Synthesis of Biodegradable Polymers by "One Pot" Depolymerization and Polycondensation of PET

Hong-ming Zhang; Jun-yu Zhao; Feng-xiang Gao; Shun-jie Liu; Qing-hai Zhou; Xian-hong Wang

doi:10.11777/j.issn1000-3304.2022.22167

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Synthesis of Biodegradable Polymers by "One Pot" Depolymerization and Polycondensation of PET

Research Article | 更新时间：2024-10-08

- Synthesis of Biodegradable Polymers by "One Pot" Depolymerization and Polycondensation of PET
  增强出版
- ACTA POLYMERICA SINICA Vol. 53, Issue 9, Pages: 1142-1149(2022)
- 作者机构：
  
  中国科学院长春应用化学研究所中国科学院生态环境高分子材料实验室长春 130022
- 作者简介：
  
  Shun-jie Liu, E-mail: sjliu@ciac.ac.cn
  Xian-hong WangE-mail: xhwang@ciac.ac.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2022.22167
  CLC：
- Published：20 September 2022，
  
  Published Online：15 August 2022，
  
  Received：05 May 2022，
  
  Accepted：06 July 2022
- 稿件说明：
移动端阅览
张红明,赵君宇,高凤翔等.PET的解聚-共缩聚“一锅法”合成生物降解高分子的研究[J].高分子学报,2022,53(09):1142-1149.

Zhang Hong-ming,Zhao Jun-yu,Gao Feng-xiang,et al.Synthesis of Biodegradable Polymers by "One Pot" Depolymerization and Polycondensation of PET[J].ACTA POLYMERICA SINICA,2022,53(09):1142-1149.
张红明,赵君宇,高凤翔等.PET的解聚-共缩聚“一锅法”合成生物降解高分子的研究[J].高分子学报,2022,53(09):1142-1149. DOI： 10.11777/j.issn1000-3304.2022.22167.

Zhang Hong-ming,Zhao Jun-yu,Gao Feng-xiang,et al.Synthesis of Biodegradable Polymers by "One Pot" Depolymerization and Polycondensation of PET[J].ACTA POLYMERICA SINICA,2022,53(09):1142-1149. DOI： 10.11777/j.issn1000-3304.2022.22167.

摘要

发展聚对苯二甲酸乙二醇酯(PET)再生利用新途径是学术界和产业界均十分关注的研究方向

而传统的化学转化法存在着工艺流程长、能耗高的问题. 本文利用不同结构的二元醇将PET醇解成低分子量预聚物，然后加入二元酸进一步进行酯化、缩聚，使PET解聚和共聚反应通过“一锅法”完成，省去了复杂、高耗能的单体提纯过程，且PET原料可以100%再生，所制备的高分子材料具有生物降解性能. 值得指出的是，选择不同的醇解剂和二元酸可以实现再生高分子材料结构和性能关系的调控. 本文提出的“解聚-共缩聚”合成生物降解高分子方法，对推动PET的高值化回收再生有较高参考价值.

Abstract

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关键词

聚对苯二甲酸乙二醇酯化学转化解聚共缩聚生物降解高分子

Keywords

Poly(ethylene terephthalate)Chemical conversionDepolymerizationCopolycondensationBiodegradable polymer

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