Ring-opening Metathesis Polymerization-induced Self-assembly

Ting-ting Xu; Mu-zhou Li; Xin Hu; Ning Zhu

doi:10.11777/j.issn1000-3304.2026.26009

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Ring-opening Metathesis Polymerization-induced Self-assembly

更新时间：2026-05-13

- Ring-opening Metathesis Polymerization-induced Self-assembly
- Acta Polymerica Sinica Pages: 1-17(2026)
- 作者机构：
  
  1.南京工业大学，生物与制药工程学院材料化学工程全国重点实验室，南京 211800
  2.南京工业大学，材料科学与工程学院，南京 211800
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2026.26009
  CLC：
- CSTR：32057.14.GFZXB.2026.7574
- Received：15 January 2026，
  
  Accepted：12 March 2026，
  
  Online First：13 May 2026，
- 稿件说明：
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徐婷婷, 李牧舟, 胡欣, 朱宁. 开环易位聚合诱导自组装. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26009.

Xu, T. T.; Li, M. Z.; Hu, X.; Zhu, N. Ring-opening metathesis polymerization-induced self-assembly. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26009.
徐婷婷, 李牧舟, 胡欣, 朱宁. 开环易位聚合诱导自组装. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26009. DOI： CSTR： 32057.14.GFZXB.2026.7574.

Xu, T. T.; Li, M. Z.; Hu, X.; Zhu, N. Ring-opening metathesis polymerization-induced self-assembly. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26009. DOI： CSTR： 32057.14.GFZXB.2026.7574.

摘要

聚合诱导自组装(PISA)已成为一种高效合成固含量高、形貌多样纳米颗粒的新方法，在高分子化学和纳米材料等领域引起了广泛关注. 近年来，面向环烯烃单体的开环易位聚合(ROMP)具有可控性好、官能团耐受性高、适配大位阻单体等优势，越来越多地应用于聚合诱导自组装领域，成功获得系列主链含有不饱和双键的聚合物纳米颗粒. 本综述聚焦开环易位聚合诱导自组装(ROMPISA)，从有机相、水相和有机/水相三个方面，总结开环易位聚合诱导自组装在纳米颗粒形貌控制、功能调控以及应用等方面的研究进展，同时探讨了相关领域存在的机遇与挑战，希望为聚合诱导自组装领域的发展提供借鉴.

Abstract

Polymerization-induced self-assembly (PISA) has emerged as a highly efficient strategy for the synthesis of high-solid-content nano-objects with diverse morphologies

which has attracted growing interest in polymer chemistry and nanomaterials. In recent years

the ring-opening metathesis polymerization (ROMP) of cyclic olefin monomers has been used in PISA because of its good controllability

high tolerance for functional groups

and availability for sterically hindered monomers. Ring-opening metathesis polymerization-induced self-assembly (ROMPISA) has been demonstrated as a powerful platform for the preparation of a series of polyolefin block copolymer nano-objects containing unsaturated double bonds in the main chain. This review focuses on the advances in ring-opening metathesis polymerization-induced self-assembly. The morphologies

functions

and applications of nano-objects from ROMPISA are summarized from the perspectives of the organic

aqueous

and organic/aqueous phases

respectively. Challenges and opportunities are discussed to provide insights into the further development of polymerization-induced self-assembly.

关键词

Keywords

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