Research Progress on Processing and Structural Regulation of High-filled Polymer Composites

Li-jun Ye; Jie-qing Shen; Ying Tao; Jia-hui Hong; Yong-jin Li

doi:10.11777/j.issn1000-3304.2025.25209

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Research Progress on Processing and Structural Regulation of High-filled Polymer Composites

Review | 更新时间：2025-12-18

- Research Progress on Processing and Structural Regulation of High-filled Polymer Composites
- Acta Polymerica Sinica Vol. 56, Issue 12, Pages: 2139-2158(2025)
- 作者机构：
  
  杭州师范大学材料与化学化工学院有机硅化学及材料技术教育部重点实验室杭州 311121
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2025.25209
  CLC：
- CSTR：32057.14.GFZXB.2025.7475
- Received：29 August 2025，
  
  Accepted：26 September 2025，
  
  Published Online：27 November 2025，
  
  Published：20 December 2025
- 稿件说明：
移动端阅览
叶丽军, 沈洁清, 陶莹, 洪佳晖, 李勇进. 高填充高分子复合材料成型加工与结构调控研究进展. 高分子学报, 2025, 56(12), 2139-2158

Ye, L. J.; Shen, J. Q.; Tao, Y.; Hong, J. H.; Li, Y. J. Research progress on processing and structural regulation of high-filled polymer composites. Acta Polymerica Sinica, 2025, 56(12), 2139-2158
叶丽军, 沈洁清, 陶莹, 洪佳晖, 李勇进. 高填充高分子复合材料成型加工与结构调控研究进展. 高分子学报, 2025, 56(12), 2139-2158 DOI： 10.11777/j.issn1000-3304.2025.25209. CSTR： 32057.14.GFZXB.2025.7475.

Ye, L. J.; Shen, J. Q.; Tao, Y.; Hong, J. H.; Li, Y. J. Research progress on processing and structural regulation of high-filled polymer composites. Acta Polymerica Sinica, 2025, 56(12), 2139-2158 DOI： 10.11777/j.issn1000-3304.2025.25209. CSTR： 32057.14.GFZXB.2025.7475.

摘要

高填充高分子复合材料在电子封装、生物医学等领域具有广阔应用前景. 功能填料的引入能够显著提升高分子材料的导电性、导热性、阻燃性及电磁屏蔽等性能，但高含量填料往往会降低复合材料的力学性能和加工性能. 本文综述了高填充高分子复合材料在热塑性加工与结构调控方面的研究进展，重点讨论了填料堆积密度的调控及其对成型加工的影响、热塑性加工条件下的填料网络设计，以及可逆动态化学键在基体黏度调控中的应用. 同时，阐述了热塑性高分子复合材料成型加工过程中的结构演变及其调控方法，旨在为高填充复合材料的加工工艺优化和性能提升提供理论指导.

Abstract

High-filled polymer composites hold significant potential in electronics packaging

biomedical applications

and other fields. The incorporation of functional fillers can substantially enhance the electrical conductivity

thermal conductivity

flame retardancy

and electromagnetic shielding performance of polymer materials; however

high filler content often compromises the mechanical properties and processability of the composites. This review summarizes recent advances in the thermoplastic processing and structural design of high-filled polymer composites

with a focus on controlling filler packing density and its influence on processing

the design of filler networks under thermoplastic processing conditions

and the application of reversible dynamic chemical bonds for tuning matrix viscosity. Additionally

the structural evolution during thermoplastic processing and corresponding control strategies are elucidated

aiming to provide theoretical guidance for the optimization of processing techniques and the enhancement of performance in high-filled polymer composites.

关键词

Keywords

references

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