bandgap Diketopyrrolopyrrole-based Polymer

Research Article | 更新时间：2024-10-08

- High Performance Near-infrared Organic Photodetectors Based on Narrow-bandgap Diketopyrrolopyrrole-based Polymer
  增强出版
- ACTA POLYMERICA SINICA Vol. 53, Issue 4, Pages: 405-413(2022)
- 作者机构：
  
  1.北京分子科学国家研究中心中国科学院化学研究所有机固体院重点实验室北京 100190
  2.中国科学院大学北京 100049
- 作者简介：
  
  Yun-long Guo, E-mail: guoyunlong@iccas.ac.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2021.21334
  CLC：
- Published：20 April 2022，
  
  Published Online：19 January 2022，
  
  Received：01 November 2021，
  
  Revised：17 December 2021，
- 稿件说明：
移动端阅览
秦铭聪,李清源,张帆等.基于窄带系DPP类聚合物的高性能近红外有机光探测器件[J].高分子学报,2022,53(04):405-413.

Qin Ming-cong,Li Qing-yuan,Zhang Fan,et al.High Performance Near-infrared Organic Photodetectors Based on Narrow-bandgap Diketopyrrolopyrrole-based Polymer[J].ACTA POLYMERICA SINICA,2022,53(04):405-413.
秦铭聪,李清源,张帆等.基于窄带系DPP类聚合物的高性能近红外有机光探测器件[J].高分子学报,2022,53(04):405-413. DOI： 10.11777/j.issn1000-3304.2021.21334.

Qin Ming-cong,Li Qing-yuan,Zhang Fan,et al.High Performance Near-infrared Organic Photodetectors Based on Narrow-bandgap Diketopyrrolopyrrole-based Polymer[J].ACTA POLYMERICA SINICA,2022,53(04):405-413. DOI： 10.11777/j.issn1000-3304.2021.21334.

摘要

采用窄带隙给体材料DPPDTT和富勒烯衍生物受体PCBM共混作为活性层，制备了具有高激子分离和电荷传输效率的近红外有机光探测器件，并进一步采用窄带隙受体Y6代替PCBM制备一种“双窄带隙吸收”的异质结结构，在近红外区域的吸收叠加有效地增强了器件光响应能力. 最后，通过采用厚活性层、插入阻挡层以及制备倒置结构等方法，将器件的暗电流进一步降低1个数量级. 在850 nm，0.53 μW·cm

-2

的近红外光照射下，比探测率提升至8.28×10

Jones. 同时，随着测量频率的提升，器件响应的速度和强度几乎没有发生变化，在120帧/秒的条件下仍表现出很好的循环稳定性. 研究结果表明该类器件在光电通信、近红外成像以及医疗生理检测等方向具有良好的应用前景.

Abstract

High-performance near-infrared (NIR) organic photodetectors (OPDs) have widespread application prospects in artificial vision

biological imaging

flexible wearable electronic devices. Ascribed to high absorption coefficient and charge-carrier mobility

the narrow-bandgap polymer DPPDTT displayed a great potential for NIR OPDs. However

due to the nature of narrow bandgap and strong intermolecular interactions

the DPPDTT-based OPDs exhibit a low detectivity (

(

)). Here

we introduced PCBM as the acceptor material to construct bulk-heterojunction photodiodes

which improved the efficiency of exciton separation and charge transfer

so that the

(

) can be simultaneously enhanced. Moreover

when the narrow-bandgap acceptor Y6 is utilized instead of PCBM to afford a "double narrow-bandgap absorption" heterojunction structure

the superposition of absorption in the near-infrared region could effectively enhance the light response capability of devices. Finally

by adopting the inverted structure and inserting barrier layers

the dark current is further reduced by one order of magnitude

and the

(λ)

is increased to 8.28×10

Jones under 850 nm at a light irradiation of 0.53 μW·cm

-2

. With the increase of the measurement frequency

the response spe

ed and the

(

) of the device were kept at same value

and it still showed good cycle stability under the condition of 120 frames per second. Thus

the above results confirm that this type of device will show promising applications in photoelectric communication

NIR imaging

physiological testing

and so forth.

关键词

窄带系DPP类聚合物高性能二极管近红外有机光探测器

Keywords

Narrow-bandgap DPP-based polymerHigh performanceDiodeNear-infrared organic photodetectors

references

Simone G, Rasi D D C, Vries X D, Heintges G H L, Meskers S C J, Janssen R A J, Gelinck G H. Adv Mater, 2018, 30(51): e1804678. doi:10.1002/adma.201804678http://dx.doi.org/10.1002/adma.201804678

Mathieson K, Loudin J, Goetz G, Huie P, Wang L, Kamins T I, Galambos L, Smith R, Harris J S, Sher A, Palanker D. Nat Photonics, 2012, 6(6): 391-397. doi:10.1038/nphoton.2012.104http://dx.doi.org/10.1038/nphoton.2012.104

Wu Z, Zhai Y, Yao W, Eedugurala N, Zhang S, Huang L, Gu X, Azoulay J D, Ng T N. Adv Funct Mater, 2018, 28(50): 1805738. doi:10.1002/adfm.201805738http://dx.doi.org/10.1002/adfm.201805738

Li C, Wang H, Wang F, Li T, Xu M, Wang H, Wang Z, Zhan X, Hu W, Shen L. Light Sci Appl, 2020, 9(31): 1-8. doi:10.1038/s41377-020-0264-5http://dx.doi.org/10.1038/s41377-020-0264-5

Lochner C M, Khan Y, Pierre A, Arias A C. Nat Commun, 2014, 5(1): 5745. doi:10.1038/ncomms6745http://dx.doi.org/10.1038/ncomms6745

Park S, Fukuda K, Wang M, Lee C, Yokota T, Jin H, Jinno H, Kimura H, Zalar P, Matsuhisa N, Umezu S, Bazan G C, Someya T. Adv Mater, 2018, 30(34): e1802359. doi:10.1002/adma.201870252http://dx.doi.org/10.1002/adma.201870252

Bilgaiyan A, Elsamnah F, Ishidai H, Shim C H, Misran M A B, Adachi C, Hattori R. ACS Appl Electron Mater, 2020, 2(5): 1280-1288. doi:10.1021/acsaelm.0c00082http://dx.doi.org/10.1021/acsaelm.0c00082

Siegmund B, Mischok A, Benduhn J, Zeika O, Ullbrich S, Nehm F, Bȍhm M, Spoltore D, Frȍb H, Kȍrner C, Leo K, Vandewal K. Nat Commun, 2017, 8: 15421. doi:10.1038/ncomms15421http://dx.doi.org/10.1038/ncomms15421

Tang Z, Ma Z, Sánchez-Díaz A, Ullbrich S, Liu Y, Siegmund B, Mischok A, Leo K, Campoy-Quiles M, Li W, Vandewal K. Adv Mater, 2017, 29(33): 1702184. doi:10.1002/adma.201702184http://dx.doi.org/10.1002/adma.201702184

Li Q, Guo Y, Liu Y. Chem Mater, 2019, 31(17): 6359-6379. doi:10.1021/acs.chemmater.9b00966http://dx.doi.org/10.1021/acs.chemmater.9b00966

Baeg K J, Binda M, Natali D, Caironi M, Noh Y Y. Adv Mater, 2013, 25(31): 4267-4295. doi:10.1002/adma.201204979http://dx.doi.org/10.1002/adma.201204979

Huang Fei(黄飞), Bo Zhishan(薄志山), Geng Yanhou(耿延候), Wang Xianhong(王献红), Wang Lixiang(王利祥), Ma Yuguang(马於光), Hou Jinahui(侯剑辉), Hu Wenping(胡文平), Pei Jian(裴坚), Dong Huanli(董焕丽), Wang Shu(王树), Li Zhen(李振), Shuai Zhigang(帅志刚), Li Yingfang(李永舫), Cao Yong(曹镛). Acta Polymerica Sinica(高分子学报), 2019, 50(10): 988-1046. doi:10.11777/j.issn1000-3304.2019.19110http://dx.doi.org/10.11777/j.issn1000-3304.2019.19110

Yang K, Wang J, Zhao Z, Zhou Z, Liu M, Zhang J, He Z, Zhang F. ACS Appl Mater Inter, 2021, 13(18): 21565-21572. doi:10.1021/acsami.1c06486http://dx.doi.org/10.1021/acsami.1c06486

Yang K, Zhao Z, Liu M, Zhou Z, Wang K, Ma X, Wang J, He Z, Zhang F. Chem Eng J, 2022, 427: 131802. doi:10.1016/j.cej.2021.131802http://dx.doi.org/10.1016/j.cej.2021.131802

Yang C M, Tsai P Y, Horng S F, Lee K C, Tzeng S R, Meng H F, Shy J T, Shu C F. Appl Phys Lett, 2008, 92(8): 083504. doi:10.1063/1.2839397http://dx.doi.org/10.1063/1.2839397

Arca F, Sramek M, Tedde S F, Lugli P, Hayden O. IEEE J Quantum Elect, 2013, 49(12): 1016-1025. doi:10.1109/jqe.2013.2285158http://dx.doi.org/10.1109/jqe.2013.2285158

Mischok A, Siegmund B, Ghosh D S, Benduhn J, Spoltore D, Böhm M, Fröb H, Körner C, Leo K. ACS Photonics, 2017, 4(9): 2228-2234. doi:10.1021/acsphotonics.7b00427http://dx.doi.org/10.1021/acsphotonics.7b00427

Yazmaciyan A, Meredith P, Armin A. Adv Opt Mater, 2019, 7(8): 1801543. doi:10.1002/adom.201801543http://dx.doi.org/10.1002/adom.201801543

Armin A, Jansen-van Vuuren R D, Kopidakis N, Burn P L, Meredith P. Nat Commun, 2015, 6(1): 1-8. doi:10.1038/ncomms7343http://dx.doi.org/10.1038/ncomms7343

Xie B, Xie R, Zhang K, Yin Q, Hu Z, Yu G, Huang F, Cao Y. Nat Commun, 2020, 11(1): 2871. doi:10.1038/s41467-020-16675-xhttp://dx.doi.org/10.1038/s41467-020-16675-x

Li W, Xu Y, Meng X, Xiao Z, Li R, Jiang L, Cui L, Zheng M, Liu C, Ding L, Lin Q. Adv Funct Mater, 2019, 29(20): 1808948. doi:10.1002/adfm.201808948http://dx.doi.org/10.1002/adfm.201808948

Lan Z, Lei Y, Chan W K E, Chen S, Luo D, Zhu F. Sci Adv, 2020, 6(5): eaaw8065. doi:10.1126/sciadv.aaw8065http://dx.doi.org/10.1126/sciadv.aaw8065

Yi Z, Wang S, Liu Y. Adv Mater, 2015, 27(24): 3589-3606. doi:10.1002/adma.201500401http://dx.doi.org/10.1002/adma.201500401

Li J, Zhao Y, Tan H S, Guo Y, Di C A, Yu G, Liu Y, Lin M, Lim S H, Zhou Y, Su H, Ong B S. Sci Rep, 2012, 2: 754. doi:10.1038/srep00754http://dx.doi.org/10.1038/srep00754

Liu S, You P, Li J, Li J, Lee C S, Ong B S, Surya C, Yan F. Energ Environ Sci, 2015, 8(5): 1463-1470. doi:10.1039/c5ee00090dhttp://dx.doi.org/10.1039/c5ee00090d

Sun Y n, Lv Y, Han P, Li K, Liang Y, Duan Y, Zhang H, Geng H, Zhang Y, Fu H, Liao Y. Sol Energy Mater Sol Cells, 2020, 215: 110684. doi:10.1016/j.solmat.2020.110684http://dx.doi.org/10.1016/j.solmat.2020.110684

Li Q, Ran Y, Shi W, Qin M, Sun Y, Kuang J, Wang H, Chen H, Guo Y, Liu Y. Appl Mater Today, 2021, 22: 100899. doi:10.1016/j.apmt.2020.100899http://dx.doi.org/10.1016/j.apmt.2020.100899

Yuan J, Zhang Y, Zhou L, Zhang G, Yip H L, Lau T K, Lu X, Zhu C, Peng H, Johnson P A, Leclerc M, Cao Y, Ulanski J, Li Y, Zou Y. Joule, 2019, 3(4): 1140-1151. doi:10.1016/j.joule.2019.01.004http://dx.doi.org/10.1016/j.joule.2019.01.004

Simone G, Dyson M J, Weijtens C H L, Meskers S C J, Coehoorn R, Janssen R A J, Gelinck G H. Adv Opt Mater, 2019, 8(1): 1901568. doi:10.1002/adom.201901568http://dx.doi.org/10.1002/adom.201901568

Zhong Wenkai(钟文楷), Xie Ruihao(谢锐浩), Ying Lei(应磊), Huang Fei(黄飞), Cao Yong(曹镛). Acta Polymerica Sinica(高分子学报), 2018, (2): 217-222. doi:10.11777/j.issn1000-3304.2018.17242http://dx.doi.org/10.11777/j.issn1000-3304.2018.17242

Gao Shijia(高诗佳), Wang Xin(王鑫), Zhang Yulin(张育林), Zhang Sai(张赛), Qiao Wenqiang(乔文强), Wang Zhiyuan(王植源). Acta Polymerica Sinica(高分子学报), 2020, 51(4): 338-345. doi:10.11777/j.issn1000-3304.2019.19206http://dx.doi.org/10.11777/j.issn1000-3304.2019.19206

Geng Yue(耿悦), Gao Hanfei(高寒飞), Wu Yuchen(吴雨辰), Jiang Lei(江雷). Acta Polymerica Sinica(高分子学报), 2020, 51(5): 421-433. doi:10.11777/j.issn1000-3304.2020.19218http://dx.doi.org/10.11777/j.issn1000-3304.2020.19218

Xia K, Li Y, Wang Y, Portilla L, Pecunia V. Adv Opt Mater, 2020, 8(8): 1902056. doi:10.1002/adom.201902056http://dx.doi.org/10.1002/adom.201902056

Han J, Qi J, Zheng X, Wang Y, Hu L, Guo C, Wang Y, Li Y, Ma D, Qiao W, Wang Z Y. J Mater Chem C, 2017, 5(1): 159-165. doi:10.1039/c6tc05031jhttp://dx.doi.org/10.1039/c6tc05031j

Armin A, Hambsch M, Kim I K, Burn P L, Meredith P, Namdas E B. Laser Photonics Rev, 2014, 8(6): 924-932. doi:10.1002/lpor.201400081http://dx.doi.org/10.1002/lpor.201400081

Strobel N, Seiberlich M, Rodlmeier T, Lemmer U, Hernandez-Sosa G. ACS Appl Mater Interfaces, 2018, 10(49): 42733-42739. doi:10.1021/acsami.8b16018http://dx.doi.org/10.1021/acsami.8b16018

Liu X, Lin Y, Liao Y, Wu J, Zheng Y. J Mater Chem C, 2018, 6(14): 3499-3513. doi:10.1039/c7tc05042ahttp://dx.doi.org/10.1039/c7tc05042a

Views

236

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

High Performance Ambipolar Polymer Semiconductors and Transistors

HIGH PERFORMANCE AND FUNCTIONALITY MODIFICATION OF ELASTOMER MATERIALS

Related Author

Yun-long Guo

MING Tian

JIAN Yang

Hai-lan Kang

DAN Yang

XUE Bai

Li-qun Zhang

Related Institution

Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences

College of Materials Science and Engineering, Beijing University of Chemical Technology Beijing

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰