Preparation of Poly(acrylonitrile/ethyl acrylate) Colored Latex Particles and Their Printing Properties

Le Zhao; Jing Yang; Yang-qi Lv; Chun-xia Tang; Yu Guan; Shao-hai Fu

doi:10.11777/j.issn1000-3304.2023.23267

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Preparation of Poly(acrylonitrile/ethyl acrylate) Colored Latex Particles and Their Printing Properties

Research Article | 更新时间：2024-06-05

- Preparation of Poly(acrylonitrile/ethyl acrylate) Colored Latex Particles and Their Printing Properties
- Acta Polymerica Sinica Vol. 55, Issue 6, Pages: 750-760(2024)
- 作者机构：
  
  江南大学纺织科学与工程学院生态纺织教育部重点实验室(江南大学) 无锡 214122
- 作者简介：
  
  Chun-xia Tang, E-mail: chunxia.tang@jiangnan.edu.cn
  Shao-hai Fu, E-mail: shaohaifu@jiangnan.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2023.23267
  CLC：
- Published：20 June 2024，
  
  Published Online：19 February 2024，
  
  Received：17 November 2023，
  
  Accepted：26 December 2023
- 稿件说明：
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赵乐, 杨静, 吕杨奇, 唐春霞, 关玉, 付少海. 聚(丙烯腈/丙烯酸乙酯)彩色乳胶粒的制备及其印花性能研究. 高分子学报, 2024, 55(6), 750-760

Zhao, L.; Yang, J.; Lv, Y. Q.; Tang, C. X.; Guan, Y.; Fu, S. H. Preparation of poly(acrylonitrile/ethyl acrylate) colored latex particles and their printing properties. Acta Polymerica Sinica, 2024, 55(6), 750-760
赵乐, 杨静, 吕杨奇, 唐春霞, 关玉, 付少海. 聚(丙烯腈/丙烯酸乙酯)彩色乳胶粒的制备及其印花性能研究. 高分子学报, 2024, 55(6), 750-760 DOI： 10.11777/j.issn1000-3304.2023.23267.

Zhao, L.; Yang, J.; Lv, Y. Q.; Tang, C. X.; Guan, Y.; Fu, S. H. Preparation of poly(acrylonitrile/ethyl acrylate) colored latex particles and their printing properties. Acta Polymerica Sinica, 2024, 55(6), 750-760 DOI： 10.11777/j.issn1000-3304.2023.23267.

摘要

针对目前共聚法制备的彩色纳米乳胶粒存在着色力差，难以实现对织物深、浓染色的问题，首先通过计算常用聚合单体的溶解度参数，筛选出对可聚合蒽醌染料溶解性更好的硬、软单体组合，再通过半连续乳液聚合的方法制备了聚(丙烯腈/丙烯酸乙酯)红色纳米乳胶粒，采用红外光谱仪、透射电子显微镜、示差扫描量热仪、电子万能材料试验机等仪器对乳胶粒的结构和性能进行了表征，探究了硬、软单体比例、可聚合染料用量、油水比、引发剂浓度等因素对乳胶粒性能的影响，并研究了不同固含量的红色纳米乳胶粒对棉织物的印花效果. 结果表明：硬单体丙烯腈(AN)和软单体丙烯酸乙酯(EA)对染料的溶解性良好，当二者比例在1:1.5~1:2时，所得乳胶膜兼具强力及延展性；染料的用量从0.5 wt%增加到2.5 wt%，油水比从1:8增加到1:4，单体和染料的转化率都呈降低趋势；当乳胶粒固含量为30%时，印花织物的

值为10.34. 与以往共聚法制备的彩色乳胶粒相比，乳胶粒中染料的接枝率大幅上升，有效提高了彩色纳米乳胶粒的着色力.

Abstract

In view of the problem that the color nano-latex particles prepared by the copolymerization method have poor color strength

and it is difficult to achieve deep and intensive dyeing of fabrics

this study first screened out the combination of soft and hard monomers with better solubility to polymerizable anthraquinone dyes (AHAQ) by calculating the solubility parameters of commonly used polymeric monomers

and then prepared poly(acrylonitrile/ethyl acrylate) red nano-latex particles (PAEA) by semi-continuous emulsion polymerization. The structure and properties of latex particles were characterized by electronic universal materials testing machine and other instruments

and the effects of factors such as the proportion of hard and soft monomers

the amount of crosslinker divinylbenzene (DVB)

the amount of AHAQ

the ratio of oil to water

and the concentration of initiator on the properties of latex particles were explored

and the printing effect of colored latex particles with different solid contents on cotton fabrics was studied. The results showed that the hard monomer acrylonitrile (AN) and the soft monomer ethyl acrylate (EA) had good solubility to the dye

and when the ratio of the two was 1:1.5‍‒‍1:2

the obtained latex film had both strength and ductility. The dosage of dye increased from 0.5 wt% to 2.5 wt%

the oil-water ratio increased from 1:8 to 1:4

and the conversion rates of monomer and dye showed a decreasing trend. When the solids content of latex is 30 wt%

the

value of the printed fabric is 10.34. Compared with the

color latex particles prepared by the previous copolymerization method

the grafting rate of the dye in the latex particles increased significantly

which effectively improved the tinting strength of the color nano latex particles.

关键词

彩色乳胶粒纳米颜料乳液聚合印花

Keywords

Colored latex granulesNano pigmentsEmulsion polymerizationPrinting

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Related Institution

College of Chemical Engineering, Fuzhou University

School of Materials Science and Engineering, Changzhou University

Department of Chemical Engineering and Key Laboratory of Advanced Materials of Ministry of Education of China, Tsinghua University

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