Bimodal Polymer-grafted Nanoparticles with Precisely Controlled Structures

Hua-lin Ou; Bao-qing Zhang; Chen-yang Liu

doi:10.11777/j.issn1000-3304.2022.22110

您当前的位置：

首页 >

文章列表页 >

Bimodal Polymer-grafted Nanoparticles with Precisely Controlled Structures

Research Article | 更新时间：2024-10-08

- Bimodal Polymer-grafted Nanoparticles with Precisely Controlled Structures
- ACTA POLYMERICA SINICA Vol. 53, Issue 11, Pages: 1388-1398(2022)
- 作者机构：
  
  1.中国科学院化学研究所北京分子科学国家研究中心中国科学院工程塑料重点实验室北京 100190
  2.中国科学院大学北京 100049
- 作者简介：
  
  Chen-yang Liu, E-mail: liucy@iccas.ac.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2022.22110
  CLC：
- Published：20 November 2022，
  
  Published Online：23 August 2022，
  
  Received：03 April 2022，
  
  Accepted：18 May 2022
- 稿件说明：
移动端阅览
欧华林,张宝庆,刘琛阳.结构可控的聚合物长短刷接枝纳米粒子[J].高分子学报,2022,53(11):1388-1398.

Ou Hua-lin,Zhang Bao-qing,Liu Chen-yang.Bimodal Polymer-grafted Nanoparticles with Precisely Controlled Structures[J].ACTA POLYMERICA SINICA,2022,53(11):1388-1398.
欧华林,张宝庆,刘琛阳.结构可控的聚合物长短刷接枝纳米粒子[J].高分子学报,2022,53(11):1388-1398. DOI： 10.11777/j.issn1000-3304.2022.22110.

Ou Hua-lin,Zhang Bao-qing,Liu Chen-yang.Bimodal Polymer-grafted Nanoparticles with Precisely Controlled Structures[J].ACTA POLYMERICA SINICA,2022,53(11):1388-1398. DOI： 10.11777/j.issn1000-3304.2022.22110.

摘要

通过RAFT聚合制备了一系列窄分子量分布的聚(γ-甲基丙烯酰氧基丙基三乙氧基硅烷)(PTEPM)-

-聚甲基丙烯酸甲酯(PMMA)嵌段共聚物和PTEPM、PMMA低聚物. 将具有不同PMMA分子量的2种PTEPM-

-PMMA共聚物与低聚物PMMA或PTEPM进行共组装(微相分离)，形成片、柱、球等不同PTEPM相区结构. 采用盐酸气氛处理，PTEPM相区水解交联形成倍半硅氧烷SiO

1.5

内核，分离纯化得到聚合物长短刷接枝纳米粒子.使用这种相分离-交联-分散制备方法，调节嵌段共聚物分子结构和三组分比例，可实现聚合物接枝纳米粒子内核形状和尺寸、接枝密度、长短刷比例、长刷长度的精确调控. 这些纳米粒子是研究聚合物纳米复合材料结构-性能关系的理想模型体系.

Abstract

A series of poly(3-(triethoxysilyl)propyl methacrylate) (PTEPM) oligomers (oT)

polymethylmethacrylate (PMMA) oligomers (oM)

and block copolymers of PTEPM-

-PMMA with narrow molecular weight distributions were synthesized using RAFT polymerization. Two PTEPM-

-PMMA copolymers with the PMMA blocks of different molecular weights were co-assembled with the oligomers of PMMA or PTEPM to form various ordered nanoscale

structures

such as lamellae

cylinders

and spheres. PTEPM block could be crosslinked to form silsesquioxane core (

i.e.

SiO

1.5

)

when the obtained co-assembly materials were immersed in hydrochloric acid atmosphere. After appropriate separation and purification

the bimodal polymer grafted nanoparticles (PGNPs) with different microstructures could be prepared. Using this assembling-crosslinking-dispersing (ACD) method and adjusting the molecular structure of block copolymer and the ratio of the three components (PTEPM-

-PMMA

and oM)

the structural parameters of bimodal PGNPs

including the shape and size of core

grafting density

molar ratio between long and short brushes

and length of long brushes

could be precisely controlled. By adjusting the proportions of two block copolymers with the PMMA blocks of different molecular weights and the amounts of oMs

bimodal PGNPs with different molar ratios of long and short brushes could be prepared. By adjusting the molecular weight of the long brush and the amounts of oM

bimodal PGNPs with different lengths of long brushes were obtained. By adjusting the amounts of oM and oT

bimodal PGNPs with the same core shape but different sizes were obtained. By adjusting the amounts of oM

bimodal PGNPs with the same core weight but different shapes (cylindrical or spherical) were obtained. These nanoparticles are ideal model models for studying the relationship between the microstructures and properties of polymer nanocomposites.

关键词

嵌段共聚物聚合物接枝纳米粒子二氧化硅双分布刷

Keywords

Block copolymerPolymer grafted nanoparticlesSilica dioxideBimodal brushes

references

Gilman J. Appl Clay Sci, 1999, 15: 31-49. doi:10.1016/s0169-1317(99)00019-8http://dx.doi.org/10.1016/s0169-1317(99)00019-8

Winey K I, Kashiwagi T, Mu M. MRS Bulletin, 2007, 32(4): 348-353. doi:10.1557/mrs2007.234http://dx.doi.org/10.1557/mrs2007.234

Choudalakis G, Gotsis A. Eur Polym J, 2009, 45(4): 967-984. doi:10.1016/j.eurpolymj.2009.01.027http://dx.doi.org/10.1016/j.eurpolymj.2009.01.027

Kumar S K, Jouault N, Benicewicz B, Neely T. Macromolecules, 2013, 46(9): 3199-3214. doi:10.1021/ma4001385http://dx.doi.org/10.1021/ma4001385

Hashemi A, Jouault N, Williams G A, Zhao D, Cheng K J, Kysar J W, Guan Z, Kumar S K. Nano Lett, 2015, 15(8): 5465-5471. doi:10.1021/acs.nanolett.5b01859http://dx.doi.org/10.1021/acs.nanolett.5b01859

Zhao D, Ge S, Senses E, Akcora P, Jestin J, Kumar S K. Macromolecules, 2015, 48(15): 5433-5438. doi:10.1021/acs.macromol.5b00962http://dx.doi.org/10.1021/acs.macromol.5b00962

Li Shaofan(李少范), Wen Xiangning(温向宁), Ju Weilong(鞠维龙), Su Yunlan(苏允兰), Wang Dujin(王笃金). Acta Polymerica Sinica(高分子学报), 2021, 52(2): 146-157. doi:10.11777/j.issn1000-3304.2020.20189http://dx.doi.org/10.11777/j.issn1000-3304.2020.20189

Hu S N, Lin Y, Wu G Z. Chinese J Polym Sci, 2020, 38(1): 100-108. doi:10.1007/s10118-019-2300-6http://dx.doi.org/10.1007/s10118-019-2300-6

Pandey Y N, Papakonstantopoulos G J, Doxastakis M. Macromolecules, 2013, 46(13): 5097-5106. doi:10.1021/ma400444whttp://dx.doi.org/10.1021/ma400444w

Li C, Benicewicz B C. Macromolecules, 2005, 38(14): 5929-5936. doi:10.1021/ma050216rhttp://dx.doi.org/10.1021/ma050216r

Li C, Han J, Ryu C Y, Benicewicz B C. Macromolecules, 2006, 39(9): 3175-3183. doi:10.1021/ma051983thttp://dx.doi.org/10.1021/ma051983t

Barbey R, Lavanant L, Paripovic D, Schuwer N, Sugnaux C, Tugulu S, Klok H A. Chem Rev, 2009, 109(11): 5437-5527. doi:10.1021/cr900045ahttp://dx.doi.org/10.1021/cr900045a

Akcora P, Liu H, Kumar S K, Moll J, Li Y, Benicewicz B C, Schadler L S, Acehan D, Panagiotopoulos A Z, Pryamitsyn V, Ganesan V, Ilavsky J, Thiyagarajan P, Colby R H, Douglas J F. Nat Mater, 2009, 8(4): 354-359. doi:10.1038/nmat2404http://dx.doi.org/10.1038/nmat2404

Sunday D, Ilavsky J, Green D L. Macromolecules, 2012, 45(9): 4007-4011. doi:10.1021/ma300438ghttp://dx.doi.org/10.1021/ma300438g

Green D L, Mewis J. Langmuir, 2006, 22(23): 9546-9553. doi:10.1021/la061136zhttp://dx.doi.org/10.1021/la061136z

Harton S E, Kumar S K. J Polym Sci, Part B: Polym Phys, 2008, 46(4): 351-358. doi:10.1002/polb.21346http://dx.doi.org/10.1002/polb.21346

Ganesan V, Ellison C J, Pryamitsyn V. Soft Matter, 2010, 6(17): 4010-4025. doi:10.1039/b926992dhttp://dx.doi.org/10.1039/b926992d

Meng D, Kumar S K, Lane J M D, Grest G S. Soft Matter, 2012, 8(18): 5002-5010. doi:10.1039/c2sm07395ahttp://dx.doi.org/10.1039/c2sm07395a

Martin T B, Jayaraman A. Macromolecules, 2013, 46(22): 9144-9150. doi:10.1021/ma401763yhttp://dx.doi.org/10.1021/ma401763y

Jayaraman A. J Polym Sci, Part B: Polym Phys, 2013, 51(7): 524-534. doi:10.1002/polb.23260http://dx.doi.org/10.1002/polb.23260

Martin T B, Jayaraman A. J Polym Sci, Part B: Polym Phys, 2014, 52(24): 1661-1668. doi:10.1002/polb.23517http://dx.doi.org/10.1002/polb.23517

Shi D W, Lai X L, Jiang Y P, Yan C, Liu Z Y, Yang W, Yang M B. Chinese J Polym Sci, 2019, 37(3): 216-226. doi:10.1007/s10118-019-2191-6http://dx.doi.org/10.1007/s10118-019-2191-6

Mansoori Y, Roojaei K, Zamanloo M R, Imanzadeh G. Chinese J Polym Sci, 2012, 30(6): 815-823. doi:10.1007/s10118-012-1188-1http://dx.doi.org/10.1007/s10118-012-1188-1

Tsujii Y, Ohno K, Yamamoto S, Goto A, Fukuda T. Surface-Initiated Polymerization I. “Berlin, Heidelberg: Springer,” 2006. 1-45. doi:10.1007/12_063http://dx.doi.org/10.1007/12_063

Hui C M, Pietrasik J, Schmitt M, Mahoney C, Choi J, Bockstaller M R, Matyjaszewski K. Chem Mater, 2014, 26(1): 745-762. doi:10.1021/cm4023634http://dx.doi.org/10.1021/cm4023634

Lin H C, Li C C, Lee J T. J Power Sources, 2011, 196(19): 8098-8103. doi:10.1016/j.jpowsour.2011.05.037http://dx.doi.org/10.1016/j.jpowsour.2011.05.037

Tao P, Li Y, Rungta A, Viswanath A, Gao J, Benicewicz B C, Siegel R W, Schadler L S. J Mater Chem, 2011, 21(46): 18623-18629. doi:10.1039/c1jm13093ehttp://dx.doi.org/10.1039/c1jm13093e

Lindenblatt G, Schärtl W, Pakula T, Schmidt M. Macromolecules, 2000, 33(25): 9340-9347. doi:10.1021/ma001328fhttp://dx.doi.org/10.1021/ma001328f

Blencowe A, Tan J F, Goh T K, Qiao G G. Polymer, 2009, 50(1): 5-32. doi:10.1016/j.polymer.2008.09.049http://dx.doi.org/10.1016/j.polymer.2008.09.049

Gao H, Matyjaszewski K. Prog Polym Sci, 2009, 34(4): 317-350. doi:10.1016/j.progpolymsci.2009.01.001http://dx.doi.org/10.1016/j.progpolymsci.2009.01.001

Gao H, Ohno S, Matyjaszewski K. J Am Chem Soc, 2006, 128(47): 15111-15113. doi:10.1021/ja066964thttp://dx.doi.org/10.1021/ja066964t

Gao H, Matyjaszewski K. Macromolecules, 2007, 40(3): 399-401. doi:10.1021/ma062640dhttp://dx.doi.org/10.1021/ma062640d

Qiao Y, Yin X, Wang L, Islam M S, Benicewicz B C, Ploehn H J, Tang C. Macromolecules, 2015, 48(24): 8998-9006. doi:10.1021/acs.macromol.5b02018http://dx.doi.org/10.1021/acs.macromol.5b02018

Rungta A, Natarajan B, Neely T, Dukes D, Schadler L S, Benicewicz B C. Macromolecules, 2012, 45(23): 9303-9311. doi:10.1021/ma3018876http://dx.doi.org/10.1021/ma3018876

Yan J, Kristufek T, Schmitt M, Wang Z, Xie G, Dang A, Hui C M, Pietrasik J, Bockstaller M R, Matyjaszewski K. Macromolecules, 2015, 48(22): 8208-8218. doi:10.1021/acs.macromol.5b01905http://dx.doi.org/10.1021/acs.macromol.5b01905

Bates F S, Fredrickson G H. Phys Today, 1999, 52(2): 32-38. doi:10.1063/1.882522http://dx.doi.org/10.1063/1.882522

Zhang K, Gao L, Chen Y. Macromolecules, 2007, 40(16): 5916-5922. doi:10.1021/ma070780xhttp://dx.doi.org/10.1021/ma070780x

Zhang K, Gao L, Chen Y. Macromolecules, 2008, 41(5): 1800-1807. doi:10.1021/ma7021698http://dx.doi.org/10.1021/ma7021698

Chen Y. Macromolecules, 2012, 45(6): 2619-2631. doi:10.1021/ma201495mhttp://dx.doi.org/10.1021/ma201495m

Tanaka H, Hashimoto T. Macromolecules, 1991, 24(20): 5713-5720. doi:10.1021/ma00020a035http://dx.doi.org/10.1021/ma00020a035

Koizumi S, Hasegawa H, Hashimoto T. Macromolecules, 1994, 27(22): 6532-6540. doi:10.1021/ma00100a044http://dx.doi.org/10.1021/ma00100a044

Koizumi S, Hasegawa H, Hashimoto T. Macromolecules, 1994, 27(26): 7893-7906. doi:10.1021/ma00104a053http://dx.doi.org/10.1021/ma00104a053

Hashimoto T, Koizumi S, Hasegewa H. Physica B: Condens Matter, 1995, 213676-681

Bodycomb J, Yamaguchi D, Hashimoto T. Macromolecules, 2000, 33(14): 5187-5197. doi:10.1021/ma9917996http://dx.doi.org/10.1021/ma9917996

Ruan Y, Gao L, Yao D, Zhang K, Zhang B, Chen Y, Liu C Y. ACS Macro Lett, 2015, 4(10): 1067-1071. doi:10.1021/acsmacrolett.5b00408http://dx.doi.org/10.1021/acsmacrolett.5b00408

Views

104

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Dissipative Particle Dynamics Simulation of Self-assembly of Regio-isomeric Cage-type Amphiphiles in Bulk

Synthesis of Self-demulsification Thermosensitive Polymeric Surfactants and Their Application in Emulsion Polymerization

Stimuli Responsive Nano-objects via Polymerization Induced Self-assembly

Related Author

Ming-hu Xu

Qing-liang Song

Mei-jiao Liu

Cheng-tao Tang

Lin-xi Hou

Long-qiang Xiao

Hao-wei Zhang

Wen-jian Han

Related Institution

State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University

Key Laboratory of Surface & Interface Science of Polymer Materials of Zhejiang Province, School of Chemistry and Chemical Engineering, Zhejiang Sci-Tech University

College of Chemical Engineering, Fuzhou University

College of Materials Science and Engineering, Nanjing Tech University

State Key Laboratory of Materials-Oriented Chemical Engineering

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰