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Preparation of High Strength Zwitterionic Polymer Hydrogel Antifouling and Drag Reducing Coating
- Acta Polymerica Sinica Vol. 55, Issue 1, Pages: 99-107(2024)
- 作者机构：
1.高分子合成与功能构造教育部重点实验室 浙江大学高分子科学与工程学系 杭州 310027
2.山西浙大新材料与化工研究院 太原 030000
- 作者简介：
Miao Du, E-mail: dumiao@zju.edu.cn
- 基金信息：
DOI：10.11777/j.issn1000-3304.2023.23170
CLC：Published：20 January 2024，
Published Online：27 September 2023，
Received：28 June 2023，
Accepted：24 July 2023
- 稿件说明：
移动端阅览
陈再宏, 虞海超, 吴子良, 左敏, 宋义虎, 杜淼, 郑强. 高强度两性离子聚合物防污减阻水凝胶涂层的制备. 高分子学报, 2024, 55(1), 99-107
Chen, Z. H.; Yu, H. C.; Wu, Z. L.; Zuo, M.; Song, Y. H.; Du, M.; Zheng, Q. Preparation of high strength zwitterionic polymer hydrogel antifouling and drag reducing coating. Acta Polymerica Sinica, 2024, 55(1), 99-107
陈再宏, 虞海超, 吴子良, 左敏, 宋义虎, 杜淼, 郑强. 高强度两性离子聚合物防污减阻水凝胶涂层的制备. 高分子学报, 2024, 55(1), 99-107 DOI： 10.11777/j.issn1000-3304.2023.23170.
Chen, Z. H.; Yu, H. C.; Wu, Z. L.; Zuo, M.; Song, Y. H.; Du, M.; Zheng, Q. Preparation of high strength zwitterionic polymer hydrogel antifouling and drag reducing coating. Acta Polymerica Sinica, 2024, 55(1), 99-107 DOI： 10.11777/j.issn1000-3304.2023.23170.
摘要
在两性离子甲基丙烯酰乙基磺基甜菜碱(SBMA)聚合物体系中引入天然、易得的
κ
-卡拉胶(
κ
-CG)调控前体溶液的流变行为，采用涂覆工艺在硅烷偶联剂处理的玻璃表面制备了多组分双网络水凝胶涂层，并用锆离子(Zr
4+
)配位交联强化
κ
-CG网络结构. 双网络结构使两性离子水凝胶涂层的力学强度得到显著提高，其拉伸强度、断裂伸长率和杨氏模量最高可达2.51 MPa、1620.76%和1.67 MPa. 该水凝胶涂层在玻璃表面呈强粘接状态，粘接能达2500 J·m
-2
. 该水凝胶涂层在不同介质中均表现出较低的溶胀度，可避免因变形导致的涂层脱落. 同时，SBMA使水凝胶表面形成致密水合层，在防污、减阻方面表现优异.
Abstract
Polymethacrylate sulfonate Betaine (PSBMA) is a classic zwitterionic polymer. As a typical hydrogel
it has the characteristics of high water content
super hydrophilicity
low friction coefficient
low biological toxicity but poor mechanical properties. In this work
the natural and easily available
κ
-carrageenan (
κ
-CG) is employed to endow the preducor solution with good thixotropy. Then
the preducor solution is coated on the glass surface to form multicomponent double network hydrogel coating. In which
κ
-CG network is the first network
acrylamide (AM) and dimethylpropyl sulfonate ethyl methacrylate (SBMA) are the second network monomers
and
N
N'
-Methylene-bis(acrylamide) (MBAA) as crosslinkage agent. The
κ
-CG network is further enhanced using zirconium ion (Zr
4+
) coordination crosslinking. Finally
we get the strong
tough and stable
κ
-CG/AM/SBMA multicomponent double network hydrogel coating. Benefitted by the double network structure
the mechanical properties of the zwitterion polyelectrolyte hydrogel are significantly strengthened. Its best fracture stress
fracture strain
and Young's modulus reaches 2.51 MPa
1620.76% and 1.67 MPa
respectively
which basically meets the conditions for its use in the marine environment. The hydrogel coating swells weakly in different medium (water and seawater). Silane coupling agent KH-570 is used to modify the glass surface which help the hydrogel bond to glass surface. The adhesion energy of the hydrogel coating on glass surface obtained from the 90° peel test reaches about 2500 J·m
-2
. A series of experiments have shown that this
κ
-CG/AM/SBMA ternary double network hydrogel has excellent hydrophilicity
high breaking strength
good toughness
high modulus and low swelling degree. At the same time
due to the existence of surface hydration layer
the hydrogel coating also behaves drag reduction and excellent performance in antifouling.
关键词
两性离子聚合物双网络水凝胶涂层力学性能防污性能
Keywords
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