Advances in CO<sub>2</sub> Stimuli-responsive Polymers

Ming-yu Ding; Qian-yu Jiang; Peng-chao Wu; Hai-bao Jin; Xiao-ling Yang; Shao-liang Lin

doi:10.11777/j.issn1000-3304.2024.24250

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Advances in CO₂ Stimuli-responsive Polymers

Review | 更新时间：2025-06-17

- Advances in CO₂ Stimuli-responsive Polymers
- Acta Polymerica Sinica Vol. 56, Issue 5, Pages: 690-704(2025)
- 作者机构：
  
  上海市先进聚合物材料重点实验室华东理工大学材料科学与工程学院上海 200237
- 作者简介：
  
  Hai-bao Jin, E-mail: haibaojin@ecust.edu.cn
  Xiao-ling Yang, E-mail: xlyang@ecust.edu.cn
  Shao-liang Lin, E-mail: slin@ecust.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2024.24250
  CLC：
- CSTR：32057.14.GFZXB.2024.7330
- Received：09 October 2024，
  
  Accepted：11 December 2024，
  
  Published Online：18 February 2025，
  
  Published：20 May 2025
- 稿件说明：
移动端阅览
丁明宇, 蒋钱宇, 武鹏超, 靳海宝, 杨晓玲, 林绍梁. 二氧化碳刺激响应型聚合物的研究进展. 高分子学报, 2025, 56(5), 690-704

Ding, M. Y.; Jiang, Q. Y.; Wu, P. C.; Jin, H. B.; Yang, X. L.; Lin, S. L. Advances in CO₂ stimuli-responsive polymers. Acta Polymerica Sinica, 2025, 56(5), 690-704
丁明宇, 蒋钱宇, 武鹏超, 靳海宝, 杨晓玲, 林绍梁. 二氧化碳刺激响应型聚合物的研究进展. 高分子学报, 2025, 56(5), 690-704 DOI： 10.11777/j.issn1000-3304.2024.24250. CSTR： 32057.14.GFZXB.2024.7330.

Ding, M. Y.; Jiang, Q. Y.; Wu, P. C.; Jin, H. B.; Yang, X. L.; Lin, S. L. Advances in CO₂ stimuli-responsive polymers. Acta Polymerica Sinica, 2025, 56(5), 690-704 DOI： 10.11777/j.issn1000-3304.2024.24250. CSTR： 32057.14.GFZXB.2024.7330.

摘要

二氧化碳(CO

)刺激响应型聚合物是指在向聚合物体系中引入或排除CO

后，聚合物物理结构与化学性质等发生可逆变化的“智能”大分子，在各科学领域具有广阔的应用前景. 本文从CO

响应基团出发，分类介绍不同种类CO

响应基团的作用机理，随后依次综述了CO

响应型聚合物的合成、表征、智能体系及其应用领域. 最后讨论与总结该类聚合物材料现存的挑战，并对其未来应用前景与发展方向进行了展望.

Abstract

is a benign

inexpensive

abundant

and non-toxic trigger for stimuli-responsive materials

and has received increasing attention in recent years. CO

stimuli-responsive polymers

as an attractive type of "smart" macromolecules

undergo a reversible transition in the physical and chemical properties of polymers when CO

is introduced or excluded from the polymer system

exhibiting broad application prospects in various scientific fields. Herein

this review summarizes the recent development of CO

-responsive polymers and introduces the working mechanisms of different types of CO

-responsive groups from chemical structures

including amidines

tertiary amines

guanidines

imidazoles

and frustrated Lewis pair (FLP). Methods for the synthesis of CO

-responsive polymers are introduced

including free radical polymerization (FRP)

reversible addition-fragmentation chain-transfer (RAFT)

atom transfer radical polymerization (ATRP)

nitroxide-mediated polymerization (NMP)

and postpolymerization modification. Subsequently

the techniques for the characterization of CO

-responsive polymers are summarized

including structural characterization using

H-NMR and FTIR

and property characterization using measurements of pH

conductivity

Zeta potential

and transmittance. Assemblies

latexes

gels

composites

and membranes with CO

responsiveness are introduced separately from the perspective of smart response systems

and the current status of these developments is summarized. Among these

research on the second generation of CO

-responsive systems is highlighted

which are based on the "dynamic gas bridge" formed between boron/phosphorus frustrated Lewis acid-base pairs and carbon dioxide gas molecules. Meanwhile

a stepwise summary of CO

-responsive polymers for CO

capture

smart catalysts

protein adsorption

controllable separation

fluorescence sensing

and drug delivery is presented. Eventually

the current challenges toward the development of CO

-responsive polymers are discussed and summarized

accompanied by an outlook of the future application prospects and development directions. Large-scale production of CO

-responsive polymers remains a significant challenge

while further investigation of the response mechanism to improve the sensitivity and cyclic stability of the response process will provide the basis for the development of CO

-responsive materials that have a broader range of applications.

关键词

Keywords

references

Stuart M. A. C. ; Huck W. T. S. ; Genzer J. ; Müller M. ; Ober C. ; Stamm M. ; Sukhorukov G. B. ; Szleifer I. ; Tsukruk V. V. ; Urban M. ; Winnik F. ; Zauscher S. ; Luzinov I. ; Minko S. Emerging applications of stimuli-responsive polymer materials . Nat. Mater. , 2010 , 9 , 101 - 113 . doi: 10.1038/nmat2614 http://dx.doi.org/10.1038/nmat2614

Sato O. Dynamic molecular crystals with switchable physical properties . Nat. Chem. , 2016 , 8 ( 7 ), 644 - 656 . doi: 10.1038/nchem.2547 http://dx.doi.org/10.1038/nchem.2547

Raje V. P. ; Morgado P. I. ; Ribeiro M. P. ; Correia I. J. ; Bonifácio V. D. B. ; Branco P. S. ; Aguiar-Ricardo A. Dual on-off and off-on switchable oligoaziridine biosensor . Biosens. Bioelectron. , 2013 , 39 ( 1 ), 64 - 69 . doi: 10.1016/j.bios.2012.06.047 http://dx.doi.org/10.1016/j.bios.2012.06.047

Huo M. ; Yuan J. Y. ; Tao L. ; Wei Y. Redox-responsive polymers for drug delivery: from molecular design to applications . Polym. Chem. , 2014 , 5 ( 5 ), 1519 - 1528 . doi: 10.1039/c3py01192e http://dx.doi.org/10.1039/c3py01192e

Gil E. S. ; Hudson S. M. Stimuli-reponsive polymers and their bioconjugates . Prog. Polym. Sci. , 2004 , 29 ( 12 ), 1173 - 1222 . doi: 10.1016/j.progpolymsci.2004.08.003 http://dx.doi.org/10.1016/j.progpolymsci.2004.08.003

Hu X. L. ; Zhang Y. Q. ; Xie Z. G. ; Jing X. B. ; Bellotti A. ; Gu Z. Stimuli-responsive polymersomes for biomedical applications . Biomacromolecules , 2017 , 18 ( 3 ), 649 - 673 . doi: 10.1021/acs.biomac.6b01704 http://dx.doi.org/10.1021/acs.biomac.6b01704

Cunningham, M. F.; Jessop, P. G. CO 2 -switchable colloids . Chem. Commun. , 2023 , 59 ( 89 ), 13272 - 13288 . doi: 10.1039/d3cc03929c http://dx.doi.org/10.1039/d3cc03929c

Du N. Y. ; Park H. B. ; Robertson G. P. ; Dal-Cin M. M. ; Visser T. ; Scoles L. ; Guiver M. D. Polymer nanosieve membranes for CO 2 -capture applications . Nat. Mater. , 2011 , 10 ( 5 ), 372 - 375 . doi: 10.1038/nmat2989 http://dx.doi.org/10.1038/nmat2989

Lin, S. J.; Theato, P. CO 2 -responsive polymers . Macromol. Rapid Commun. , 2013 , 34 ( 14 ), 1118 - 1133 . doi: 10.1002/marc.201300288 http://dx.doi.org/10.1002/marc.201300288

Cunningham M. F. ; Jessop P. G. Carbon dioxide-switchable polymers: where are the future opportunities? Macromolecules , 2019 , 52 ( 18 ), 6801 - 6816 . doi: 10.1021/acs.macromol.9b00914 http://dx.doi.org/10.1021/acs.macromol.9b00914

Zeng R. J. ; Chen L. ; Yan Q. CO 2-folded single-chain nanoparticles as recyclable, improved carboxylase mimics. Angew. Chem. Int. Ed. , 2020 , 59 ( 42 ), 18418 - 18422 . doi: 10.1002/anie.202006842 http://dx.doi.org/10.1002/anie.202006842

Darabi A. ; Jessop P. G. ; Cunningham M. F. CO 2-responsive polymeric materials: synthesis, self-assembly, and functional applications. Chem. Soc. Rev. , 2016 , 45 ( 15 ), 4391 - 4436 . doi: 10.1039/c5cs00873e http://dx.doi.org/10.1039/c5cs00873e

Png Z. M. ; Wang C. G. ; Yeo J. C. C. ; Lee J. J. C. ; Surat'man N. E. ; Tan Y. L. ; Liu H. F. ; Wang P. ; Tan B. H. ; Xu J. W. ; Loh X. J. ; Zhu Q. Stimuli-responsive structure-property switchable polymer materials . Mol. Syst. Des. Eng. , 2023 , 8 ( 9 ), 1097 - 1129 . doi: 10.1039/d3me00002h http://dx.doi.org/10.1039/d3me00002h

Jiang B. X. ; Zhang Y. C. ; Huang X. D. ; Kang T. ; Severtson S. J. ; Wang W. J. ; Liu P. W. Tailoring CO 2 -responsive polymers and nanohybrids for green chemistry and processes . Ind. Eng. Chem. Res. , 2019 , 58 ( 33 ), 15088 - 15108 . doi: 10.1021/acs.iecr.9b02433 http://dx.doi.org/10.1021/acs.iecr.9b02433

Lin S. J. ; Shang J. J. ; Zhang X. X. ; Theato P. " Breathing" CO 2 -, O 2 -, and light-responsive vesicles from a triblock copolymer for rate-tunable controlled release. Macromol. Rapid Commun. , 2018 , 39 ( 1 ), 1700313 . doi: 10.1002/marc.201700313 http://dx.doi.org/10.1002/marc.201700313

Sundberg R. J. ; Martin R. B. Interactions of histidine and other imidazole derivatives with transition metal ions in chemical and biological systems . Chem. Rev. , 1974 , 74 ( 4 ), 471 - 517 . doi: 10.1021/cr60290a003 http://dx.doi.org/10.1021/cr60290a003

Yan Q. ; Wang J. B. ; Yin Y. W. ; Yuan J. Y. Breathing polymersomes: CO 2-tuning membrane permeability for size-selective release, separation, and reaction. Angew. Chem. Int. Ed. , 2013 , 52 ( 19 ), 5070 - 5073 . doi: 10.1002/anie.201300397 http://dx.doi.org/10.1002/anie.201300397

Guo Z. R. ; Feng Y. J. ; Wang Y. ; Wang J. Y. ; Wu Y. F. ; Zhang Y. M. A novel smart polymer responsive to CO 2 . Chem. Commun. , 2011 , 47 ( 33 ), 9348 - 9350 . doi: 10.1039/c1cc12388b http://dx.doi.org/10.1039/c1cc12388b

闫强 , 赵越 . 二氧化碳响应性聚合物及其应用进展 . 高分子材料科学与工程 , 2014 , 30 ( 2 ), 170 - 178 .

Dai Y. ; Ruan X. H. ; Yan Z. J. ; Yang K. ; Yu M. ; Li H. ; Zhao W. ; He G. H. Imidazole functionalized graphene oxide/PEBAX mixed matrix membranes for efficient CO 2 capture . Sep. Purif. Technol. , 2016 , 166 , 171 - 180 . doi: 10.1016/j.seppur.2016.04.038 http://dx.doi.org/10.1016/j.seppur.2016.04.038

Pinaud J. ; Vignolle J. ; Gnanou Y. ; Taton D. Poly( N -heterocyclic-carbene)s and their CO 2 adducts as recyclable polymer-supported organocatal ysts for benzoin condensation and transesterification reactions . Macromolecules , 2011 , 44 ( 7 ), 1900 - 1908 . doi: 10.1021/ma1024285 http://dx.doi.org/10.1021/ma1024285

Lin S. J. ; Shang J. J. ; Theato P. Facile fabrication of CO 2 -responsive nanofibers from photo-cross-linked poly(pentafluorophenyl acrylate) nanofibers . ACS Macro Lett. , 2018 , 7 ( 4 ), 431 - 436 . doi: 10.1021/acsmacrolett.8b00115 http://dx.doi.org/10.1021/acsmacrolett.8b00115

Song Z. F. ; Wang K. ; Gao C. Q. ; Wang S. ; Zhang W. Q. A new thermo-, pH-, and CO 2-responsive homopolymer of poly[N-‍[2-‍(diethylamino)ethyl ] acrylamide ] : is the diethylamino group underestimated? Macromolecules , 2016 , 49 ( 1 ), 162 - 171 . doi: 10.1021/acs.macromol.5b02458 http://dx.doi.org/10.1021/acs.macromol.5b02458

Zeng M. ; Huo M. ; Feng Y. J. ; Yuan J. Y. CO 2 -breathing polymer assemblies via one-pot sequential RAFT dispersion polymerization . Macromol. Rapid Commun. , 2018 , 39 ( 15 ), e 1800291 . doi: 10.1002/marc.201800291 http://dx.doi.org/10.1002/marc.201800291

Wang K. ; Zhang J. L. ; Si M. Y. ; Wang Z. L. ; An L. R. ; Liu G. Y. ; Zeng Y. F. Novel temperature/pH/CO 2 /redox-quadruple-respon sive ferrocene-containing homopolymers and their self-assembly behavior . Macromolecules , 2023 , 56 ( 22 ), 9127 - 9137 . doi: 10.1021/acs.macromol.3c02068 http://dx.doi.org/10.1021/acs.macromol.3c02068

van de Wetering P. ; Moret E. E. ; Schuurmans-Nieuwenbroek N. M. E. ; van Steenbergen M. J. ; Hennink W. E. Structure-activity relationships of water-soluble cationic methacrylate/methacrylamide polymers for nonviral gene delivery . Bioconjugate Chem. , 1999 , 10 ( 4 ), 589 - 597 . doi: 10.1021/bc980148w http://dx.doi.org/10.1021/bc980148w

Zhang D. Y. ; Boopathi S. K. ; Hadjichristidis N. ; Gnanou Y. ; Feng X. S. Metal-free alternating copolymerization of CO 2 epoxideswith: fulfilling "green" synthesis and activity. J. Am. Chem. Soc. , 2016 , 138 ( 35 ), 11117 - 11120 . doi: 10.1021/jacs.6b06679 http://dx.doi.org/10.1021/jacs.6b06679

Kubas, G. J. Breaking the H 2 marriage and reuniting the couple . Science , 2006 , 314 ( 5802 ), 1096 - 1097 . doi: 10.1126/science.1135430 http://dx.doi.org/10.1126/science.1135430

牟桂芳 , 杨翠琴 , 闫强 . 气体调控的高分子自组装 . 高分子学报 , 2024 , 55 ( 7 ), 781 - 801 .

McCahill J. S. J. ; Welch G. C. ; Stephan D. W. Reactivity of "frustrated Lewis pairs": three-component reactions of phosphines, a borane, and olefins . Angew. Chem. Int. Ed. , 2007 , 46 ( 26 ), 4968 - 4971 . doi: 10.1002/anie.200701215 http://dx.doi.org/10.1002/anie.200701215

Chase P. A. ; Stephan D. W. Hydrogen and amine activation by a frustrated Lewis pair of a bulky N-heterocyclic carbene and B(C 6 F 5 ) 3 . Angew. Chem. Int. Ed., 2008, 47 ( 39 ), 7433 - 7437 .

Moebs-Sanchez S. ; Bouhadir G. ; Saffon N. ; Maron L. ; Bourissou D. Tracking reactive intermediates in phosphine-promoted reactions with ambiphilic phosphino-boranes . Chem. Commun. , 2008 ( 29 ), 3435 - 3437 . doi: 10.1039/b805161e http://dx.doi.org/10.1039/b805161e

Su X. ; Jessop P. G. ; Cunningham M. F. Switchable surfactants at the polystyrene-water interface: effect of molecular structure . Green Mater. , 2014 , 2 ( 2 ), 69 - 81 . doi: 10.1680/gmat.13.00015 http://dx.doi.org/10.1680/gmat.13.00015

Liu H. B. ; Zhao Y. ; Dreiss C. A. ; Feng Y. J. CO 2 -switchable multi-compartment micelles with segregated corona . Soft Matter , 2014 , 10 ( 34 ), 6387 - 6391 . doi: 10.1039/c4sm01207k http://dx.doi.org/10.1039/c4sm01207k

Zhang Q. ; Wang W. J. ; Lu Y. Y. ; Li B. G. ; Zhu S. P. Reversibly coagulatable and redispersible polystyrene latex prepared by emulsion polymerization of styrene containing switchable amidine . Macromolecules , 2011 , 44 ( 16 ), 6539 - 6545 . doi: 10.1021/ma201056g http://dx.doi.org/10.1021/ma201056g

Huo M. ; Du H. T. ; Zeng M. ; Pan L. ; Fang T. ; Xie X. M. ; Wei Y. ; Yuan J. Y. CO 2 -stimulated morphology transition of ABC miktoarm star terpolymer assemblies . Polym. Chem. , 2017 , 8 ( 18 ), 2833 - 2840 . doi: 10.1039/c7py00214a http://dx.doi.org/10.1039/c7py00214a

Darabi A. ; Shirin-Abadi A. R. ; Jessop P. G. ; Cunningham M. F. Nitroxide-mediated polymerization of 2-(diethylamino)ethyl methacrylate (DEAEMA) in water . Macromolecules , 2015 , 48 ( 1 ), 72 - 80 . doi: 10.1021/ma502175c http://dx.doi.org/10.1021/ma502175c

Yuan W. Z. ; Huang W. W. ; Zou H. Synthesis and properties of CO 2 -responsive copolymer by the combination of reversible addition-fragmentation chain transfer polymerization and click chemistry . Polym. Bull. , 2016 , 73 ( 8 ), 2199 - 2210 . doi: 10.1007/s00289-016-1603-9 http://dx.doi.org/10.1007/s00289-016-1603-9

Zhang D. P. ; Fan Y. J. ; Chen H. ; Trépout S. ; Li M. H. CO 2 -activated reversible transition between polymersomes and micelles with AIE fluorescence . Angew. Chem. Int. Ed. , 2019 , 58 ( 30 ), 10260 - 10265 . doi: 10.1002/anie.201905089 http://dx.doi.org/10.1002/anie.201905089

Chen L. ; Liu R. J. ; Yan Q. Polymer meets frustrated Lewis pair: second-generation CO 2-responsive nanosystem for sustainable CO2 conversion. Angew. Chem. Int. Ed. , 2018 , 57 ( 30 ), 9336 - 9340 . doi: 10.1002/anie.201804034 http://dx.doi.org/10.1002/anie.201804034

Yan Q. ; Zhou R. ; Fu C. K. ; Zhang H. J. ; Yin Y. W. ; Yuan J. Y. CO 2 -responsive polymeric vesicles that breathe . Angew. Chem. Int. Ed. , 2011 , 50 ( 21 ), 4923 - 4927 . doi: 10.1002/anie.201100708 http://dx.doi.org/10.1002/anie.201100708

周硕 , 杨松铭 , 袁金颖 . 基于二氧化碳响应的聚合物及复合材料的构建与功能 . 高分子学报 , 2023 , 54 ( 10 ), 1409 - 1425 .

Yan, Q.; Zhao, Y. CO 2 -stimulated diversiform deformations of polymer assemblies . J. Am. Chem. Soc. , 2013 , 135 ( 44 ), 16300 - 16303 . doi: 10.1021/ja408655n http://dx.doi.org/10.1021/ja408655n

Zhu J. N. ; Gong Z. H. ; Yang C. Q. ; Yan Q. Reshaping membrane polymorphism of polymer vesicles through dynamic gas exchange . J. Am. Chem. Soc. , 2021 , 143 ( 48 ), 20183 - 20191 . doi: 10.1021/jacs.1c07838 http://dx.doi.org/10.1021/jacs.1c07838

Gong Z. H. ; Wang Y. X. ; Yan Q. Polymeric partners breathe together: using gas to direct polymer self-assembly via gas-bridging chemistry . Sci. China Chem. , 2022 , 65 ( 7 ), 1401 - 1410 . doi: 10.1007/s11426-022-1266-8 http://dx.doi.org/10.1007/s11426-022-1266-8

Zhang Y. M. ; Guo S. ; Ren X. F. ; Liu X. F. ; Fang Y. CO 2 and redox dual responsive Pickering emulsion . Langmuir , 2017 , 33 ( 45 ), 12973 - 12981 . doi: 10.1021/acs.langmuir.7b02976 http://dx.doi.org/10.1021/acs.langmuir.7b02976

Liu Y. X. ; Jessop P. G. ; Cunningham M. ; Eckert C. A. ; Liotta C. L. Switchable surfactants . Science , 2006 , 313 ( 5789 ), 958 - 960 . doi: 10.1126/science.1128142 http://dx.doi.org/10.1126/science.1128142

Mu M. ; Yuan R. ; Zhang G. H. ; Wu D. G. ; Quan H. P. ; Han P. H. ; Feng Y. J. Tuning CO 2 -induced reversible redispersion or irreversible destabilisation for latex separation . J. Colloid Interface Sci. , 2020 , 573 , 250 - 262 . doi: 10.1016/j.jcis.2020.03.121 http://dx.doi.org/10.1016/j.jcis.2020.03.121

Wang, Y. X.; Yan, Q. CO 2 -fueled transient breathing nanogels that couple nonequilibrium catalytic polymerization . Angew. Chem. Int. Ed. , 2023 , 62 ( 14 ), e202217001 . doi: 10.1002/anie.202217001 http://dx.doi.org/10.1002/anie.202217001

Nagai D. ; Suzuki A. ; Kuribayashi T. Synthesis of hydrogels from polyallylamine with carbon dioxide as gellant: development of reversible CO 2 absorbent . Macromol. Rapid Commun. , 2011 , 32 ( 4 ), 404 - 410 . doi: 10.1002/marc.201000601 http://dx.doi.org/10.1002/marc.201000601

Jansen-van Vuuren R. D. ; Naficy S. ; Ramezani M. ; Cunningham M. ; Jessop P. CO 2 -responsive gels . Chem. Soc. Rev. , 2023 , 52 ( 10 ), 3470 - 3542 . doi: 10.1039/d2cs00053a http://dx.doi.org/10.1039/d2cs00053a

Jia Y. G. ; Zhang M. ; Zhu X. X. CO 2 -switchable self-healing host—guest hydrogels . Macromolecules , 2017 , 50 ( 24 ), 9696 - 9701 . doi: 10.1021/acs.macromol.7b02163 http://dx.doi.org/10.1021/acs.macromol.7b02163

Chen L. ; Liu R. J. ; Hao X. ; Yan Q. CO 2 -cross-linked frustrated Lewis networks as gas-regulated dynamic covalent materials . Angew. Chem. , 2019 , 131 ( 1 ), 270 - 274 . doi: 10.1002/ange.201812365 http://dx.doi.org/10.1002/ange.201812365

Liu R. J. ; Wang Y. X. ; Yan Q. CO 2 -strengthened double-cross-linked polymer gels from frustrated Lewis pair networks . Macromol. Rapid Commun. , 2021 , 42 ( 6 ), 2000699 . doi: 10.1002/marc.202170016 http://dx.doi.org/10.1002/marc.202170016

Guo Z. R. ; Feng Y. J. ; He S. ; Qu M. Z. ; Chen H. L. ; Liu H. B. ; Wu Y. F. ; Wang Y. CO 2 -responsive "smart" single-walled carbon nanotubes . Adv. Mater. , 2013 , 25 ( 4 ), 584 - 590 . doi: 10.1002/adma.201202991 http://dx.doi.org/10.1002/adma.201202991

Yoon B. ; Choi S. J. ; Swager T. M. ; Walsh G. F. Switchable single-walled carbon nanotube—polymer composites for CO 2 sensing . ACS Appl. Mater. Interfaces , 2018 , 10 ( 39 ), 33373 - 33379 . doi: 10.1021/acsami.8b11689 http://dx.doi.org/10.1021/acsami.8b11689

Kota A. K. ; Kwon G. ; Choi W. ; Mabry J. M. ; Tuteja A. Hygro-responsive membranes for effective oil-water separation . Nat. Commun. , 2012 , 3 , 1025 . doi: 10.1038/ncomms2027 http://dx.doi.org/10.1038/ncomms2027

Che H. L. ; Huo M. ; Peng L. ; Fang T. ; Liu N. ; Feng L. ; Wei Y. ; Yuan J. Y. CO 2 -responsive nanofibrous membranes with switchable oil/water wettability . Angew. Chem. Int. Ed. , 2015 , 54 ( 31 ), 8934 - 8938 . doi: 10.1002/anie.201501034 http://dx.doi.org/10.1002/anie.201501034

Wang Y. Y. ; Yang S. K. ; Zhang J. W. ; Chen Z. ; Zhu B. ; Li J. ; Liang S. J. ; Bai Y. X. ; Xu J. H. ; Rao D. W. ; Dong L. L. ; Zhang C. F. ; Yang X. W. Scalable and switchable CO 2 -responsive membranes with high wettability for separation of various oil/water systems . Nat. Commun. , 2023 , 14 ( 1 ), 1108 . doi: 10.1038/s41467-023-36685-9 http://dx.doi.org/10.1038/s41467-023-36685-9

Zhang S. ; He L. N. Capture and fixation of CO 2 promoted by guanidine derivatives . Aust. J. Chem. , 2014 , 67 ( 7 ), 980 . doi: 10.1071/ch14125 http://dx.doi.org/10.1071/ch14125

Gabriele B. ; Della Ca N. ; Mancuso R. ; Veltri L. ; Ziccarelli I. Amidine- and guanidine-based synthetic methods for CO 2 capture and utilization . Curr. Opin. Green Sustain. Chem. , 2023 , 41 , 100793 . doi: 10.1016/j.cogsc.2023.100793 http://dx.doi.org/10.1016/j.cogsc.2023.100793

Qu Q. H. ; Cheng L. Y. ; Wang P. R. ; Fang C. ; Li H. P. ; Ding J. ; Wan H. ; Guan G. F. Guanidine-functionalized basic binuclear poly(ionic liquid)s for low partial pressure CO 2 fixation into cyclic carbonate . Sep. Purif. Technol. , 2024 , 339 , 126682 . doi: 10.1016/j.seppur.2024.126682 http://dx.doi.org/10.1016/j.seppur.2024.126682

Feng A. C. ; Wang Y. ; Peng L. ; Wang X. S. ; Yuan J. Y. Breathing catalyst-supports: CO 2 adjustable and magnetic recyclable "smart" hybrid nanoparticles . RSC Adv. , 2016 , 6 ( 99 ), 97030 - 97035 . doi: 10.1039/c6ra22762g http://dx.doi.org/10.1039/c6ra22762g

Liu H. B. ; Yang X. H. ; Wang J. X. ; Meng Q. J. ; Qian L. W. ; Wu H. W. ; Duan C. ; Li Z. J. ; Zhou H. W. Gas responsive cellulose fibers for capturing and releasing of dyes and proteins from water by packing a smart separation column . Cellulose , 2020 , 27 ( 12 ), 7127 - 7138 . doi: 10.1007/s10570-020-03277-5 http://dx.doi.org/10.1007/s10570-020-03277-5

Glasing J. ; Jessop P. G. ; Champagne P. ; Cunningham M. F. Graft-modified cellulose nanocrystals as CO 2 -switchable Pickering emulsifiers . Polym. Chem. , 2018 , 9 ( 28 ), 3864 - 3872 . doi: 10.1039/c8py00417j http://dx.doi.org/10.1039/c8py00417j

Wei H. B. ; Zhang J. L. ; Shi N. ; Liu Y. ; Zhang B. ; Zhang J. ; Wan X. H. A recyclable polyoxometalate-based supramolecular chemosensor for efficient detection of carbon dioxide . Chem. Sci. , 2015 , 6 ( 12 ), 7201 - 7205 . doi: 10.1039/c5sc02020d http://dx.doi.org/10.1039/c5sc02020d

Hsiao Y. N. ; Ilhami F. B. ; Cheng C. C. CO 2 -responsive water-soluble conjugated polymers as a multifunctional fluorescent probe for bioimaging applications . Biomacromolecules , 2024 , 25 ( 2 ), 997 - 1008 . doi: 10.1021/acs.biomac.3c01078 http://dx.doi.org/10.1021/acs.biomac.3c01078

Bayle E. A. ; Ilhami F. B. ; Huang S. Y. ; Su T. H. ; Shieh Y. T. ; Chen J. K. ; Cheng C. C. Development of CO 2 -responsive supramolecular drug carrier system for potential application in anticancer treatment . Appl. Mater. Today , 2023 , 33 , 101865 . doi: 10.1016/j.apmt.2023.101865 http://dx.doi.org/10.1016/j.apmt.2023.101865

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Advances in CO2 Stimuli-responsive Polymers

DOI：10.11777/j.issn1000-3304.2024.24250

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Advances in CO₂ Stimuli-responsive Polymers