From Ring-opening Polymerization of <italic style="font-style: italic">O</italic>-carboxyanhydride to the Discovery of Anion-binding Catalytic Polymerization

Mao-sheng Li; You-hua Tao

doi:10.11777/j.issn1000-3304.2024.24271

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From Ring-opening Polymerization of O-carboxyanhydride to the Discovery of Anion-binding Catalytic Polymerization

Feature Article | 更新时间：2025-02-27

- From Ring-opening Polymerization of O-carboxyanhydride to the Discovery of Anion-binding Catalytic Polymerization
- Acta Polymerica Sinica Vol. 56, Issue 3, Pages: 361-376(2025)
- 作者机构：
  
  中国科学院长春应用化学研究所中国科学院生态环境高分子材料重点实验室长春 130022
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2024.24271
  CLC：
- CSTR：32057.14.GFZXB.2024.7335
- Received：04 November 2024，
  
  Accepted：2024-12-19，
  
  Published Online：23 January 2025，
  
  Published：20 March 2025
- 稿件说明：
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李茂盛, 陶友华. 从O-羧基环内酸酐的开环聚合到阴离子结合催化聚合方法的发现. 高分子学报, 2025, 56(3), 361-376

Li, M. S.; Tao, Y. H. From ring-opening polymerization of O-carboxyanhydride to the discovery of anion-binding catalytic polymerization. Acta Polymerica Sinica, 2025, 56(3), 361-376
李茂盛, 陶友华. 从O-羧基环内酸酐的开环聚合到阴离子结合催化聚合方法的发现. 高分子学报, 2025, 56(3), 361-376 DOI： 10.11777/j.issn1000-3304.2024.24271. CSTR： 32057.14.GFZXB.2024.7335.

Li, M. S.; Tao, Y. H. From ring-opening polymerization of O-carboxyanhydride to the discovery of anion-binding catalytic polymerization. Acta Polymerica Sinica, 2025, 56(3), 361-376 DOI： 10.11777/j.issn1000-3304.2024.24271. CSTR： 32057.14.GFZXB.2024.7335.

摘要

随着全球社会对可持续发展的日益重视，探索高效、绿色、安全及经济的可持续聚合新方法，实现高分子材料的精准合成，已成为高分子合成化学的研究重点. 近年来，我们突破链式聚合主要依赖金属催化剂调控链末端的局限，创新性地提出阴离子结合催化聚合理念，旨在通过氢键给体与阴离子物种之间的非共价相互作用来动态结合、识别与活化链末端，从而实现聚合活性和选择性的统一. 本文首先从

-羧基环内酸酐单体的开环聚合研究出发，综述了该领域的发展脉络和代表性研究进展. 接着，回顾和梳理了我们针对该领域的关键挑战而开展的系列研究工作，重点介绍了阴离子结合催化聚合方法的提出背景与建立过程. 最后，展望了这种新兴催化聚合方法的未来发展趋势. 我们相信，利用非共价相互作用来催化挑战性的离子聚合，代表了一个前景广阔的聚合催化研究新方向，必将在推动高分子科学及其产业的可持续发展中发挥重要作用.

Abstract

With the increasingly emphasizes on sustainable development

exploring efficient

green

safe

and economical new sustainable polymerization methodologies has become a central focus in polymer synthesis. To address the limitations of chain polymerization primarily relying on metal catalysts to regulate chain ends

we have recently developed an innovative concept of anion-binding catalytic polymerization

where the hydrogen bond donors could leverage non-covalent anion-binding interactions to dynamically bind

recognize and activate propagating species

thereby achieving ideal polymerization activity and selectivity. This article begins by reviewing the development and representative research progress in ring-opening p

olymerization (ROP) of

-carboxyanhydrides (OCA). It then revisits and organizes our series of research efforts for addressing key challenges in this area

with a particular focus on the background and establishment of the anion-binding catalytic polymerization method. Finally

we discuss the future development trends of this emerging catalytic polymerization approach. We believe that utilizing non-covalent interactions to catalyze challenging ionic polymerization represents a promising new direction in polymerization catalysis

which will significantly contribute to the sustainable development of polymer science and its associated industries.

关键词

Keywords

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From Ring-opening Polymerization of O-carboxyanhydride to the Discovery of Anion-binding Catalytic Polymerization

DOI：10.11777/j.issn1000-3304.2024.24271

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