Synthesis and Properties of Low-foaming Nonionic Gemini Surfactants

Jie-wen Ma; Zhi-jun Zhang; Ya-qi Li; Bin Hu; You-mei Xing; Yun-jian Yin; Wei-hua Fang; Zhen Wu; Guo-jie Wang

doi:10.11777/j.issn1000-3304.2024.24083

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Synthesis and Properties of Low-foaming Nonionic Gemini Surfactants

Research Article | 更新时间：2024-11-15

- Synthesis and Properties of Low-foaming Nonionic Gemini Surfactants
- Acta Polymerica Sinica Vol. 55, Issue 10, Pages: 1356-1364(2024)
- 作者机构：
  
  1.北京科技大学材料科学与工程学院北京 100083
  2.杭州格林达电子材料股份有限公司杭州 310051
- 作者简介：
  
  Zhen Wu, E-mail: wuzhen@ustb.edu.cn
  Guo-jie Wang, E-mail: guojie.wang@mater.ustb.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2024.24083
  CLC：
- Published：20 October 2024，
  
  Published Online：14 June 2024，
  
  Received：19 March 2024，
  
  Accepted：30 April 2024
- 稿件说明：
移动端阅览
马杰文, 张之钧, 李雅琪, 胡斌, 邢攸美, 尹云舰, 方伟华, 吴振, 王国杰. 低泡型非离子Gemini表面活性剂的合成及性能研究. 高分子学报, 2024, 55(10), 1356-1364

Ma, J. W.; Zhang, Z. J.; Li, Y. Q.; Hu, B.; Xing, Y. M.; Yin, Y. J.; Fang, W. H.; Wu, Z.; Wang, G. J. Synthesis and properties of low-foaming nonionic gemini surfactants. Acta Polymerica Sinica, 2024, 55(10), 1356-1364
马杰文, 张之钧, 李雅琪, 胡斌, 邢攸美, 尹云舰, 方伟华, 吴振, 王国杰. 低泡型非离子Gemini表面活性剂的合成及性能研究. 高分子学报, 2024, 55(10), 1356-1364 DOI： 10.11777/j.issn1000-3304.2024.24083.

Ma, J. W.; Zhang, Z. J.; Li, Y. Q.; Hu, B.; Xing, Y. M.; Yin, Y. J.; Fang, W. H.; Wu, Z.; Wang, G. J. Synthesis and properties of low-foaming nonionic gemini surfactants. Acta Polymerica Sinica, 2024, 55(10), 1356-1364 DOI： 10.11777/j.issn1000-3304.2024.24083.

摘要

低泡型非离子双子(Gemini)表面活性剂在工业清洗、光刻胶显影等领域有着广泛的应用. 以二叔戊基氢醌为母体在碱催化的条件下与环氧乙烷通过开环反应合成了3种(

、

和

)不同聚氧乙烯链长度的非离子Gemini表面活性剂，通过表面张力仪、接触角测量仪等研究了不同聚氧乙烯链长度对表面张力、润湿性能、乳化性能、泡沫性能的影响. 在相同浓度下，随着聚氧乙烯链长度的增加，表面张力和接触角增加，乳化能力逐渐增强，发泡体积逐渐增加. 此外，3种非离子Gemini表面活性剂均具有优异的低泡性能，表面活性剂

发泡量低于传统表面活性剂Tween-80的1%，在工业清洗、光刻胶显影等领域中具有巨大的应用潜力.

Abstract

Low-foaming nonionic Gemini surfactants are widely used in industrial cleaning and photoresist development. In this study

three low-foaming nonionic Gem

ini surfactants are synthesized by using 2

5-di-tert-pentylbenzene-1

‍4-diol and ethylene oxide as raw materials

via

ring-opening reaction under alkali-catalyzed conditions. The surfactants

named

and

have different polyoxyethylene chain lengths of 6

and 8

respectively. The surface tension

critical micelle concentration (CMC)

wettability

emulsifying

and foaming properties of the three Gemini nonionic surfactants are carefully investigated. The surface tension of

and

decreases with increasing concentration and remains unchanged when CMC is reached. While at the same concentration

the surface tension increases with the increase of polyoxymethylene chain length due to increased hydrophilicity. The CMC of

and

are 1.225 mmol/L

1.016 mmol/L

and 0.700 mmol/L

respectively

decreasing with the increment of polyoxymethylene chain length. The contact angle of

and

decreases with increasing concentration and remains unchanged when the concentration is higher than CMC. The contact angle increases with the increase of polyoxymethylene chain length at the same concentration. The emulsion stability of

and

increases with increasing concentration and it increases with the increasement of the polyoxyethylene chain length at the same time. The initial foaming volume of

and

increases with increasing concentration and the chain length of polyoxymethylene at the same concentration. In particular

has the lowest initial foaming volume

which is 1% of the conventional nonionic surfactant Tween-80

exhibiting excellent low-foaming properties.

and

also show good low-foaming ability

with less than 20% of the foaming ability of conventional surfactant Tween-80. Overall

the three Gemini surfactants offer excellent low-foaming properties while reducing surface tension

making them well-suited for real-world applications such as industrial cleaning and developer fluids.

关键词

非离子Gemini表面活性剂低泡性表面张力润湿性能乳化性能

Keywords

Nonionic Gemini surfactantsLow-foamingSurface tensionWettabilityEmulsifying property

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