Structural Design, Controlled Preparation and Applications of Two-dimensional sp<sup>2</sup>c-Conjugated Polymers

Wen-kai Zhao; Sheng-xu Li; Guang-en Fu; Tao Zhang

doi:10.11777/j.issn1000-3304.2023.23301

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Structural Design, Controlled Preparation and Applications of Two-dimensional sp²c-Conjugated Polymers

Review | 更新时间：2025-06-17

- Structural Design, Controlled Preparation and Applications of Two-dimensional sp²c-Conjugated Polymers
- Acta Polymerica Sinica Vol. 55, Issue 5, Pages: 532-552(2024)
- 作者机构：
  
  1.中国科学院宁波材料技术与工程研究所中国科学院海洋新材料与应用技术重点实验室宁波 315201
  2.中国科学院大学北京 100049
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2023.23301
  CLC：
- Received：30 December 2023，
  
  Accepted：31 January 2024，
  
  Published：20 May 2024
- 稿件说明：
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赵文凯, 李升旭, 付广恩, 张涛. 二维sp²-碳共轭聚合物的结构设计、可控制备与应用研究. 高分子学报, 2024, 55(5), 532-552

Zhao, W. K.; Li, S. X.; Fu, G. E.; Zhang, T. Structural design, controlled preparation and applications of two-dimensional sp²c-conjugated polymers. Acta Polymerica Sinica, 2024, 55(5), 532-552
赵文凯, 李升旭, 付广恩, 张涛. 二维sp²-碳共轭聚合物的结构设计、可控制备与应用研究. 高分子学报, 2024, 55(5), 532-552 DOI： 10.11777/j.issn1000-3304.2023.23301.

Zhao, W. K.; Li, S. X.; Fu, G. E.; Zhang, T. Structural design, controlled preparation and applications of two-dimensional sp²c-conjugated polymers. Acta Polymerica Sinica, 2024, 55(5), 532-552 DOI： 10.11777/j.issn1000-3304.2023.23301.

摘要

二维sp

-碳共轭聚合物是指通过碳碳双键将构筑单元连接起来的层状聚合物材料. 因其具有可设计的周期性多孔结构、高比表面积、优异的结构稳定性和高载流子迁移速率等优点，被认为是最具前景的聚合物新材料之一. 本文以作者课题组的研究工作为主，对二维sp

-碳共轭聚合物的结构设计和合成方法、薄膜可控制备策略及其在盐差发电、海水提铀、光催化、荧光传感和质子传导等领域应用进行了总结，并从晶体结构的调控、新型合成方法的探索、通用性薄膜合成策略的设计以及相关应用的拓展等方面对二维sp

-碳共轭聚合物的研究进行了展望.

Abstract

Two-dimensional sp

c-conjugated polymers (2D sp

c-CPs) refer to layered materials constructed by C＝C. 2D sp

c-CPs have shown great potential in photocatalytic conversion of high-value-added products

osmotic energy generation

fluorescence sensing

proton conduction

organic semiconductor devices

and the extraction of radioactive nuclides

due to their designable periodic porous structures

high surface area

excellent structural stability

and high charge transfer. This review primarily elucidates the research endeavors of our research group concerning 2D sp

c-CPs. Firstly

the structural design and synthesis methods of 2D sp

c-CPs are presented. Subsequently

the preparation strategies for 2D sp

c-CP films

primarily conducted by our research group are introduced. Moreover

the applications of 2D sp

c-CPs in seawater uranium extraction

osmotic energy generation

fluorescence sensing

proton conduction

and photocatalysis are summarized in detail. Finally

the review offers a perspective on the research of 2D

c-CPs

encompassing modulation of crystal structure

exploration of novel synthesis methods

design of universal film synthesis strategies

and the expansion of related applications.

关键词

Keywords

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Structural Design, Controlled Preparation and Applications of Two-dimensional sp2c-Conjugated Polymers

DOI：10.11777/j.issn1000-3304.2023.23301

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Structural Design, Controlled Preparation and Applications of Two-dimensional sp²c-Conjugated Polymers