Influence of Dodecylated Lignin/Carbon Black Hybrid Filler System on the Performance of Natural Rubber

Shu-fen Zeng; Shu-ting Chen; Qi-bin Zeng; Xiao-xia Ye; Yi-fan Liu; Ming-hua Liu

doi:10.11777/j.issn1000-3304.2025.25285

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Influence of Dodecylated Lignin/Carbon Black Hybrid Filler System on the Performance of Natural Rubber

Research Article | 更新时间：2026-04-01

- Influence of Dodecylated Lignin/Carbon Black Hybrid Filler System on the Performance of Natural Rubber
- Acta Polymerica Sinica Vol. 57, Issue 4, Pages: 986-997(2026)
- 作者机构：
  
  1.福州大学环境与安全工程学院福州 350108
  2.莆田学院环境与生物工程学院莆田 351100
- 作者简介：
  
  Ming-hua Liu, E-mail: mhliu2000@fzu.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2025.25285
  CLC：
- CSTR：32057.14.GFZXB.2025.7543
- Received：27 October 2025，
  
  Accepted：18 December 2025，
  
  Online First：02 February 2026，
  
  Published：20 April 2026
- 稿件说明：
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曾舒芬, 陈淑婷, 曾奇斌, 叶晓霞, 刘以凡, 刘明华. 烷基化木质素/炭黑复配体系对天然橡胶复合材料性能的影响. 高分子学报, 2026, 57(4), 986-997.

Zeng, S. F.; Chen, S. T.; Zeng, Q. B.; Ye, X. X.; Liu, Y. F.; Liu, M. H. Influence of dodecylated lignin/carbon black hybrid filler system on the performance of natural rubber. Acta Polymerica Sinica (in Chinese), 2026, 57(4), 986-997.
曾舒芬, 陈淑婷, 曾奇斌, 叶晓霞, 刘以凡, 刘明华. 烷基化木质素/炭黑复配体系对天然橡胶复合材料性能的影响. 高分子学报, 2026, 57(4), 986-997. DOI： 10.11777/j.issn1000-3304.2025.25285. CSTR： 32057.14.GFZXB.2025.7543.

Zeng, S. F.; Chen, S. T.; Zeng, Q. B.; Ye, X. X.; Liu, Y. F.; Liu, M. H. Influence of dodecylated lignin/carbon black hybrid filler system on the performance of natural rubber. Acta Polymerica Sinica (in Chinese), 2026, 57(4), 986-997. DOI： 10.11777/j.issn1000-3304.2025.25285. CSTR： 32057.14.GFZXB.2025.7543.

摘要

通过烷基化改性工艺制备了十二烷基化木质素(DL)，并将其与炭黑(CB)复配构建双相填料体系，系统探究了不同DL/CB复配比例对天然橡胶复合材料性能的影响. 结果表明，DL的引入使复合材料的正硫化时间缩短，门尼黏度降低，并且有效改善了填料在橡胶基体中的分散状态，进而减弱复合材料的Payne效应，显著提升力学性能、耐热氧老化性能与耐屈挠性能. 其中NR-10DL/40CB复合材料表现出最佳的综合性能，其在维持与NR-50CB相当的热稳定性、拉伸强度及抗湿滑性能的基础上，断裂伸长率提高了21.1%. 此外，热氧老化系数与屈挠龟裂周数分别提升了31.1%与41.4%，滚动阻力及耐切割性也得到同步优化，在轮胎、传送带等橡胶制品领域具有良好的应用前景.

Abstract

To enhance the interfacial compatibility and dispersion of lignin within the natural rubber (NR) matrix

thereby enhancing the mechanical properties of the rubber composite

dodecylated lignin (DL) was synthesized through alkylation modification

and a hybrid filler system was constructed by incorporating it with carbon black (CB). The influence of the DL/CB ratio on the properties of NR composites was systematically investigated. The results indicated that the incorporation of DL reduced the optimum curing time and Mooney viscosity of the composites

effectively improved the dispersion of the fillers in the rubber matrix

and significantly enhanced the mechanical properties

thermo-oxidative aging resistance

and flex resistance of the composites. Among the tested formulations

the NR-10DL/40CB composite exhibited the best performance. While maintaining thermal stability

tensile strength

and wet skid resistance comparable to those of the NR-50CB benchmark

the NR-10DL/40CB composite achieved a remarkable 21.1% increase in elongation at break. Furthermore

the thermal oxidative aging coefficient and the number of flex cracking cycles were improved by 31.1% and 41.4%

respectively

while the rolling resistance and cut resistance were optimized. These findings demonstrate the promising potential of the composite for application in rubber products such as tires and conveyor belts.

关键词

Keywords

references

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