Recent Research Progress on Controlling the Assembly Process <italic style="font-style: italic">via</italic> Solvent Recrystallization

Qing-rui Fan; Jun-qiang Mao; Jian-jun Wang

doi:10.11777/j.issn1000-3304.2022.22156

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Recent Research Progress on Controlling the Assembly Process via Solvent Recrystallization

Review | 更新时间：2024-10-08

- Recent Research Progress on Controlling the Assembly Process via Solvent Recrystallization
- ACTA POLYMERICA SINICA Vol. 53, Issue 11, Pages: 1316-1323(2022)
- 作者机构：
  
  中国科学院化学研究所北京 100190
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2022.22156
  CLC：
- Published：20 November 2022，
  
  Published Online：26 August 2022，
  
  Received：29 April 2022，
  
  Accepted：31 May 2022
- 稿件说明：
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范庆瑞,毛俊强,王健君.调控分子组装过程的研究进展[J].高分子学报,2022,53(11):1316-1323.

Fan Qing-rui,Mao Jun-qiang,Wang Jian-jun.Recent Research Progress on Controlling the Assembly Process via Solvent Recrystallization[J].ACTA POLYMERICA SINICA,2022,53(11):1316-1323.
范庆瑞,毛俊强,王健君.调控分子组装过程的研究进展[J].高分子学报,2022,53(11):1316-1323. DOI： 10.11777/j.issn1000-3304.2022.22156.

Fan Qing-rui,Mao Jun-qiang,Wang Jian-jun.Recent Research Progress on Controlling the Assembly Process via Solvent Recrystallization[J].ACTA POLYMERICA SINICA,2022,53(11):1316-1323. DOI： 10.11777/j.issn1000-3304.2022.22156.

摘要

生命系统通过精确地调控组装过程，根据实际需求将有限的原料组装成具有不同聚集结构的材料，极大地丰富了材料的形式与功能. 对分子组装的热力学环境与动力学聚集速率进行独立且精确地调控，是组装得到各种功能材料的关键. 本文简单介绍了本课题组利用溶剂重结晶策略，通过控制重结晶的温度及温度变化率在精确控制溶剂分子组装过程方面的研究进展.

Abstract

Living systems have the capacity to effectively regulate the assembly of molecules into natural materials with outstanding functionalities

via

controlling the assembly process. Inspired by nature

great efforts have recently been focused on controlling the assembly process

ot only enriching materials formats

but also assisting further understand the complex assembly mechanisms. In this review

we firstly introduce the current considerable progresses

via

tuning the assembly process

as well as illustrating that the reported strategies are insufficient to regulate precisely the assembly process because it is difficult to independently control the thermodynamics of assembly and molecular assembly rates. Then we summarize our recent research progress on precise controlling the molecular assembly process

via

a novel method

solvent recrystallization. The two key parameters

recrystallization temperature and temperature change rate

can independently control the assembly thermodynamic environment and molecular aggregation rates. Thus

the same assembly units including small molecules and polymers can be assembled into desired materials with controllable sizes and adjustable molecular packings.

关键词

分子自组装溶剂重结晶组装过程

Keywords

Molecular self-assemblySolvent recrystallizationAssembly process

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Recent Research Progress on Controlling the Assembly Process via Solvent Recrystallization

DOI：10.11777/j.issn1000-3304.2022.22156

摘要

Abstract

关键词

Keywords

references