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A Solvent/Light Dual Responsive Inverse Opal Photonic Crystal Polymer Composite Film
- Acta Polymerica Sinica Vol. 56, Issue 4, Pages: 590-597(2025)
- 作者机构：
1.天津大学理学院 天津 300350
2.吉林大学化学学院 长春 130012
- 作者简介：
Yu-lan Chen, E-mail: yulanchen@jlu.edu.cn
- 基金信息：
DOI：10.11777/j.issn1000-3304.2024.24259
CLC：- CSTR：32057.14.GFZXB.2024.7323
Received：25 October 2024，
Accepted：2024-11-15，
Published Online：21 February 2025，
Published：20 April 2025
- 稿件说明：
移动端阅览
王亚欣, 陈于蓝. 溶剂/光双重响应性反蛋白石光子晶体-聚合物复合薄膜. 高分子学报, 2025, 56(4), 590-597
Wang, Y. X.; Chen, Y. L. A solvent/light dual responsive inverse opal photonic crystal polymer composite film. Acta Polymerica Sinica, 2025, 56(4), 590-597
王亚欣, 陈于蓝. 溶剂/光双重响应性反蛋白石光子晶体-聚合物复合薄膜. 高分子学报, 2025, 56(4), 590-597 DOI： 10.11777/j.issn1000-3304.2024.24259. CSTR： 32057.14.GFZXB.2024.7323.
Wang, Y. X.; Chen, Y. L. A solvent/light dual responsive inverse opal photonic crystal polymer composite film. Acta Polymerica Sinica, 2025, 56(4), 590-597 DOI： 10.11777/j.issn1000-3304.2024.24259. CSTR： 32057.14.GFZXB.2024.7323.
摘要
以结构色光子晶体材料为模板，将偶氮苯与丙烯酸酯类单体和交联剂共聚，通过聚合物亲疏水性的调控，成功制备了一种对溶剂和光双重刺激响应的反蛋白石结构复合薄膜. 通过测试薄膜的反射光谱和接触角，确定了聚合物的最佳组成. 利用不同直径的二氧化硅光子晶体获得的薄膜在不同溶剂中实现了可见光范围的宽波段反射. 这种具备双重响应性质的复合薄膜在紫外光照射下可以写入信息，并在干燥环境中加密图案，而在溶剂中能够快速、高对比度地显示图案，有望应用于高级别的防伪、信息加密与存储、传感等领域.
Abstract
Recently
photonic crystals and their composite films have attracted much attention due to their unique optical properties and promising applications in optical sensors
optical communication
anti-counterfeiting techniques and so on. Photonic crystal-polymer composite films with multimodal responsiveness are highly desirable yet still limited. In this work
a new kind of inverse opal composite polymer films responsive to both solvent and light has been successfully prepared
by copolymerizing azobenzene (AzoMMA) with different hydrophilic/hydrophobic acrylic monomers (butyl methacrylate (BMA)
poly(ethylene glycol) acrylate (PEGDA)) and cross-linking agent (ethoxylated trimethylolpropane triacrylate (ETPTA)) and using structural colored photonic crystals as the template. The optimal composition of the polymers is determined (AzoMMA:PEGDA:BMA:ETPTA = 1:4:8:1
molar ratio) according to the reflection spectra and contact angle testing. Wideband visible light reflection is achieved for films that are obtained by using silica photonic crystals with different diameters and in different solvents. This composite film with dual responsive properties can be used to store information under ultraviolet light irradiation
encrypt patterns in its dry state
and decrypt the information quickly and with a high-contrast visual effect in solvents. This material is thus expected to be applied in high-level anti-counterfeiting
encryption storage of information
sensing and other fields.
关键词
Keywords
references
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