Preparation of Silicon-containing Hybrid Porous Materials by Piers-Rubinsztajn Reaction

Shu-hong Li; Kai Xiang; Cai-hong Xu

doi:10.11777/j.issn1000-3304.2023.23182

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Preparation of Silicon-containing Hybrid Porous Materials by Piers-Rubinsztajn Reaction

Research Article | 更新时间：2024-01-03

- Preparation of Silicon-containing Hybrid Porous Materials by Piers-Rubinsztajn Reaction
  增强出版
- Acta Polymerica Sinica Vol. 55, Issue 1, Pages: 91-98(2024)
- 作者机构：
  
  1.北京工商大学化学系北京 100048
  2.中国科学院化学研究所北京 100191
  3.山东科学院先进材料研究所济南 250014
- 作者简介：
  
  Shu-hong Li, E-mail: lish@th.btbu.edu.cn
  Cai-hong Xu, E-mail: caihong@iccas.ac.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2023.23182
  CLC：
- Published：20 January 2024，
  
  Published Online：24 October 2023，
  
  Received：10 July 2023，
  
  Accepted：18 August 2023
- 稿件说明：
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李书宏, 项锴, 徐彩虹. 经Piers-Rubinsztajn反应制备含硅杂化多孔材料. 高分子学报, 2024, 55(1), 91-98

Li, S. H.; Xiang, K.; Xu, C. H. Preparation of silicon-containing hybrid porous materials by Piers-Rubinsztajn reaction. Acta Polymerica Sinica, 2024, 55(1), 91-98
李书宏, 项锴, 徐彩虹. 经Piers-Rubinsztajn反应制备含硅杂化多孔材料. 高分子学报, 2024, 55(1), 91-98 DOI： 10.11777/j.issn1000-3304.2023.23182.

Li, S. H.; Xiang, K.; Xu, C. H. Preparation of silicon-containing hybrid porous materials by Piers-Rubinsztajn reaction. Acta Polymerica Sinica, 2024, 55(1), 91-98 DOI： 10.11777/j.issn1000-3304.2023.23182.

摘要

利用B(C

)

催化的Piers-Rubinsztajn反应，探讨了螺旋桨结构四苯基乙烯(TPE)分子与多面体低聚倍半硅氧烷(POSS)合成反应路线，制备了POSS基有机-无机杂化多孔材料. 该反应的突出特点是生成的Si－O－C键合产物中POSS核保持完整. 采用氮气吸附-脱附分析及热重分析对POSS基杂化多孔材料

的孔性能和热性能进行了初步研究. 其比表面积为

BET

=582 m

/g，非定域密度泛函理论(NL-DFT)计算得到其孔体积是0.43 cm

/g，热重分析显示

初始分解温度为463 ℃. 上述结果表明，该杂化材料是一类介孔和微孔并存、并具有很好热稳定性的材料. 该工作为构建有机-无机杂化多孔材料提供了新的思路.

Abstract

Organic-inorganic hybrid porous polymers not only exhibit the diversity of synthesis and flexibility in pore performance control as that of organic porous materials

but also show excellent thermal stability and mechanical properties of inorganic porous materials

and thus play a very important role in the field of porous materials. Polyhedral oligomeric silsesquioxane (POSS) has highly symmetrical structure

is easy to be chemically modified

and has excellent thermal and chemical stability. The silicon oxygen connection at the center of POSS is identical to the Si―O―Si double quaternary ring structure in molecular sieves

making POSS an ideal building block for hybrid porous materials. The Piers-Rubinsztajn reaction catalyzed by B(C

)

avoids the use of expensive precious metal catalysis

which is difficult to completely remove during post-processing. The reaction proceeds under mild conditions and provides an easy route to the formation of Si―O―C linkage. Using the reaction

POSS based organic-inorganic hybrid porous materials were prepared by bonding propeller tetraphenylethylene (TPE) molecules with POSS. Nitrogen adsorption-desorption analysis and thermogravimetric analysis were performed on the hybrid material

which was found to have a combined structure of mesoporous and microporous

and good thermal stability

with a specific surface area of 582 m

/g and

of 463 ℃.

关键词

有机-无机杂化多孔材料多面体低聚倍半硅氧烷Piers-Rubinsztajn反应

Keywords

Organic-inorganic hybrid porous materialsPolyhedral oligomeric silsesquioxanePiers-Rubinsztajn reaction

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