Supramolecular Chiroptical Switches Based on Azobenzene Polymers

Xin Song; Xue-feng Zhu; Wei Tian; Ming-hua Liu

doi:10.11777/j.issn1000-3304.2022.22185

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Supramolecular Chiroptical Switches Based on Azobenzene Polymers

Review | 更新时间：2024-10-08

- Supramolecular Chiroptical Switches Based on Azobenzene Polymers
- ACTA POLYMERICA SINICA Vol. 53, Issue 10, Pages: 1239-1250(2022)
- 作者机构：
  
  1.西北工业大学化学与化工学院西安 710072
  2.中国科学院化学研究所北京 100190
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2022.22185
  CLC：
- Published：20 October 2022，
  
  Published Online：29 July 2022，
  
  Received：17 May 2022，
  
  Accepted：16 June 2022
- 稿件说明：
移动端阅览
宋昕,朱雪锋,田威等.基于偶氮苯聚合物的超分子手性开关[J].高分子学报,2022,53(10):1239-1250.

Song Xin,Zhu Xue-feng,Tian Wei,et al.Supramolecular Chiroptical Switches Based on Azobenzene Polymers[J].ACTA POLYMERICA SINICA,2022,53(10):1239-1250.
宋昕,朱雪锋,田威等.基于偶氮苯聚合物的超分子手性开关[J].高分子学报,2022,53(10):1239-1250. DOI： 10.11777/j.issn1000-3304.2022.22185.

Song Xin,Zhu Xue-feng,Tian Wei,et al.Supramolecular Chiroptical Switches Based on Azobenzene Polymers[J].ACTA POLYMERICA SINICA,2022,53(10):1239-1250. DOI： 10.11777/j.issn1000-3304.2022.22185.

摘要

手性聚合物的研究对于理解生命过程和制备智能材料具有重要的指导意义. 作为一类典型的光响应性发色团，将偶氮苯基团引入到手性聚合物体系中，能够赋予聚合物光手性开关特性. 相比于传统的利用手性单体共价聚合的方式，利用超分子手段实现聚合物手性诱导是一种更为简便、高效、智能、廉价的方式. 本文从偶氮苯基手性聚合物的构筑方法入手，介绍不同构筑策略对于超分子手性开关行为的影响，并且总结了不同构筑策略的优势与特点. 最后指出在偶氮苯基聚合物的超分子手性开关领域存在的关键科学问题和未来研究中的挑战.

Abstract

The study of chiral polymers has important guiding significance for understanding life processes and preparing smart materials. As a typical photo-responsive chromophore

the introduction of azobenzene groups into chiral polymer systems can endow polymers with optical chirality switch characteristics. Compared with the traditional covalent polymerization by chiral monomers

the use of supramolecular strategy means is a more convenient

efficient and intelligent way to induce polymer chirality. Generally speaking

inducing polymer chirality by supramolecular means can often avoid the use of expensive chiral reagents to save costs

and it can also endow polymer systems with more excellent chirality properties. In recent years

chiral polymers in biomimetic materials

asymmetric catalytic materials and chiral optical devices have shown great application prospects

and promote the interest of scholars in this field. Based on the above background

this paper is classified by the construction methods of azobenzene-based chiral polymers such as chiral monomers

chiral end groups

chiral solvents

chiral gel factors

circularly polarized light and chiral host macrocycles. Then

the effects of different construction strategies on the supramolecular chirality switches are mainly introduced

and the advantages and characteristics of different construction strategies are also summarized. Finally

at the end of this paper

we point out the key scientific issues and challenges in future research of supramolecular chirality switching based on azobenzene polymers.

关键词

手性聚合物超分子手性手性光学开关偶氮苯光响应

Keywords

Chiral polymersSupramolecular chiralityChiroptical switchesAzobenzenePhotoresponsive

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Related Institution

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