Carbon Nanotube Composite Fiber Reinforced by Aramid Nanofibers

Hong-ji Sun; Hong-yu Jiang; Pei-yu Liu; Zhe Yang; Kun Zhang; Pei-ning Chen; Hui-sheng Peng

doi:10.11777/j.issn1000-3304.2024.24015

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Carbon Nanotube Composite Fiber Reinforced by Aramid Nanofibers

Research Article | 更新时间：2024-09-25

- Carbon Nanotube Composite Fiber Reinforced by Aramid Nanofibers
  增强出版
- Acta Polymerica Sinica Vol. 55, Issue 7, Pages: 891-899(2024)
- 作者机构：
  
  聚合物分子工程国家重点实验室复旦大学高分子科学系纤维材料与器件研究院先进材料实验室上海 200438
- 作者简介：
  
  Pei-ning Chen, E-mail: peiningc@fudan.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2024.24015
  CLC：
- Published：20 July 2024，
  
  Published Online：03 April 2024，
  
  Received：15 January 2024，
  
  Accepted：19 February 2024
- 稿件说明：
移动端阅览
孙虹纪, 蒋鸿宇, 刘沛雨, 杨哲, 张琨, 陈培宁, 彭慧胜. 芳纶纳米纤维增强的碳纳米管复合纤维. 高分子学报, 2024, 55(7), 891-899

Sun, H. J.; Jiang, H. Y.; Liu, P. Y.; Yang, Z.; Zhang, K.; Chen, P. N.; Peng, H. S. Carbon nanotube composite fiber reinforced by aramid nanofibers. Acta Polymerica Sinica, 2024, 55(7), 891-899
孙虹纪, 蒋鸿宇, 刘沛雨, 杨哲, 张琨, 陈培宁, 彭慧胜. 芳纶纳米纤维增强的碳纳米管复合纤维. 高分子学报, 2024, 55(7), 891-899 DOI： 10.11777/j.issn1000-3304.2024.24015.

Sun, H. J.; Jiang, H. Y.; Liu, P. Y.; Yang, Z.; Zhang, K.; Chen, P. N.; Peng, H. S. Carbon nanotube composite fiber reinforced by aramid nanofibers. Acta Polymerica Sinica, 2024, 55(7), 891-899 DOI： 10.11777/j.issn1000-3304.2024.24015.

摘要

利用浮动催化化学气相沉积法可以将性能优异的碳纳米管(CNT)组装成碳纳米管纤维(CNTF)，但如何有效增强碳纳米管纤维内部碳纳米管及其管束之间的相互作用力，以大幅提升其力学和电学性能，是该领域的一个重要难题. 本文提出通过溶剂质子化策略，将芳纶纳米纤维引入碳纳米管纤维，制备得到了高性能的碳纳米管复合纤维材料，其拉伸强度达到1.23 GPa，杨氏模量达到26.97 GPa，相较于初始的碳纳米管纤维分别提升了92.1%和133.5%. 该复合纤维的比强度和比模量分别为28.67和628.67 cN/dtex，与芳纶纤维等高性能纤维相当. 此外，该复合纤维兼具良好的柔性与电学性能，可以直接作为纤维电子器件的电极材料，展现出良好的应用潜力.

Abstract

Carbon nanotubes (CNT) can be assembled into carbon nanotube fibers (CNTF) by floating catalytic chemical vapor deposition

but it remains challenging to effectively enhance the interaction force between carbon nanotubes and their bundles inside carbon nanotube fibers to effectively improve mechanical and electrical properties. In this study

we proposed to introduce aramid nanofibers into carbon nanotube fibers through solvent protonation to obtain high-performance carbon nanotube composite fibers. The composite fibers exhibited tensile strength of 1.23 GPa and the Young's modulus of 26.97 GPa

which were improved by 92.1% and 133.5% compared with the original carbon nanotube fibers

respectively. The specific strength and specific modulus of the composite fibers were 28.67 and 628.67 cN/dtex

which were comparable to those of high-performance fibers such as aramid fiber. In addition

the composite fibers showed good flexibility and electrical conductivity

which can be directly used as the electrode material in fiber electronic devices

showing good application potential.

关键词

碳纳米管纤维芳纶纳米纤维氢键高分子复合纤维

Keywords

Carbon nanotube fiberAramid nanofiberHydrogen bondPolymer composite fiber

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Related Institution

School of Chemistry, Xi'an Jiaotong University

College of Polymer Science and Engineering, Sichuan University

State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Laboratory of Advanced Materials, Fudan University

State Key Laboratory of Chemical Resource Engineering, Beijing Laboratory of Biomedical Materials, Beijing University of Chemical Technology

State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-dimension Materials, College of Material Science and Engineering, Donghua University

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