Effect of Silane Terminated Liquid Polybutadiene on the Properties of Silica-filled Styrene-butadiene Rubber/Butadiene Rubber Composites

Min Li; Xin-li Liu; Dong-mei Cui

doi:10.11777/j.issn1000-3304.2025.25180

您当前的位置：

首页 >

文章列表页 >

Effect of Silane Terminated Liquid Polybutadiene on the Properties of Silica-filled Styrene-butadiene Rubber/Butadiene Rubber Composites

Research Article | 更新时间：2026-01-16

- Effect of Silane Terminated Liquid Polybutadiene on the Properties of Silica-filled Styrene-butadiene Rubber/Butadiene Rubber Composites
- Acta Polymerica Sinica Vol. 57, Issue 1, Pages: 119-128(2026)
- 作者机构：
  
  1.中国科学院长春应用化学研究所高分子科学与技术全国重点实验室长春 130022
  2.中国科学技术大学应用化学与工程学院合肥 230026
- 作者简介：
  
  Dong-mei Cui, E-mail: dmcui@ciac.ac.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2025.25180
  CLC：
- CSTR：32057.14.GFZXB.2025.7487
- Received：13 September 2025，
  
  Accepted：14 October 2025，
  
  Published Online：19 December 2025，
  
  Published：20 January 2026
- 稿件说明：
移动端阅览
李敏, 刘新立, 崔冬梅. 硅烷封端液体聚丁二烯对二氧化硅填充丁苯橡胶/顺丁橡胶复合材料性能的影响. 高分子学报, 2026, 57(1), 119-128.

Li, M.; Liu, X. L.; Cui, D. M. Effect of silane terminated liquid polybutadiene on the properties of silica-filled styrene-butadiene rubber/butadiene rubber composites. Acta Polymerica Sinica (in Chinese), 2026, 57(1), 119-128.
李敏, 刘新立, 崔冬梅. 硅烷封端液体聚丁二烯对二氧化硅填充丁苯橡胶/顺丁橡胶复合材料性能的影响. 高分子学报, 2026, 57(1), 119-128. DOI： 10.11777/j.issn1000-3304.2025.25180. CSTR： 32057.14.GFZXB.2025.7487.

Li, M.; Liu, X. L.; Cui, D. M. Effect of silane terminated liquid polybutadiene on the properties of silica-filled styrene-butadiene rubber/butadiene rubber composites. Acta Polymerica Sinica (in Chinese), 2026, 57(1), 119-128. DOI： 10.11777/j.issn1000-3304.2025.25180. CSTR： 32057.14.GFZXB.2025.7487.

摘要

通过羰基的硅氢化反应实现液体聚丁二烯橡胶的精准封端，合成了三甲氧基硅烷封端(TMSLPB)与三乙氧基硅烷封端(TESLPB)的液体聚丁二烯橡胶. 研究了上述硅烷封端液体橡胶(SLPBs)作为二氧化硅填充的丁苯橡胶/顺丁橡胶(SBR/BR)的界面改性剂对橡胶复合材料性能的影响. 结果表明，SLPBs能显著减弱二氧化硅的团聚现象，改善填料分散性，增强橡胶复合材料性能. 此外，3份TESLPB作为界面改性剂时SBR/BR橡胶复合材料的力学性能最优异，60 ℃时损耗因子值最低，磨耗损失最小.

Abstract

Precise capping of liquid polybutadiene was achieved by silica hydrogenation reaction

and trimethoxysilane terminated (TMSLPB) and triethoxysilane terminated (TESLPB) liquid polybutadiene rubbers were successfully synthesised. The effects of the above liquid rubbers as interfacial modifiers of silica-filled styrene-butadiene rubber/butadiene rubber (SBR/BR) on the properties of the composites were investigated. The results showed that TMSLPB and TESLPB could significantly attenuate the agglomeration phenomenon of silica

improve the dispersion of filler

and enhance the rubber composite properties. In addition

the mechanical properties of SBR/BR rubber composites were the best when 3 phr of TESLPB was used as plasticiser

with the lowest loss factor value at 60 ℃ and the smallest abrasion loss.

关键词

Keywords

references

Shoul B. ; Marfavi Y. ; Sadeghi B. ; Kowsari E. ; Sadeghi P. ; Ramakrishna S. Investigating the potential of sustainable use of green silica in the green tire industry: a review . Environ. Sci. Pollut. Res. Int. , 2022 , 29 ( 34 ), 51298 - 51317 . doi: 10.1007/s11356-022-20894-8 http://dx.doi.org/10.1007/s11356-022-20894-8

Abraham E. ; Thomas M. S. ; John C. ; Pothen L. A. ; Shoseyov O. ; Thomas S. Green nanocomposites of natural rubber/nanocellulose: membrane transport, rheological and thermal degradation characterisations . Ind. Crops Prod. , 2013 , 51 , 415 - 424 . doi: 10.1016/j.indcrop.2013.09.022 http://dx.doi.org/10.1016/j.indcrop.2013.09.022

Ansari A. ; Mohanty T. R. ; Ramakrishnan S. ; Amarnath S. K. P. ; Singha N. K. Design of silyl functionalized emulsion SBR and its application in green tire . Ind. Eng. Chem. Res. , 2025 , 64 ( 7 ), 3795 - 3809 . doi: 10.1021/acs.iecr.4c04125 http://dx.doi.org/10.1021/acs.iecr.4c04125

Xiao Y. ; Li B. ; Diao P. F. ; Huang Y. G. ; Li X. X. ; Wang C. S. ; Bian H. G. Raw rubber network of acid-free natural rubber and its application with solution-polymerized styrene butadiene rubber in green tires . Polym. Test. , 2024 , 140 , 108605 . doi: 10.1016/j.polymertesting.2024.108605 http://dx.doi.org/10.1016/j.polymertesting.2024.108605

Sittiphan T. ; Prasassarakich P. ; Poompradub S. Styrene grafted natural rubber reinforced by in situ silica generated via sol-gel technique . Mater. Sci. Eng. B , 2014 , 181 , 39 - 45 . doi: 10.1016/j.mseb.2013.11.018 http://dx.doi.org/10.1016/j.mseb.2013.11.018

Lolage M. ; Parida P. ; Chaskar M. ; Gupta A. ; Rautaray D. Green Silica: industrially scalable & sustainable approach towards achieving improved "nano filler-Elastomer" interaction and reinforcement in tire tread compounds . Sustainable Mater. Technol. , 2020 , 26 , e00232 . doi: 10.1016/j.susmat.2020.e00232 http://dx.doi.org/10.1016/j.susmat.2020.e00232

Sęk M. ; Kaewsakul W. ; Anyszka R. ; Schultz S. ; Bandzierz K. ; Blume A. Interfacial coupling efficiency of functionalised rubbers on silica surfaces . Surf. Interfaces , 2024 , 44 , 103719 . doi: 10.1016/j.surfin.2023.103719 http://dx.doi.org/10.1016/j.surfin.2023.103719

Fröhlich J. ; Niedermeier W. ; Luginsland H. D. The effect of filler-filler and filler-elastomer interaction on rubber reinforcement . Compos. Part A Appl. Sci. Manuf. , 2005 , 36 ( 4 ), 449 - 460 . doi: 10.1016/j.compositesa.2004.10.004 http://dx.doi.org/10.1016/j.compositesa.2004.10.004

Tong Z. H. ; Jiang T. Y. ; Qiu R. ; Lin G. Z. ; Xie C. L. ; Bi M. Q. Effect of different silane coupling agent modified SiO 2 on the properties of silicone rubber composites: based on molecular dynamics . Colloids Surf. A Physicochem. Eng. Aspects , 2025 , 705 , 135615 . doi: 10.1016/j.colsurfa.2024.135615 http://dx.doi.org/10.1016/j.colsurfa.2024.135615

Kaewsakul W. ; Sahakaro K. ; Dierkes W. K. ; Noordermeer J. W. M. Mechanistic aspects of silane coupling agents with different functionalities on reinforcement of silica-filled natural rubber compounds . Polym. Eng. Sci. , 2015 , 55 ( 4 ), 836 - 842 . doi: 10.1002/pen.23949 http://dx.doi.org/10.1002/pen.23949

Yrieix M. ; Da Cruz-Boisson F. ; Majesté J. C. Rubber/silane reactions and grafting rates investigated by liquid-state NMR spectroscopy . Polymer , 2016 , 87 , 90 - 97 . doi: 10.1016/j.polymer.2016.01.055 http://dx.doi.org/10.1016/j.polymer.2016.01.055

Li S. Q. ; Zhai X. B. ; Chen Z. ; Han D. L. ; Ye X. ; Zhang L. Q. Balancing the "magic triangle" performance of tire rubber nanocomposites with novel low VOC silane coupling agents . Compos. Commun. , 2024 , 46 , 101836 . doi: 10.1016/j.coco.2024.101836 http://dx.doi.org/10.1016/j.coco.2024.101836

Aso O. ; Eguiazábal J. I. ; Nazábal J. The influence of surface modification on the structure and properties of a nanosilica filled thermoplastic elastomer . Compos. Sci. Technol. , 2007 , 67 ( 13 ), 2854 - 2863 . doi: 10.1016/j.compscitech.2007.01.021 http://dx.doi.org/10.1016/j.compscitech.2007.01.021

Liu X. Y. ; Lv X. H. ; Tian Q. F. ; AlMasoud N. ; Xu Y. F. ; Alomar T. S. ; El-Bahy Z. M. ; Li J. T. ; Algadi H. ; Roymahapatra G. ; Ding T. ; Guo J. ; Li X. H. Silica binary hybrid particles based on reduced graphene oxide for natural rubber composites with enhanced thermal conductivity and mechanical properties . Adv. Compos. Hybrid Mater. , 2023 , 6 ( 4 ), 141 . doi: 10.1007/s42114-023-00703-7 http://dx.doi.org/10.1007/s42114-023-00703-7

Castellano M. ; Conzatti L. ; Costa G. ; Falqui L. ; Turturro A. ; Valenti B. ; Negroni F. Surface modification of silica: 1. thermodynamic aspects and effect on elastomer reinforcement . Polymer , 2005 , 46 ( 3 ), 695 - 703 . doi: 10.1016/j.polymer.2004.11.010 http://dx.doi.org/10.1016/j.polymer.2004.11.010

Sun Z. ; Huang Q. ; Zhang L. Q. ; Wang Y. Z. ; Wu Y. P. Tailoring silica-rubber interactions by interface modifiers with multiple functional groups . RSC Adv. , 2017 , 7 ( 62 ), 38915 - 38922 . doi: 10.1039/c7ra07321f http://dx.doi.org/10.1039/c7ra07321f

Mohapatra S. ; Alex R. ; Nando G. B. Cardanol grafted natural rubber: a green substitute to natural rubber for enhancing silica filler dispersion . J. Appl. Polym. Sci. , 2016 , 133 ( 8 ), 43057 . doi: 10.1002/app.43057 http://dx.doi.org/10.1002/app.43057

Liu J. H. ; Li D. ; Fu Z. ; Geng J. T. ; Hua J. Preparation and properties of 1,2-polybutadiene grafting with poly(1,3-butadiene)-block-(dimethylsiloxane) . Polym. Adv. Technol. , 2019 , 30 ( 7 ), 1663 - 1672 . doi: 10.1002/pat.4597 http://dx.doi.org/10.1002/pat.4597

Ying W. L. ; Pan W. J. ; Gan Q. ; Jia X. Y. ; Grassi A. ; Gong D. R. Preparation and property investigation of chain end functionalized cis -1,4 polybutadienes via de-polymerization and cross metathesis of cis -1,4 polybutadienes . Polym. Chem. , 2019 , 10 ( 25 ), 3525 - 3534 . doi: 10.1039/c9py00485h http://dx.doi.org/10.1039/c9py00485h

Liu X. ; Zhao S. H. ; Zhang X. Y. ; Li X. L. ; Bai Y. Preparation, structure, and properties of solution-polymerized styrene-butadiene rubber with functionalized end-groups and its silica-filled composites . Polymer , 2014 , 55 ( 8 ), 1964 - 1976 . doi: 10.1016/j.polymer.2014.02.067 http://dx.doi.org/10.1016/j.polymer.2014.02.067

Xu T. W. ; Jia Z. X. ; Luo Y. F. ; Jia D. M. ; Peng Z. Interfacial interaction between the epoxidized natural rubber and silica in natural rubber/silica composites . Appl. Surf. Sci. , 2015 , 328 , 306 - 313 . doi: 10.1016/j.apsusc.2014.12.029 http://dx.doi.org/10.1016/j.apsusc.2014.12.029

Pourhossaini M. R. ; Razzaghi-Kashani M. Grafting hydroxy-terminated polybutadiene onto nanosilica surface for styrene butadiene rubber compounds . J. Appl. Polym. Sci. , 2012 , 124 ( 6 ), 4721 - 4728 . doi: 10.1002/app.35514 http://dx.doi.org/10.1002/app.35514

Abd-El-Messieh S. L. ; Abd-El-Nour K. N. Effect of curing time and sulfur content on the dielectric relaxation of styrene butadiene rubber . J. Appl. Polym. Sci. , 2003 , 88 ( 7 ), 1613 - 1621 . doi: 10.1002/app.11686 http://dx.doi.org/10.1002/app.11686

Zhou Q. Z. ; Jie S. Y. ; Li B. G. Preparation of hydroxyl-terminated polybutadiene with high cis -1,4 content . Ind. Eng. Chem. Res. , 2014 , 53 ( 46 ), 17884 - 17893 . doi: 10.1021/ie503652g http://dx.doi.org/10.1021/ie503652g

Mukherjee D. ; Ellern A. ; Sadow A. D. Magnesium-catalyzed hydroboration of esters: evidence for a new zwitterionic mechanism . Chem. Sci. , 2014 , 5 ( 3 ), 959 - 964 . doi: 10.1039/c3sc52793j http://dx.doi.org/10.1039/c3sc52793j

Lampland N. L. ; Pindwal A. ; Neal S. R. ; Schlauderaff S. ; Ellern A. ; Sadow A. D. Magnesium-catalyzed hydrosilylation of α , β -unsaturated esters . Chem. Sci. , 2015 , 6 ( 12 ), 6901 - 6907 . doi: 10.1039/c5sc02435h http://dx.doi.org/10.1039/c5sc02435h

Rauch M. ; Ruccolo S. ; Parkin G. Synthesis , structure, and reactivity of a terminal magnesium hydride compound with a carbatrane motif, [TismPriBenz ] MgH : a multifunctional catalyst for hydrosilylation and hydroboration . J. Am. Chem. Soc., 2017 , 139 ( 38 ), 13264 - 13267 . doi: 10.1021/jacs.7b06719 http://dx.doi.org/10.1021/jacs.7b06719

Zhang X. G. ; Lu K. ; Chen X. ; Su G. X. ; Rong X. F. ; Ma M. T. Hydroboration and hydrosilylation of alkenes catalyzed by an unsymmetrical magnesium methyl complex . Org. Biomol. Chem. , 2024 , 22 ( 26 ), 5353 - 5360 . doi: 10.1039/d4ob00745j http://dx.doi.org/10.1039/d4ob00745j

Li M. ; Liu X. L. ; Cui D. M. Catalytic hydroboration of carbonyl derivatives by using phosphinimino amide ligated magnesium complexes . Dalton Trans. , 2021 , 50 ( 37 ), 13037 - 13041 . doi: 10.1039/d1dt00143d http://dx.doi.org/10.1039/d1dt00143d

Sreeja T. D. ; Kutty S. K. N. Cure characteristics and mechanical properties of natural rubber/reclaimed rubber blends . Polym. Plast. Technol. Eng. , 2000 , 39 ( 3 ), 501 - 512 . doi: 10.1081/ppt-100100043 http://dx.doi.org/10.1081/ppt-100100043

Sirisinha C. ; Sae-oui P. ; Suchiva K. ; Thaptong P. Properties of tire tread compounds based on functionalized styrene butadiene rubber and functionalized natural rubber . J. Appl. Polym. Sci. , 2020 , 137 ( 20 ), 48696 . doi: 10.1002/app.48696 http://dx.doi.org/10.1002/app.48696

Parameswaran S. K. ; Bhattacharya S. ; Mukhopadhyay R. ; Naskar K. ; Bhowmick A. K. Excavating the unique synergism of nanofibers and carbon black in Natural rubber based tire tread composition . J. Appl. Polym. Sci. , 2021 , 138 ( 3 ), 49682 . doi: 10.1002/app.49682 http://dx.doi.org/10.1002/app.49682

Views

184

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Influence of the Surface Electrical Property of Polymer Template Microspheres on the Morphology of Hollow Silica Microspheres

Modification of Polypropylene with Composite Nucleating Agents Containing 2,2-Methylene-bis-(4,6-di-t-butylphenylene) Phosphate/Attapulgite/Silica Nano-particles

UREA FORMALDEHYDE POLYMERIZATION CONTROLLED BY USING GLYOXAL

SYNTHESIS AND ELECTRIC-SENSITIVE PROPERTIES OF PAMPS/SiO2 HYBRID HYDROGELS

Related Author

Li-zhao Xie

Chi Zhao

Mo-zhen Wang

Xue-wu Ge

Guo-wei Duan

Jin-qing Li

Min Guo

Zhuang Miao

Related Institution

CAS Key Laboratory of Soft pMatter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China

School of Material Science and Engineering, Beijing Institute of Technology

SINOPEC Beijing Research Institute of Chemical Industry

Academy of Ordnance Science

Department of Chemistry, Tongji University

AI脑图

AI问答

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802046899号
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰