Pultrusion Spinning of Elastic Ionogel Fibers

Ying-kun Shi; Dong Wang; Pei-yi Wu; Sheng-tong Sun

doi:10.11777/j.issn1000-3304.2023.23266

您当前的位置：

首页 >

文章列表页 >

Pultrusion Spinning of Elastic Ionogel Fibers

Research Article | 更新时间：2025-06-17

- Pultrusion Spinning of Elastic Ionogel Fibers
- Acta Polymerica Sinica Vol. 55, Issue 5, Pages: 573-581(2024)
- 作者机构：
  
  1.纤维材料改性国家重点实验室东华大学化学与化工学院先进低维材料中心上海 201620
  2.武汉纺织大学材料科学与工程学院武汉 430200
- 作者简介：
  
  Dong Wang, E-mail: wangd@wtu.edu.cn；
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2023.23266
  CLC：
- Received：16 November 2023，
  
  Accepted：19 December 2023，
  
  Published Online：01 February 2024，
  
  Published：20 May 2024
- 稿件说明：
移动端阅览
时英坤, 王栋, 武培怡, 孙胜童. 提拉纺丝制备弹性离子液体凝胶纤维. 高分子学报, 2024, 55(5), 573-581

Shi, Y. K.; Wang, D.; Wu, P. Y.; Sun, S. T. Pultrusion spinning of elastic ionogel fibers. Acta Polymerica Sinica, 2024, 55(5), 573-581
时英坤, 王栋, 武培怡, 孙胜童. 提拉纺丝制备弹性离子液体凝胶纤维. 高分子学报, 2024, 55(5), 573-581 DOI： 10.11777/j.issn1000-3304.2023.23266.

Shi, Y. K.; Wang, D.; Wu, P. Y.; Sun, S. T. Pultrusion spinning of elastic ionogel fibers. Acta Polymerica Sinica, 2024, 55(5), 573-581 DOI： 10.11777/j.issn1000-3304.2023.23266.

摘要

规模化制备兼具高弹性和高离子电导率的可拉伸导电纤维极具挑战性. 为此，我们开发了一步法提拉纺丝策略，可连续制备高弹性离子液体凝胶纤维. 其中，离子液体与聚合物基质以非共价相互作用结合，在纤维中稳定存在，并可大幅调控纤维力学性能. 得益于通过氢键自发纳米限域形成的多尺度相分离结构，所得离子液体凝胶纤维具有良好的拉伸性(707%)、高透明度(98%)、高回弹性(残余应变仅9%)、导电性(0.12 S·m

-1

)以及抗冻性能. 此外，该纤维还可对湿气、温度以及应变表现出极为灵敏的信号感知能力. 这一工作为开发面向智能感知的高性能离子导电纤维材料提供了设计思路.

Abstract

Stretchable ionically conductive fibers hold great promise in the fields of flexible electronic devices

smart textiles

and human-machine interfaces. However

the scalable production of stretchable fibers with both high conductivity and elasticity remains a significant challenge. In recent years

pultrusion spinning has emerged as a promising technique for the continuous fabrication of ultrathin gel fibers at ambient conditions. Nevertheless

the reduction in fiber diameter often comes at the cost of significantly increased resistance

hampering their applications in smart sensing. To overcome this limitation

in this study

we introduce a one-step pultrusion spinning approach for the continuous production of highly elastic ionogel fibers. Our ionogel fiber is derived from a spinning dope containing poly(2-(dimethylamino)ethylacrylate) methyl chloride quarternary salt (PDMAEA-Q)

poly(methacrylic acid) (PMAA)

and an ionic liquid

1-ethyl-3-methylimidazolium ethyl sulfate (EMI ES). Upon water evaporation

PMAA chains undergo nanoconfinement through hydrogen bonding

forming numerous clusters dispersed within the ductile PDMAEA-Q matrix. Moreover

the employed ionic liquid

EMI ES

interacts with polymer matrix through various physical interactions

further modulating the mechanical and electric properties of the resulting fiber. Owing to its hierarchical phase-separated structure formed by spontaneous nanoconfinement

the ionogel fiber exhibits exceptional stretchability (707% elongation)

remarkable transparency (98%)

high elasticity (~9% residual strain)

high ionic conductivity (0.12 S·m

-1

)

and anti-freezing properties. Furthermore

the ionogel fiber is sensitive to humidity

temperature

and strain changes

enabling its high-resolution detection of different stimuli

via

electrical signals. This work paves the way for the design of advanced ionically conductive fibers

unlocking a myriad of possibilities in smar

t sensing applications.

关键词

Keywords

references

Ju M. ; Wu B. H. ; Sun S. T. ; Wu P. Y. Redox-active iron-citrate complex regulated robust coating-free hydrogel microfiber net with high environmental tolerance and sensitivity . Adv. Funct. Mater. , 2020 , 30 ( 14 ), 1910387 . doi: 10.1002/adfm.201910387 http://dx.doi.org/10.1002/adfm.201910387

Lee Y. ; Song W. J. ; Jung Y. ; Yoo H. ; Kim M. Y. ; Kim H. Y. ; Sun J. Y. Ionic spiderwebs . Sci. Robot. , 2020 , 5 ( 44 ), eaaz 5405 . doi: 10.1126/scirobotics.aaz5405 http://dx.doi.org/10.1126/scirobotics.aaz5405

Liao M. ; Wang C. ; Hong Y. ; Zhang Y. F. ; Cheng X. L. ; Sun H. ; Huang X. L. ; Ye L. ; Wu J. X. ; Shi X. ; Kang X. Y. ; Zhou X. F. ; Wang J. W. ; Li P. Z. ; Sun X. M. ; Chen P. N. ; Wang B. J. ; Wang Y. G. ; Xia Y. Y. ; Cheng Y. H. ; Peng H. S. Industrial scale production of fibre batteries by a solution-extrusion method . Nat. Nanotechnol. , 2022 , 17 ( 4 ), 372 - 377 . doi: 10.1038/s41565-021-01062-4 http://dx.doi.org/10.1038/s41565-021-01062-4

Mo F. N. ; Liang G. J. ; Huang Z. D. ; Li H. F. ; Wang D. H. ; Zhi C. Y. An overview of fiber-shaped batteries with a focus on multifunctionality, scalability, and technical difficulties . Adv. Mater. , 2020 , 32 ( 5 ), e 1902151 . doi: 10.1002/adma.201902151 http://dx.doi.org/10.1002/adma.201902151

Hao Y. ; Zhang Y. N. ; Mensah A. ; Liao S. Q. ; Lv P. F. ; Wei Q. F. Scalable, ultra-high stretchable and conductive fiber triboelectric nanogenerator for biomechanical sensing . Nano Energy , 2023 , 109 , 108291 . doi: 10.1016/j.nanoen.2023.108291 http://dx.doi.org/10.1016/j.nanoen.2023.108291

Yang Z. H. ; Zhai Z. R. ; Song Z. M. ; Wu Y. Z. ; Liang J. H. ; Shan Y. F. ; Zheng J. R. ; Liang H. C. ; Jiang H. Q. Conductive and elastic 3D helical fibers for use in washable and wearable electronics . Adv. Mater. , 2020 , 32 ( 10 ), e 1907495 . doi: 10.1002/adma.202070076 http://dx.doi.org/10.1002/adma.202070076

Wei L. Q. ; Wang S. S. ; Shan M. Q. ; Li Y. M. ; Wang Y. L. ; Wang F. J. ; Wang L. ; Mao J. F. Conductive fibers for biomedical applications . Bioact. Mater. , 2023 , 22 , 343 - 364 . doi: 10.1016/j.bioactmat.2022.10.014 http://dx.doi.org/10.1016/j.bioactmat.2022.10.014

Sim H. J. ; Choi C. ; Lee D. Y. ; Kim H. ; Yun J. H. ; Kim J. M. ; Kang T. M. ; Ovalle R. ; Baughman R. H. ; Kee C. W. ; Kim S. J. Biomolecule based fiber supercapacitor for implantable device . Nano Energy , 2018 , 47 , 385 - 392 . doi: 10.1016/j.nanoen.2018.03.011 http://dx.doi.org/10.1016/j.nanoen.2018.03.011

Lu C. ; Park S. ; Richner T. J. ; Derry A. ; Brown I. ; Hou C. ; Rao S. Y. ; Kang J. ; Mortiz C. T. ; Fink Y. ; Anikeeva P. Flexible and stretchable nanowire-coated fibers for optoelectronic probing of spinal cord circuits . Sci. Adv. , 2017 , 3 ( 3 ), e 1600955 . doi: 10.1126/sciadv.1600955 http://dx.doi.org/10.1126/sciadv.1600955

Seyedin S. ; Razal J. M. ; Innis P. C. ; Jeiranikhameneh A. ; Beirne S. ; Wallace G. G. Knitted strain sensor textiles of highly conductive all-polymeric fibers . ACS Appl. Mater. Interfaces , 2015 , 7 ( 38 ), 21150 - 21158 . doi: 10.1021/acsami.5b04892 http://dx.doi.org/10.1021/acsami.5b04892

Granero A. J. ; Wagner P. ; Wagner K. ; Razal J. M. ; Wallace G. G. ; in het Panhuis M. Highly stretchable conducting SIBS-P3HT fibers . Adv. Funct. Mater. , 2011 , 21 ( 5 ), 955 - 962 . doi: 10.1002/adfm.201001460 http://dx.doi.org/10.1002/adfm.201001460

Zhang X. H. ; Lu W. B. ; Zhou G. H. ; Li Q. W. Understanding the mechanical and conductive properties of carbon nanotube fibers for smart electronics . Adv. Mater. , 2020 , 32 ( 5 ), e 1902028 . doi: 10.1002/adma.201902028 http://dx.doi.org/10.1002/adma.201902028

Kim I. H. ; Yun T. ; Kim J. E. ; Yu H. ; Sasikala S. P. ; Lee K. E. ; Koo S. H. ; Hwang H. ; Jung H. J. ; Park J. Y. ; Jeong H. S. ; Kim S. O. Mussel-inspired defect engineering of graphene liquid crystalline fibers for synergistic enhancement of mechanical strength and electrical conductivity . Adv. Mater. , 2018 , 30 , e1803267 . doi: 10.1002/adma.201870298 http://dx.doi.org/10.1002/adma.201870298

Zheng L. J. ; Zhu M. M. ; Wu B. H. ; Li Z. L. ; Sun S. T. ; Wu P. Y. Conductance-stable liquid metal sheath-core microfibers for stretchy smart fabrics and self-powered sensing . Sci. Adv. , 2021 , 7 ( 22 ), eabg 4041 . doi: 10.1126/sciadv.abg4041 http://dx.doi.org/10.1126/sciadv.abg4041

Zhao X. ; Chen F. ; Li Y. H. ; Lu H. ; Zhang N. ; Ma M. M. Bioinspired ultra-stretchable and anti-freezing conductive hydrogel fibers with ordered and reversible polymer chain alignment . Nat. Commun. , 2018 , 9 ( 1 ), 3579 . doi: 10.1038/s41467-018-05904-z http://dx.doi.org/10.1038/s41467-018-05904-z

Yao M. Y. ; Wu B. H. ; Feng X. D. ; Sun S. T. ; Wu P. Y. A highly robust ionotronic fiber with unprecedented mechanomodulation of ionic conduction . Adv. Mater. , 2021 , 33 ( 42 ), e 2103755 . doi: 10.1002/adma.202103755 http://dx.doi.org/10.1002/adma.202103755

Lee S. ; Sasaki D. ; Kim D. ; Mori M. M. ; Yokota T. ; Lee H. ; Park S. ; Fukuda K. ; Sekino M. ; Matsuura K. ; Shimizu T. ; Someya T. Ultrasoft electronics to monitor dynamically pulsing cardiomyocytes . Nat. Nanotechnol. , 2019 , 14 ( 2 ), 156 - 160 . doi: 10.1038/s41565-018-0331-8 http://dx.doi.org/10.1038/s41565-018-0331-8

Wu H. ; Kong D. S. ; Ruan Z. C. ; Hsu P. C. ; Wang S. ; Yu Z. F. ; Carney T. J. ; Hu L. B. ; Fan S. H. ; Cui Y. A transparent electrode based on a metal nanotrough network . Nat. Nanotechnol. , 2013 , 8 ( 6 ), 421 - 425 . doi: 10.1038/nnano.2013.84 http://dx.doi.org/10.1038/nnano.2013.84

Song J. C. ; Chen S. ; Sun L. J. ; Guo Y. F. ; Zhang L. Z. ; Wang S. L. ; Xuan H. X. ; Guan Q. B. ; You Z. W. Mechanically and electronically robust transparent organohydrogel fibers . Adv. Mater. , 2020 , 32 ( 8 ), e 1906994 . doi: 10.1002/adma.201906994 http://dx.doi.org/10.1002/adma.201906994

Tan H. ; Zhang L. Z. ; Ma X. P. ; Sun L. J. ; Yu D. L. ; You Z. W. Adaptable covalently cross-linked fibers . Nat. Commun. , 2023 , 14 ( 1 ), 2218 . doi: 10.1038/s41467-023-37850-w http://dx.doi.org/10.1038/s41467-023-37850-w

Shi Y. K. ; Wu B. H. ; Sun S. T. ; Wu P. Y. Aqueous spinning of robust, self-healable, and crack-resistant hydrogel microfibers enabled by hydrogen bond nanoconfinement . Nat. Commun. , 2023 , 14 ( 1 ), 1370 . doi: 10.1038/s41467-023-37036-4 http://dx.doi.org/10.1038/s41467-023-37036-4

Zhao W. Q. ; Shao F. ; Sun F. Q. ; Su Z. H. ; Liu S. Y. ; Zhang T. ; Zhu M. F. ; Liu Z. F. ; Zhou X. Neuron-inspired sticky artificial spider silk for signal transmission . Adv. Mater. , 2023 , 35 ( 32 ), e 2300876 . doi: 10.1002/adma.202300876 http://dx.doi.org/10.1002/adma.202300876

Zhang S. L. ; Zhou M. J. ; Liu M. Y. ; Guo Z. H. ; Qu H. ; Chen W. S. ; Tan S. C. Ambient-conditions spinning of functional soft fibers via engineering molecular chain networks and phase separation . Nat. Commun. , 2023 , 14 ( 1 ), 3245 . doi: 10.1038/s41467-023-38269-z http://dx.doi.org/10.1038/s41467-023-38269-z

Dou Y. Y. ; Wang Z. P. ; He W. Q. ; Jia T. J. ; Liu Z. J. ; Sun P. C. ; Wen K. ; Gao E. L. ; Zhou X. ; Hu X. Y. ; Li J. J. ; Fang S. L. ; Qian D. ; Liu Z. F. Artificial spider silk from ion-doped and twisted core-sheath hydrogel fibres . Nat. Commun. , 2019 , 10 ( 1 ), 5293 . doi: 10.1038/s41467-019-13257-4 http://dx.doi.org/10.1038/s41467-019-13257-4

Chu C. K. ; Joseph A. J. ; Limjoco M. D. ; Yang J. W. ; Bose S. M. ; Thapa L. S. ; Langer R. ; Anderson D. G. Chemical tuning of fibers drawn from extensible hyaluronic acid networks . J. Am. Chem. Soc. , 2020 , 142 ( 46 ), 19715 - 19721 . doi: 10.1021/jacs.0c09691 http://dx.doi.org/10.1021/jacs.0c09691

Wu Y. C. ; Shah D. U. ; Liu C. Y. ; Yu Z. Y. ; Liu J. ; Ren X. H. ; Rowland M. J. ; Abell C. ; Ramage M. H. ; Scherman O. A. Bioinspired supramolecular fibers drawn from a multiphase self-assembled hydrogel . Proc. Natl. Acad. Sci. USA , 2017 , 114 ( 31 ), 8163 - 8168 . doi: 10.1073/pnas.1705380114 http://dx.doi.org/10.1073/pnas.1705380114

Cruz M. V. ; Shah D. U. ; Warner N. C. ; McCune J. A. ; Scherman O. A. Facile, energy-efficient microscale fibrillation of polyacrylamides under ambient conditions . Adv. Mater. , 2022 , 34 ( 23 ), e 2201577 . doi: 10.1002/adma.202201577 http://dx.doi.org/10.1002/adma.202201577

Sun J. K. ; Guo W. J. ; Mei G. K. ; Wang S. L. ; Wen K. ; Wang M. L. ; Feng D. Y. ; Qian D. ; Zhu M. F. ; Zhou X. ; Liu Z. F. Artificial spider silk with buckled sheath by nano-pulley combing . Adv. Mater. , 2023 , 35 ( 32 ), e 2212112 . doi: 10.1002/adma.202212112 http://dx.doi.org/10.1002/adma.202212112

Ling S. J. ; Qin Z. ; Li C. M. ; Huang W. W. ; Kaplan D. L. ; Buehler M. J. Polymorphic regenerated silk fibers assembled through bioinspired spinning . Nat. Commun. , 2017 , 8 ( 1 ), 1387 . doi: 10.1038/s41467-017-00613-5 http://dx.doi.org/10.1038/s41467-017-00613-5

Zhang S. L. ; Zhou Y. H. ; Libanori A. ; Deng Y. B. ; Liu M. Y. ; Zhou M. J. ; Qu H. ; Zhao X. ; Zheng P. ; Zhu Y. L. ; Chen J. ; Tan S. C. Biomimetic spinning of soft functional fibres via spontaneous phase separation . Nat. Electron. , 2023 , 6 , 338 - 348 . doi: 10.1038/s41928-023-00960-w http://dx.doi.org/10.1038/s41928-023-00960-w

Holland C. ; Terry A. E. ; Porter D. ; Vollrath F. Comparing the rheology of native spider and silkworm spinning dope . Nat. Mater. , 2006 , 5 ( 11 ), 870 - 874 . doi: 10.1038/nmat1762 http://dx.doi.org/10.1038/nmat1762

Fang X. ; Li Y. X. ; Li X. ; Liu W. M. ; Yu X. H. ; Yan F. ; Sun J. Q. Dynamic hydrophobic domains enable the fabrication of mechanically robust and highly elastic poly(vinyl alcohol)-based hydrogels with excellent self-healing ability . ACS Mater. Lett. , 2020 , 2 ( 7 ), 764 - 770 . doi: 10.1021/acsmaterialslett.0c00075 http://dx.doi.org/10.1021/acsmaterialslett.0c00075

Views

834

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Construction of Stretchable Conductive Fibers Based on Polypyrrole and Their Application in Electrothermal Therapy

Related Author

Dong Wang

Sheng-tong Sun

Ji-fu Mao

Lu Wang

Fu-jun Wang

Sha-sha Wang

Li-qin Tang

Xiao-li Liu

Related Institution

College of Textile, Key Laboratory of Textile Science & Technology of the Ministry of Education, Key Laboratory of Biomedical Textile Materials and Technology in Textile Industry, Shanghai Frontiers Science Center of Advanced Textiles, Donghua University

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰