Amino Acid-based Dithiolactone Monomers towards Chemically Recyclable Polymers

Yi-nuo Zhu; You-hua Tao

doi:10.11777/j.issn1000-3304.2022.22102

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Amino Acid-based Dithiolactone Monomers towards Chemically Recyclable Polymers

Feature Article | 更新时间：2024-10-08

- Amino Acid-based Dithiolactone Monomers towards Chemically Recyclable Polymers
- ACTA POLYMERICA SINICA Vol. 53, Issue 9, Pages: 1023-1031(2022)
- 作者机构：
  
  中国科学院长春应用化学研究所中国科学院生态环境高分子材料重点实验室　长春 130022
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2022.22102
  CLC：
- Published：20 September 2022，
  
  Published Online：07 July 2022，
  
  Received：29 March 2022，
  
  Accepted：18 May 2022
- 稿件说明：
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朱忆诺,陶友华.基于氨基酸基交硫酯单体的闭环回收高分子[J].高分子学报,2022,53(09):1023-1031.

Zhu Yi-nuo,Tao You-hua.Amino Acid-based Dithiolactone Monomers towards Chemically Recyclable Polymers[J].ACTA POLYMERICA SINICA,2022,53(09):1023-1031.
朱忆诺,陶友华.基于氨基酸基交硫酯单体的闭环回收高分子[J].高分子学报,2022,53(09):1023-1031. DOI： 10.11777/j.issn1000-3304.2022.22102.

Zhu Yi-nuo,Tao You-hua.Amino Acid-based Dithiolactone Monomers towards Chemically Recyclable Polymers[J].ACTA POLYMERICA SINICA,2022,53(09):1023-1031. DOI： 10.11777/j.issn1000-3304.2022.22102.

摘要

发展闭环回收高分子被认为是解决塑料污染问题和发展循环经济的最佳选择，该方法通过设计特定的单体合成高分子材料，再将其直接转化为原单体，从而实现资源循环和同级使用. 近年来，中国学者在可闭环回收的聚酯及聚硫酯的合成方面取得了一系列重要进展. 尽管如此，“理想单体”的设计以及聚合物的使用性能始终是制约闭环回收高分子进一步发展的主要因素. 我们课题组提出氨基酸来源的交硫酯单体可以作为一类“理想单体”用于闭环回收高分子. 交硫酯单体在热力学上更有利于成环，在动力学上更有利于开环聚合，从而成功地将2种看似矛盾的性质结合到一种单体上，使交硫酯单体更容易合成、更容易聚合、其聚合物也更容易实现闭环回收. 特别是来源于缬氨酸的异丙基交硫酯的开环聚合，所得聚合产物具有无规但是结晶的不同寻常的特性. 相信进一步发展氨基酸基交硫酯单体的高效成环和可控聚合，将为闭环回收高分子的大规模制备和应用奠定基础.

Abstract

Developing chemically recyclable polymers represents a greener alternative to landfill and incineration and offers a closed-loop strategy toward a circular materials economy. Although some progress has been achieved in the synthesis of closed-loop recycled polymers

the synthesis of chemically recyclable polymers is still plagued with certain fundamental limitations

including trade-offs between the monomer's cyclizability and polymerizability

as well as between polymer's depolymerizability and properties. Very recently

our research group has proposed that amino acid-based dithiolactone monomers is a kind of "ideal monomer" for chemically recyclable polymers. These dithiolactone monomers demonstrate appealing chemical properties different from those of dilactone

including accelerated ring closure

augmented kinetics polymerizability

high depolymerizability and selectivity

and thus constitute a unique class of polythioester materials exhibiting controlled molecular weight (up to 100.5 kDa)

atactic yet high crystallinity

structurally diversity

and chemical recyclability. In particular

the ring-opening polymerization of isopropyl dithiolactone derived from valine

delivered atactic yet crystalline polythioester. These amino acid-based chemically recyclable plastics show promise as next-generation sustainable materials.

关键词

闭环回收高分子氨基酸交硫酯聚硫酯开环聚合

Keywords

Chemically recyclable polymersAmino acidsDithiolactonePolythioestersRing-opening polymerization

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