Synthesis, Structure and Properties of Isobutylene Oxide-CO<sub>2</sub> Copolymer

Xiao-han Cao; Jun-qi Lv; Jia Zhao; Cheng-jian Zhang; Yue Sun; Qing-lei Yu; Jia-xiang Hou; Xing-hong Zhang

doi:10.11777/j.issn1000-3304.2022.22109

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Synthesis, Structure and Properties of Isobutylene Oxide-CO₂ Copolymer

Research Article | 更新时间：2024-10-08

- Synthesis, Structure and Properties of Isobutylene Oxide-CO₂ Copolymer
- ACTA POLYMERICA SINICA Vol. 53, Issue 9, Pages: 1104-1111(2022)
- 作者机构：
  
  1.浙江大学，车用生物燃料技术国家重点实验室高分子新物质创制国际研究中心高分子科学与工程学系，东营 257000
  2.浙江大学，化学前瞻技术研究中心杭州 310027
  3.浙江大学，山东石大胜华化工集团股份有限公司，东营 257000
- 作者简介：
  
  Xing-hong Zhang, E-mail: xhzhang@zju.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2022.22109
  CLC：
- Published：20 September 2022，
  
  Published Online：14 July 2022，
  
  Received：01 April 2022，
  
  Accepted：07 May 2022
- 稿件说明：
移动端阅览
曹晓瀚,吕俊奇,赵佳等.氧化异丁烯与CO₂共聚物的合成及其结构与性能[J].高分子学报,2022,53(09):1104-1111.

Cao Xiao-han,Lv Jun-qi,Zhao Jia,et al.Synthesis, Structure and Properties of Isobutylene Oxide-CO₂ Copolymer[J].ACTA POLYMERICA SINICA,2022,53(09):1104-1111.
曹晓瀚,吕俊奇,赵佳等.氧化异丁烯与CO₂共聚物的合成及其结构与性能[J].高分子学报,2022,53(09):1104-1111. DOI： 10.11777/j.issn1000-3304.2022.22109.

Cao Xiao-han,Lv Jun-qi,Zhao Jia,et al.Synthesis, Structure and Properties of Isobutylene Oxide-CO₂ Copolymer[J].ACTA POLYMERICA SINICA,2022,53(09):1104-1111. DOI： 10.11777/j.issn1000-3304.2022.22109.

摘要

氧化异丁烯(IBO)是石化行业重要C4产品异丁烯的衍生物. 将IBO与二氧化碳(CO

)共聚制备脂肪族聚碳酸酯，是一条高附加值利用异丁烯和CO

的可行途径，但迄今仅有零星的研究报道. 本文采用非均相的锌-钴双金属氰化络合物(Zn-Co DMCC)在40 ℃的反应温度下催化IBO与CO

共聚，催化效率高达1.6 kg共聚物/g催化剂，所得产物聚碳酸亚丁酯(PIBC)具有全交替序列结构，区域规整度高达95%，数均分子量达18.6 kDa. 特别的，PIBC为结晶性高分子，熔点高达93.7 ℃，初始热分解温度仅为145 ℃. PIBC的拉伸强度达4.4 MPa，断裂伸长率达350%，因此PIBC有望应用于牺牲型粘接剂. 另外，Zn-Co DMCC也能催化CO

、IBO与马来酸酐共聚，得到了具有全交替结构的三元共聚物. 研究结果为异丁烯的应用开拓了一条可持续发展的新路径.

Abstract

$.abstracts[1]

关键词

二氧化碳聚碳酸酯氧化异丁烯马来酸酐结晶高分子

Keywords

Carbon dioxidePolycarbonateIsobutene oxideMaleic anhydrideCrystalline polymer

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Synthesis, Structure and Properties of Isobutylene Oxide-CO2 Copolymer

DOI：10.11777/j.issn1000-3304.2022.22109

摘要

Abstract

关键词

Keywords

references

Synthesis, Structure and Properties of Isobutylene Oxide-CO₂ Copolymer