Preparation and Research of Polyurethane Based Anti-icing Coating Based on Different Young's Modulus

Wei Song; Feng-ying Li; Ding-jun Zhang; Lei Chen; Hui-di Zhou; Jian-min Chen

doi:10.11777/j.issn1000-3304.2023.23297

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Preparation and Research of Polyurethane Based Anti-icing Coating Based on Different Young's Modulus

Research Article | 更新时间：2024-08-14

- Preparation and Research of Polyurethane Based Anti-icing Coating Based on Different Young's Modulus
- Acta Polymerica Sinica Vol. 55, Issue 8, Pages: 1033-1043(2024)
- 作者机构：
  
  1.兰州理工大学省部共建有色金属先进加工与再利用国家重点实验室兰州 730050
  2.中国科学院兰州化学物理研究所固体润滑国家重点实验室兰州 730000
  3.中国科学院大学材料与光电研究中心北京 100049
- 作者简介：
  
  Ding-jun Zhang, E-mail: zhangdingjun@lut.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2023.23297
  CLC：
- Published：20 August 2024，
  
  Published Online：06 May 2024，
  
  Received：14 February 2024，
  
  Accepted：17 March 2024
- 稿件说明：
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宋伟, 李凤英, 张定军, 陈磊, 周惠娣, 陈建敏. 基于不同杨氏模量的聚氨酯基防结冰涂层的制备及研究. 高分子学报, 2024, 55(8), 1033-1043

Song, W.; Li, F. Y.; Zhang, D. J.; Chen, L.; Zhou, H. D.; Chen, J. M. Preparation and research of polyurethane based anti-icing coating based on different Young's modulus. Acta Polymerica Sinica, 2024, 55(8), 1033-1043
宋伟, 李凤英, 张定军, 陈磊, 周惠娣, 陈建敏. 基于不同杨氏模量的聚氨酯基防结冰涂层的制备及研究. 高分子学报, 2024, 55(8), 1033-1043 DOI： 10.11777/j.issn1000-3304.2023.23297.

Song, W.; Li, F. Y.; Zhang, D. J.; Chen, L.; Zhou, H. D.; Chen, J. M. Preparation and research of polyurethane based anti-icing coating based on different Young's modulus. Acta Polymerica Sinica, 2024, 55(8), 1033-1043 DOI： 10.11777/j.issn1000-3304.2023.23297.

摘要

以4

4'-二苯基甲烷二异氰酸酯(MDI)、聚四氢呋喃醚二醇(PTMEG)为原料，通过改变

值，获得了不同杨氏模量(0.72~5.95 MPa)的单组份湿固化型聚氨酯弹性体(PUE)涂层，用不同分子量聚醚二元醇进行对比，探究涂层杨氏模量对冰黏附强度的影响. 结果发现，较高分子量聚醚二元醇系列具有较低冰黏附强度(平均57.71 kPa)，随涂层杨氏模量增大，对应冰黏附强度呈先增大后减小趋势. 分析表明，低杨氏模量涂层(如PTMEG-1000作软段时，1.05~2.96 MP

a)在水结冰膨胀过程中，涂层表面易产生变形，形成凹凸不平结构，提供更多黏附点供冰结构黏附，使得冰黏附强度与表面能密切相关，造成冰黏附强度增大的可能性. 而较高杨氏模量涂层(如PTMEG-1000作软段时，2.96~5.95 MPa)存在冰黏附强度的降低区间不符合杨氏模量与冰黏附强度的正相关关系，这是因为受低温回弹力作用，冰与涂层产生弹性失配，诱发产生微裂纹使得冰-涂层界面空化，造成冰黏附强度减小的可能性. 因此，合理利用涂层杨氏模量对冰黏附强度的影响机制可以有效降低冰黏附强度.

Abstract

Using 4

‍4'-diphenylmethane diisocyanate (MDI) and polytetrahydrofuran ether diol (PTMEG) as precursors

a one-component wet-cured polyurethane elastomer (PUE) coating with tunable Young's modulus (0.72-5.95 MPa) was synthesized by manipulating the

value. The effect of Young's modulus of coating on ice adhesion strength was studied by comparing polyether diols with different molecular weights. The results show that higher molecular weight series of polyether diols exhibit lower ice adhesion strength (average 57.71 kPa). As the Young's modulus of the coating increases

the corresponding ice adhesion strength initially rises and then declines. The analysis reveals that the surface of the coating with low Young's modulus (for example

PTMEG-1000 as the soft segment

1.05-2.96 MPa) is easily deformed during water icing expansion

forming uneven structures and providing more adhesion points fo

r the ice structure to adhere

which makes the ice adhesion strength closely related to the surface energy

resulting in the possibility of increasing the ice adhesion strength. However

the decrease interval of ice adhesion strength in coatings with higher Young's modulus (for example

PTMEG-1000 as the soft segment

2.96-5.95 MPa) is not consistent with the positive correlation between Young's modulus and ice adhesion strength. This is due to the effect of low temperature resilience

the elastic mismatch between the ice and the coating induces micro-cracks and cavitation of the ice-coating interface

resulting in the possibility of reducing the ice adhesion strength. Therefore

understanding how coating's Young's modulus affects ice adhesion can be effectively utilized to reduce such adhesive properties.

关键词

聚氨酯弹性体杨氏模量冰黏附强度机械性能

Keywords

Polyurethane elastomerYoung's modulusIce adhesion strengthMechanical property

references

Chen D. Y.; Gelenter M. D.; Hong M.; Cohen R. E.; McKinley G. H. Icephobic surfaces induced by interfacial nonfrozen water. ACS Appl. Mater. Interfaces, 2017, 9(4), 4202-4214. doi:10.1021/acsami.6b13773http://dx.doi.org/10.1021/acsami.6b13773

Liu B.; Zhang K. Q.; Tao C.; Zhao Y. H.; Li X. H.; Zhu K. Y.; Yuan X. Y. Strategies for anti-icing: low surface energy or liquid-infused? RSC Adv., 2016, 6(74), 70251-70260. doi:10.1039/c6ra11383dhttp://dx.doi.org/10.1039/c6ra11383d

Dou R. M.; Chen J.; Zhang Y. F.; Wang X. P.; Cui D. P.; Song Y. L.; Jiang L.; Wang J. J. Anti-icing coating with an aqueous lubricating layer. ACS Appl. Mater. Interfaces, 2014, 6(10), 6998-7003. doi:10.1021/am501252uhttp://dx.doi.org/10.1021/am501252u

Jung S.; Tiwari M. K.; Doan N. V.; Poulikakos D. Mechanism of supercooled droplet freezing on surfaces. Nat. Commun., 2012, 3, 615. doi:10.1038/ncomms1630http://dx.doi.org/10.1038/ncomms1630

Zhang Z. S.; Liu X. Y. Control of ice nucleation: freezing and antifreeze strategies. Chem. Soc. Rev., 2018, 47(18), 7116-7139. doi:10.1039/c8cs00626ahttp://dx.doi.org/10.1039/c8cs00626a

Knight C. A. Adding to the antifreeze agenda. Nature, 2000, 406, 249-251. doi:10.1038/35018671http://dx.doi.org/10.1038/35018671

Liu X. Y. Interfacial effect of molecules on nucleation kinetics. J. Phys. Chem. B, 2001, 105(47), 11550-11558. doi:10.1021/jp010671zhttp://dx.doi.org/10.1021/jp010671z

Liu X. Y.; Maiwa K.; Tsukamoto K. Heterogeneous two-dimensional nucleation and growth kinetics. J. Chem. Phys., 1997, 106(5), 1870-1879. doi:10.1063/1.473325http://dx.doi.org/10.1063/1.473325

Cavalieri D. J.; Markus T.; Hall D. K.; Gasiewski A. J.; Klein M.; Ivanoff A. Assessment of EOS aqua AMSR-E Arctic Sea ice concentrations using landsat-7 and airborne microwave imagery. IEEE Trans. Geosci. Remote. Sens., 2006, 44(11), 3057-3069. doi:10.1109/tgrs.2006.878445http://dx.doi.org/10.1109/tgrs.2006.878445

Subramanyam S. B.; Rykaczewski K.; Varanasi K. K. Ice adhesion on lubricant-impregnated textured surfaces. Langmuir, 2013, 29(44), 13414-13418. doi:10.1021/la402456chttp://dx.doi.org/10.1021/la402456c

Liu Y. B.; Wu Y.; Liu S. J.; Zhou F. Material strategies for ice accretion prevention and easy removal. ACS Materials Lett., 2022, 4(2), 246-262. doi:10.1021/acsmaterialslett.1c00365http://dx.doi.org/10.1021/acsmaterialslett.1c00365

Meuler A. J.; McKinley G. H.; Cohen R. E. Exploiting topographical texture to impart icephobicity. ACS Nano, 2010, 4(12), 7048-7052. doi:10.1021/nn103214qhttp://dx.doi.org/10.1021/nn103214q

Rao Q. Q.; Lu Y. L.; Song L. N.; Hou Y.; Zhan X. L.; Zhang Q. H. Highly efficient self-repairing slippery liquid-infused surface with promising anti-icing and anti-fouling performance. ACS Appl. Mater. Interfaces, 2021, 13(33), 40032-40041. doi:10.1021/acsami.1c09491http://dx.doi.org/10.1021/acsami.1c09491

Rykaczewski K.; Anand S.; Subramanyam S. B.; Varanasi K. K. Mechanism of frost formation on lubricant-impregnated surfaces. Langmuir, 2013, 29(17), 5230-5238. doi:10.1021/la400801shttp://dx.doi.org/10.1021/la400801s

Ma J.; Pan W. H.; Li Y. H.; Song J. L. Slippery coating without loss of lubricant. Chem. Engin. J., 2022, 444, 136606. doi:10.1016/j.cej.2022.136606http://dx.doi.org/10.1016/j.cej.2022.136606

Soltis J.; Palacios J.; Eden T.; Wolfe D. Ice adhesion mechanisms of erosion-resistant coatings. AIAA J., 2014, 53(3), 654-662. doi:10.2514/1.j053208http://dx.doi.org/10.2514/1.j053208

Ryzhkin I. A.; Petrenko V. F. Physical mechanisms responsible for ice adhesion. J. Phys. Chem. B, 1997, 101(32), 6267-6270. doi:10.1021/jp9632145http://dx.doi.org/10.1021/jp9632145

Wilen L. A.; Wettlaufer J. S.; Elbaum M.; Schick M. Dispersion-force effects in interfacial premelting of ice. Phys. Rev. B Condens. Matter, 1995, 52(16), 12426-12433. doi:10.1103/physrevb.52.12426http://dx.doi.org/10.1103/physrevb.52.12426

Chubarenko I. Physical processes behind interactions of microplastic particles with natural ice. Environ. Res. Commun., 2022, 4(1), 012001. doi:10.1088/2515-7620/ac49a8http://dx.doi.org/10.1088/2515-7620/ac49a8

Beemer D. L.; Wang W.; Kota A. K. Durable gels with ultra-low adhesion to ice. J. Mater. Chem. A, 2016, 4(47), 18253-18258. doi:10.1039/c6ta07262chttp://dx.doi.org/10.1039/c6ta07262c

金敬福, 李杨, 陈廷坤, 丛茜, 齐迎春. 涂层弹性模量对结冰附着强度的影响. 吉林大学学报(工学版), 2017, 47(5): 1548-1553.

顾光成, 应宇翔, 李珂, 刘俊豪, 金崇会, 钟雲濠, 薛志亮, 周永刚. 风机叶片弹性除冰涂层的性能试验研究. 工程热物理学报, 2022, 43(11), 2937-2943.

Dhyani A.; Choi W.; Golovin K.; Tuteja A. Surface design strategies for mitigating ice and snow accretion. Matter, 2022, 5(5), 1423-1454. doi:10.1016/j.matt.2022.04.012http://dx.doi.org/10.1016/j.matt.2022.04.012

杨靖, 李彦辉, 陈守兵, 张新瑞, 王廷梅, 王齐华, 张耀明. 盾构机主驱动密封用聚氨酯脲弹性体密封材料的研究. 高分子学报, 2023, 54(12), 1857-1869.

秦凤鸣, 李香玉, 王锦艳, 蹇锡高. 有机硅改性聚氨酯/纳米SiO2复合超疏水涂层的制备. 高分子学报, 2021, 52(9), 1165-1173. doi:10.11777/j.issn1000-3304.2021.21038http://dx.doi.org/10.11777/j.issn1000-3304.2021.21038

Piril Ertem S.; Yilgor E.; Kosak C.; Wilkes G. L.; Zhang M. Q.; Yilgor I. Effect of soft segment molecular weight on tensile properties of poly(propylene oxide) based polyurethaneureas. Polymer, 2012, 53(21), 4614-4622. doi:10.1016/j.polymer.2012.08.020http://dx.doi.org/10.1016/j.polymer.2012.08.020

陈晓东, 周南桥, 张海. 基于聚己内酯多元醇的浇注型聚氨酯弹性体结构与性能的研究. 陕西科技大学学报(自然科学版), 2009, 27(4), 1-9. doi:10.3969/j.issn.1000-5811.2009.04.001http://dx.doi.org/10.3969/j.issn.1000-5811.2009.04.001

张欢欢, 王杰, 黄刚, 占宏君, 石彤非, 许东华, 姚卫国. 汽车用聚氨酯减振材料的结构与性能. 高分子学报, 2016, (10), 1447-1454. doi:10.11777/j.issn1000-3304.2016.16040http://dx.doi.org/10.11777/j.issn1000-3304.2016.16040

付浩, 肖长发, 孙乐乐, 潘健, 权全. 偏氟乙烯-六氟丙烯共聚物纤维结构与性能表征. 高分子学报, 2018, (5), 624-631. doi:10.11777/j.issn1000-3004.2017.17158http://dx.doi.org/10.11777/j.issn1000-3004.2017.17158

王莉莉, 董侠, 朱平, 张秀芹, 王笃金. 长碳链聚醚酰胺弹性纤维开发及其弹性机理. 高分子学报, 2017, (5), 752-760. doi:10.11777/j.issn1000-3304.2017.16317http://dx.doi.org/10.11777/j.issn1000-3304.2017.16317

Meuler A. J.; Smith J. D.; Varanasi K. K.; Mabry J. M.; McKinley G. H.; Cohen R. E. Relationships between water wettability and ice adhesion. ACS Appl. Mater. Interfaces, 2010, 2(11), 3100-3110. doi:10.1021/am1006035http://dx.doi.org/10.1021/am1006035

陈晓东, 周南桥, 许佳润, 张海. 微观镜像分析法在聚氨酯微相分离结构研究中的应用. 橡胶工业, 2010, 57(9), 564-570. doi:10.3969/j.issn.1000-890X.2010.09.010http://dx.doi.org/10.3969/j.issn.1000-890X.2010.09.010

杨序平, 李忠明, 卢忠远, 李尚斌. 热塑性聚氨酯弹性体粘合剂的制备及力学性能的研究. 国外塑料, 2009, 27(3), 41-44. doi:10.3969/j.issn.1002-5219.2009.03.013http://dx.doi.org/10.3969/j.issn.1002-5219.2009.03.013

雷婉青. 废纸基纳米微晶纤维素/聚氨酯弹性体复合材料的制备及其性能研究. 西安理工大学博士学位论文, 2019.

Wang C. Y.; Fuller T.; Zhang W.; Wynne K. J. Thickness dependence of ice removal stress for a polydimethylsiloxane nanocomposite: sylgard 184. Langmuir, 2014, 30(43), 12819-12826. doi:10.1021/la5030444http://dx.doi.org/10.1021/la5030444

Dotan A.; Dodiuk H.; Laforte C.; Kenig S. The relationship between water wetting and ice adhesion. J. Adhes. Sci. Technol., 2009, 23(15), 1907-1915. doi:10.1163/016942409x12510925843078http://dx.doi.org/10.1163/016942409x12510925843078

Good R. Contact angle, wetting, and adhesion: a critical review. J. Adhes. Sci. Technol., 1992, 6, 1269-1302. doi:10.1163/156856192x00629http://dx.doi.org/10.1163/156856192x00629

Zou M.; Beckford S.; Wei R.; Ellis C.; Hatton G.; Miller M. A. Effects of surface roughness and energy on ice adhesion strength. Appl. Surf. Sci., 2011, 257(8), 3786-3792. doi:10.1016/j.apsusc.2010.11.149http://dx.doi.org/10.1016/j.apsusc.2010.11.149

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