Direct One-step Synthesis of Cellulose Laurate Ester <italic style="font-style: italic">via</italic> Mechanochemical Method

Zi-wei Feng; Meng-lei Li; Pei-yao Li; Kai Zhang; Ming-bo Yang

doi:10.11777/j.issn1000-3304.2023.23304

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Direct One-step Synthesis of Cellulose Laurate Ester via Mechanochemical Method

Research Article | 更新时间：2024-08-14

- Direct One-step Synthesis of Cellulose Laurate Ester via Mechanochemical Method
- Acta Polymerica Sinica Vol. 55, Issue 8, Pages: 986-1000(2024)
- 作者机构：
  
  四川大学高分子科学与工程学院高分子材料工程国家重点实验室成都 610065
- 作者简介：
  
  Kai Zhang, E-mail: k.zhang@scu.edu.cn
  Ming-bo Yang, E-mail: yangmb@scu.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2023.23304
  CLC：
- Published：20 August 2024，
  
  Published Online：30 April 2024，
  
  Received：30 December 2023，
  
  Accepted：17 March 2024
- 稿件说明：
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冯子惟, 李梦蕾, 李培尧, 张凯, 杨鸣波. 利用机械化学法“一步”制备月桂酸纤维素酯. 高分子学报, 2024, 55(8), 986-1000

Feng, Z. W.; Li, M. L.; Li, P. Y.; Zhang, K.; Yang, M. B. Direct one-step synthesis of cellulose laurate ester via mechanochemical method. Acta Polymerica Sinica, 2024, 55(8), 986-1000
冯子惟, 李梦蕾, 李培尧, 张凯, 杨鸣波. 利用机械化学法“一步”制备月桂酸纤维素酯. 高分子学报, 2024, 55(8), 986-1000 DOI： 10.11777/j.issn1000-3304.2023.23304.

Feng, Z. W.; Li, M. L.; Li, P. Y.; Zhang, K.; Yang, M. B. Direct one-step synthesis of cellulose laurate ester via mechanochemical method. Acta Polymerica Sinica, 2024, 55(8), 986-1000 DOI： 10.11777/j.issn1000-3304.2023.23304.

摘要

以微晶纤维素(MCC)、三氟乙酸酐(TFAA)和长链月桂酸(LA)为原料，通过机械球磨一步法制备具有高取代度(DS

2.5)的月桂酸纤维素酯(LCE)，并探讨了机械化学条件对产物取代度、熔融行为和热稳定性的影响. 结果表明，随着球磨转速和球磨时间的增加，产物LCE的取代度提高，熔融温度下降，当DS≥2.81时，能得到完全熔融的LCE. 在投料比为1:6:3，且以400 r/min球磨处理4 h时，能制备流动温度(

)为115 ℃且分解温度高达324 ℃的纤维素月桂酸酯. 此外，初步探讨了在体系中引入PVA对过量的TFAA以及副产物三氟乙酸进行收酸的效果，分析数据表明PVA成功固定了三氟乙酸. 本策略在简化制备过程、减少单体用量、缩短反应时间和环境友好等方面相较于传统均相手段具有显著的优势，有望应用于工业上大规模地制备热塑性纤维素衍生物.

Abstract

This study presents a simple method for obtaining LCE with high degree of substitution (DS

2.5) by directly utilizing microcrystalline cellulose (MCC)

trifluoracetic anhydride (TFAA)

and long chain lauric acid (LA). The impact of ball milling speed

grinding time

and feeding ratio on substitution

melting behavior

and thermal stability is thoroughly investigated. The results show that with increasing ball milling speed and time

LCE substitution increased and the melting temperature decreased. When the DS is larger than 2.81

LCE can be completely melted. Optimal conditions involve a feed ratio of 1:6:3

and ball milling at 400 r/min for 4 h yields cellulose laurel ester with a flow temperature (

) of 115 ℃ and a decomposition temperature of 324 ℃. In addition

the introduction of PVA into the system is explored to mitigate excessive TFAA and the side product trifluoroacetic acid. The results show that PVA not only fixed trifluoroacetic acid successfully but also had little effect on the melting and processing properties of the product. This strategy has significant advantages over conventional homogeneous methods

such as streamlining the preparation process

reducing monomer quantities

shortening reaction time

and promoting environmental friendliness. Its potential application in large-scale industrial production of thermoplastic cellulose derivatives is promising.

关键词

纤维素月桂酸纤维素酯机械化学非均相反应

Keywords

CelluloseCellulose laurate esterMechanochemistryHeterogeneous reaction

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Direct One-step Synthesis of Cellulose Laurate Ester via Mechanochemical Method

DOI：10.11777/j.issn1000-3304.2023.23304

摘要

Abstract

关键词

Keywords

references