Preparation and Viscoelastic Behavior of Hydrogel Composites

Xiao-yu Zhang; Shu-hua Deng; Chang-min Cai; Jin-cheng Li; Cai-hong Lei; An-fu Chen; Yi-fang Gao

doi:10.11777/j.issn1000-3304.2025.25016

您当前的位置：

首页 >

文章列表页 >

Preparation and Viscoelastic Behavior of Hydrogel Composites

Research Article | 更新时间：2025-07-08

- Preparation and Viscoelastic Behavior of Hydrogel Composites
- Acta Polymerica Sinica Vol. 56, Issue 7, Pages: 1215-1222(2025)
- 作者机构：
  
  1.广东工业大学材料与能源学院广州 510006
  2.广东水利电力职业技术学院广州 510925
- 作者简介：
  
  An-fu Chen, E-mail: anfuchen@gdut.edu.cn
  Yi-fang Gao, E-mail: gao.yf@foxmail.com
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2025.25016
  CLC：
- CSTR：32057.14.GFZXB.2025.7375
- Received：10 January 2025，
  
  Accepted：05 March 2025，
  
  Published Online：08 May 2025，
  
  Published：20 July 2025
- 稿件说明：
移动端阅览
张晓雨, 邓淑桦, 蔡畅敏, 李锦程, 雷彩红, 陈安伏, 高怡芳. 水凝胶复合材料的制备及其黏弹性行为研究. 高分子学报, 2025, 56(7), 1215-1222

Zhang, X. Y.; Deng, S. H.; Cai, C. M.; Li, J. C.; Lei, C. H.; Chen, A. F.; Gao, Y. F. Preparation and viscoelastic behavior of hydrogel composites. Acta Polymerica Sinica, 2025, 56(7), 1215-1222
张晓雨, 邓淑桦, 蔡畅敏, 李锦程, 雷彩红, 陈安伏, 高怡芳. 水凝胶复合材料的制备及其黏弹性行为研究. 高分子学报, 2025, 56(7), 1215-1222 DOI： 10.11777/j.issn1000-3304.2025.25016. CSTR： 32057.14.GFZXB.2025.7375.

Zhang, X. Y.; Deng, S. H.; Cai, C. M.; Li, J. C.; Lei, C. H.; Chen, A. F.; Gao, Y. F. Preparation and viscoelastic behavior of hydrogel composites. Acta Polymerica Sinica, 2025, 56(7), 1215-1222 DOI： 10.11777/j.issn1000-3304.2025.25016. CSTR： 32057.14.GFZXB.2025.7375.

摘要

作为一种高吸水高保水高分子材料，水凝胶可被用于医学和农业等领域. 然而，传统的聚丙烯酰胺(PAAm)水凝胶抗压能力弱、稳定性差，这极大限制了PAAm水凝胶的广泛应用. 本研究通过在PAAm水凝胶中引入二氧化硅(SiO

)纳米粒子，制备了具有高吸水率的PAAm/SiO

复合水凝胶. 研究表明，复合水凝胶的溶胀率随SiO

含量的增加呈现先增加后减小的趋势. 而且，与纯PAAm水凝胶相比，PAAm/SiO

复合水凝胶的孔径减小

且孔密度增大，从而提高了其抗压性能. 因此，通过对PAAm/SiO

复合水凝胶的溶胀行为、机械性能和流变性能进行研究，来阐明SiO

纳米粒子对复合水凝胶性能的影响.

Abstract

As high-water absorption and high-water retention polymers

hydrogels are widely used in many fields such as smart materials

water absorption materials

drug delivery

slow release

skin dressings

and biomedicine. However

the traditional hydrogels like polyacrylamide (PAAm) have the limitation of low mechanical strength and poor stability

which greatly limits the development of hydrogels. The commonly used methods for increasing the strength of hydrogels include the construction of double-network structure hydrogels

the introduction of chemical groups to modify hydrogels

the introduction of nanoparticles to form nanocomposite hydrogels

and so on. In this work

the mechanical properties of PAAm hydrogels are mainly improved by introducing hydrophilic silica (SiO

) nanoparticles. The results show that SiO

nanoparticles

as multi-functional crosslinking agents

are physically adsorbed or chemically bonded into the hydrogel matrix to enhance the 3D network structure of the hydrogel. In addition

hydrogen bon

ds formed between the silicon hydroxyl group on the surface of SiO

nanoparticles and the amide group on the polymer chain

which increases the crosslinking density of the hydrogel and greatly improves the compression performance. The SiO

nanoparticles are hydrophilic

which will increase the water absorption of the composite hydrogel and increase the swelling rate

but the swelling rate will decrease due to the limitation of the three-dimensional mesh of the hydrogel. The energy storage modulus of composite hydrogels will gradually increase due to the denser three-dimensional mesh structure

but the loss modulus will increase due to the increase of internal structure friction

but also because of the denser mesh

the increase of loss modulus will be limited. In general

the addition of SiO

nanoparticles has a certain significance for improving the viscoelasticity of hydrogels.

关键词

Keywords

references

Li L. ; Yan B. ; Yang J. Q. ; Chen L. Y. ; Zeng H. B. Novel mussel-inspired injectable self-healing hydrogel with anti-biofouling property . Adv. Mater. , 2015 , 27 ( 7 ), 1294 - 1299 . doi: 10.1002/adma.201405166 http://dx.doi.org/10.1002/adma.201405166

孙蕾 , 王少华 , 赵增典 , 刘秀芳 , 李相晔 . 海胆状纳米二氧化硅增强水凝胶的制备与性能研究 . 山东理工大学学报(自然科学版) , 2024 , 38 ( 1 ), 68 - 72 . doi: 10.3969/j.issn.1672-6197.2024.01.011 http://dx.doi.org/10.3969/j.issn.1672-6197.2024.01.011

Ali K. ; Asad Z. ; Agbna G. H. D. ; Saud A. ; Khan A. ; Zaidi S. J. Progress and innovations in hydrogels for sustainable agriculture . Agronomy , 2024 , 14 ( 12 ), 2815 . doi: 10.3390/agronomy14122815 http://dx.doi.org/10.3390/agronomy14122815

Han S. Y. ; An S. ; Cho S. W. Advanced bioadhesive hydrogels for skin care and therapy . Adv. Ther. , 2024 , 7 ( 1 ), 2300125 . doi: 10.1002/adtp.202300125 http://dx.doi.org/10.1002/adtp.202300125

侯文静 , 何彩庆 , 陈文清 . 农业固废基水凝胶用于水体中重金属吸附的研究进展 . 复合材料学报 , 2024 , 41 ( 7 ), 3322 - 3334 .

罗宪波 , 武海燕 , 蒲万芬 , 赵金洲 . 原子力显微镜对二次交联凝胶脱水机理的研究 . 西南石油学院学报 , 2006 , 28 ( 1 ), 65 - 67 . doi: 10.3863/j.issn.1000-2634.2006.01.018 http://dx.doi.org/10.3863/j.issn.1000-2634.2006.01.018

周长凯 , 方鹏达 , 张昊 , 孙哲 , 严锋 . 基于天青B的聚丙烯酰胺-丙烯酸水凝胶用于虾类新鲜度监测 . 高分子学报 , 2024 , 55 ( 11 ), 1518 - 1528 . doi: 10.11777/j.issn1000-3304.2024.24095 http://dx.doi.org/10.11777/j.issn1000-3304.2024.24095

Cheng Y. ; Zhang H. T. ; Wei H. ; Yu C. Y. Injectable hydrogels as emerging drug-delivery platforms for tumor therapy . Biomater. Sci. , 2024 , 12 ( 5 ), 1151 - 1170 . doi: 10.1039/d3bm01840g http://dx.doi.org/10.1039/d3bm01840g

赵新淮 , 徐红华 , 姜毓君 . 食品蛋白质: 结构、性质与功能 . 北京 : 科学出版社 , 2009 .

姚辉 , 石琳 , 周新军 . 聚丙烯酰胺的制备与应用 . 煤炭与化工 , 2023 , 46 ( 7 ), 134 - 139 .

胡佳妤 , 杜聪 , 张歆宁 , 郑强 , 吴子良 . 玻璃态水凝胶: 从凝胶材料的新状态到高性能 . 高分子学报 , 2023 , 54 ( 12 ), 1795 - 1816 .

邹健 , 陈卓 , 王盛冀 , 金涛 , 易添灏 , 杨晓宇 , 经鑫 . 导电水凝胶中交联剂含量对综合性能的影响 . 包装学报 , 2022 , 14 ( 6 ), 80 - 89 .

陈秀琼 , 廖雨青 , 王洪财 , 李东泽 , 颜慧琼 , 林强 . 基于互穿网络技术构筑的氧化海藻酸钠/纤维素纳米晶/聚丙烯酰胺-明胶双网络水凝胶与性能 . 精细化工 , 2023 , 40 ( 6 ), 1309 - 1318 . doi: 10.13550/j.jxhg.20220731 http://dx.doi.org/10.13550/j.jxhg.20220731

寿雯 , 杨双婷 , 王悦靓 , 郭隆华 . 贵金属纳米粒子与水凝胶复合材料的制备及其在分析化学领域的应用进展 . 分析化学 , 2021 , 49 ( 5 ), 676 - 685 . doi: 10.19756/j.issn.0253-3820.201536 http://dx.doi.org/10.19756/j.issn.0253-3820.201536

朱礼威 , 王江玥 , 白丁 . 纳米复合甲基丙烯酰明胶水凝胶在不同骨缺损环境中应用的价值 . 中国组织工程研究 , 2024 , 28 ( 5 ), 753 - 758 .

郑骏驰 . 纳米二氧化硅的表面修饰及其对天然橡胶复合材料结构与性能的影响 . 北京化工大学博士学位论文 , 2018 .

朱庆帅 , 项羽 , 张代维 , 李星 , 刘鑫 , 徐建根 . 纳米二氧化硅及其复合材料用作页岩稳定剂的研究进展 . 辽宁化工 , 2023 , 52 ( 12 ), 1822 - 1825 .

Murakami K. ; Imai A. ; Nakamura A. Temperature dependence of aggregation behavior and dye adsorption of poly(N-isopropylacrylamide) hydrogel/mesoporous silica composites . Colloids Surf. A Physicochem. Eng. Aspects , 2023 , 674 , 131944 . doi: 10.1016/j.colsurfa.2023.131944 http://dx.doi.org/10.1016/j.colsurfa.2023.131944

王建国 , 杨骏 , 邓声威 , 宋鑫 , 孔祥宇 . 一种以SiO 2 水凝胶为原料制备的保温砖及其制备方法 , 中国专利 , CN 109809790 A . 2019-05-28 .

Kawachi Y. ; Kugimiya S. I. ; Kato K. Preparation of silica hydrogels using a synthetic peptide for application as carriers for controlled drug release and mesoporous oxides . J. Ceram. Soc. Japan , 2014 , 122 ( 1422 ), 134 - 140 . doi: 10.2109/jcersj2.122.134 http://dx.doi.org/10.2109/jcersj2.122.134

Fathinejad H. ; Karimi E. Synthesis and characterization of polyacrylamide-based antibacterial hydrogel nanocomposite . Soft Mater. , 2024 , 22 ( 4 ), 295 - 302 . doi: 10.1080/1539445x.2024.2432259 http://dx.doi.org/10.1080/1539445x.2024.2432259

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Preparation and Viscoelastic Behavior of Hydrogel Composites

Study on Creep Behavior of Hydrogen-bonded Polymer Complexes

Rheological Behavior of Biomimetic Composite Hydrogels with Anisotropic Structures

Cylindrical Side-chain Polymers: Structure, Viscoelasticity and Functional Applications

Related Author

Xiao-yu Zhang

Shu-hua Deng

Chang-min Cai

Jin-cheng Li

Cai-hong Lei

Yi-fang Gao

An-fu Chen

Shu-guang Yang

Related Institution

广东水利电力职业技术学院

广东工业大学材料与能源学院

State Key Laboratory of Advanced Fiber Materials, Center for Advanced Low-dimension Materials, College of Material Science and Engineering, Donghua University

College of Materials Science & Engineering

Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University

AI脑图

AI问答

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰