Effect of Multiscale Reinforcement Modification on the Tribological Performance of Poly(ether ether ketone) Composites

Lu-lu Wang; Jian-xin Xue; Jie Li; Huan-huan Lu; Shuai Wang; Jian Liu; Chen-fei Song; Xian-juan Pang

doi:10.11777/j.issn1000-3304.2026.26026

您当前的位置：

首页 >

文章列表页 >

Effect of Multiscale Reinforcement Modification on the Tribological Performance of Poly(ether ether ketone) Composites

Research Article | 更新时间：2026-07-08

- Effect of Multiscale Reinforcement Modification on the Tribological Performance of Poly(ether ether ketone) Composites
- Acta Polymerica Sinica Vol. 57, Issue 7, Pages: 1551-1565(2026)
- 作者机构：
  
  1.河南科技大学高端轴承摩擦学技术与应用国家地方联合工程实验室洛阳 471023
  2.河南科技大学化学化工学院洛阳 471023
- 作者简介：
  
  Jie Li, E-mail: lijie@huast.edu.cn
  Xian-juan Pang, E-mail: xjpang2001@haust.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2026.26026
  CLC：
- CSTR：32057.14.GFZXB.2026.7591
- Received：25 February 2026，
  
  Accepted：25 March 2026，
  
  Online First：23 June 2026，
  
  Published：20 July 2026
- 稿件说明：
移动端阅览
王露露, 薛键鑫, 李杰, 陆焕焕, 王帅, 刘建, 宋晨飞, 逄显娟. 多尺度增强体改性对聚醚醚酮复合材料摩擦磨损性能的影响. 高分子学报, 2026, 57(7), 1551-1565.

Wang, L. L.; Xue, J. X.; Li, J.; Lu, H. H.; Wang, S.; Liu, J.; Song, C. F.; Pang, X. J. Effect of multiscale reinforcement modification on the tribological performance of poly(ether ether ketone) composites. Acta Polymerica Sinica (in Chinese), 2026, 57(7), 1551-1565.
王露露, 薛键鑫, 李杰, 陆焕焕, 王帅, 刘建, 宋晨飞, 逄显娟. 多尺度增强体改性对聚醚醚酮复合材料摩擦磨损性能的影响. 高分子学报, 2026, 57(7), 1551-1565. DOI： 10.11777/j.issn1000-3304.2026.26026. CSTR： 32057.14.GFZXB.2026.7591.

Wang, L. L.; Xue, J. X.; Li, J.; Lu, H. H.; Wang, S.; Liu, J.; Song, C. F.; Pang, X. J. Effect of multiscale reinforcement modification on the tribological performance of poly(ether ether ketone) composites. Acta Polymerica Sinica (in Chinese), 2026, 57(7), 1551-1565. DOI： 10.11777/j.issn1000-3304.2026.26026. CSTR： 32057.14.GFZXB.2026.7591.

摘要

针对聚醚醚酮(PEEK)在高载荷工况下承载能力不足及摩擦稳定性差的问题，本研究构建了碳纤维(CF)/碳纳米管(MWCNTs)多尺度协同增强体系，并引入聚醚酰亚胺(PEI)和第三代聚酰胺-胺(PAMAM)进行界面化学改性. 通过上浆与接枝实现MWCNTs在CF表面的均匀负载，制备了不同结构复合材料. 结果表明，改性后界面形成稳定共价键合，显著增强界面结合与载荷传递能力. 与纯PEEK相比，复合材料硬度和导热性能均得到提升，其中CF-PAMAM-MWCNTs/PEEK综合性能最优. 在130 N下，其摩擦系数和比磨损率分别降低约15.8%和31.97%，在3~9 mm/s范围内磨损率降低约65%~75%. 性能提升归因于多尺度增强体协同作用及稳定摩擦膜的形成，有效抑制纤维拔出和三体磨损.

Abstract

To address the insufficient load-bearing capacity and poor friction stability of poly(ether ether ketone) (PEEK) under severe conditions

a multiscale synergistic reinforcement system combining carbon fibers (CF) and carbon nanotubes (MWCNTs) with interfacial chemical modification was developed. Polyetherimide (PEI) and third-generation poly(amidoamine) (PAMAM) dendrimers were employed to functionalize the CF surface

enabling uniform anchoring of MWCNTs

via

sizing and grafting. The results showed that stable covalent bonding was formed at the interface

significantly enhancing interfacial adhesion and load transfer. Compared

with neat PEEK

the composites exhibited improved hardness and thermal conductivity

with CF-PAMAM-MWCNTs/PEEK showing the best overall performance. At 130 N

its friction coefficient and wear rate decreased by 15.8% and 31.97%

respectively

while the wear rate was reduced by 65%-75% within 3-9 mm·s

-1

. The enhanced tribological performance was attributed to the multiscale synergistic effect and the formation of a stable tribofilm

which effectively suppress fiber pull-out and three-body abrasion.

关键词

Keywords

references

Wang C. S. ; Yan D. Y. ; Ren H. H. ; He Y. Z. ; Sun C. F. ; Zhao H. M. ; Li T. T. ; Zhao X. F. ; Guo . R . Research progress on process optimization of 3D-printed poly(ether ether ketone) by fused deposition modeling. Polym. Bull , 2024 , 37 ( 3 ), 316 - 327 .

任天翔 , 滕晓波 , 黄兴 , 马金星 , 赵德方 , 占海华 . 聚醚醚酮的改性及应用研究进展 . 塑料科技 , 2022 , 50 ( 9 ), 123 - 128 .

党亚朋 , 汤赫男 , 王明辉 , 刘林 . 纳米ZrO 2 增强PEEK/PTFE复合材料摩擦行为分子动力学模拟 . 润滑与密封 , 2024 , 49 ( 9 ), 59 - 63 .

Dabees S. ; Henderson L. C. ; Hayne D. J. Carbon fibre surface modification and its effects on adhesion, mechanical, and tribological behaviour of high-performance thermoplastics . Compos. Part B Eng. , 2025 , 306 , 112758 . doi: 10.1016/j.compositesb.2025.112758 http://dx.doi.org/10.1016/j.compositesb.2025.112758

柳杰 , 蒋青 , 徐佳宜 , 王睿君 , 吴凌清 , 蒋嘉伟 , 杨瑾 . 基于表面织构化的异质材料连接研究现状及进展 . 焊接 , 2025 ( 1 ), 82 - 91 . doi: 10.12073/j.hj.20240422001 http://dx.doi.org/10.12073/j.hj.20240422001

Gao W. F. ; Liu D. ; Yan C. ; Zhu Y. D. ; Chen G. ; Xu H. B. ; Liu G. J. ; Huang J. P. Progress on friction properties of caron fier reinforced thermoplastic composites . Polym. Bull , 2025 , 38 ( 1 ), 1 - 13 .

王在跃 , 姜宁 , 王明道 . 碳纤维表面改性对其增强热塑性复合材料性能影响的研究进展 . 复合材料学报 , 2025 , 42 ( 1 ), 147 - 161 .

刘柳薪 , 卢晓英 , 吴颖 , 荔栓红 , 吴谨妤 , 袁文静 , 高源 . 碳纤维增强树脂基复合材料界面改性及应用进展 . 材料工程 , 2024 , 52 ( 9 ), 70 - 81 . doi: 10.11868/j.issn.1001-4381.2024.000373 http://dx.doi.org/10.11868/j.issn.1001-4381.2024.000373

李娜 , 李晓屿 , 黄玉东 , 刘丽 , 程曼芳 , 王彩凤 . 基于电泳沉积法碳纤维表面改性的研究进展及应用 . 高分子通报 , 2021 , 34 ( 2 ), 29 - 37 . doi: 10.14028/j.cnki.1003-3726.2021.02.004 http://dx.doi.org/10.14028/j.cnki.1003-3726.2021.02.004

李子琪 , 裴纯 , 朱继华 . 碳纤维增强水泥基复合材料界面优化设计研究进展 . 复合材料学报 , 2024 , 41 ( 10 ), 5125 - 5145 . doi: 10.13801/j.cnki.fhclxb.20240319.001 http://dx.doi.org/10.13801/j.cnki.fhclxb.20240319.001

Hassan E. A. M. ; Elagib T. H. H. ; Memon H. ; Yu M. H. ; Zhu S. Surface modification of carbon fibers by grafting PEEK-NH2 for improving interfacial adhesion with polyetheretherketone . Materials , 2019 , 12 ( 5 ), 778 . doi: 10.3390/ma12050778 http://dx.doi.org/10.3390/ma12050778

Ren T. N. ; Zhu G. M. ; Hou X. ; Li B. ; Hao Y. J. Improvement of interfacial interactions in CF/PEEK composites by an s-PSF/graphene oxide compound sizing agent . J. Appl. Polym. Sci. , 2021 , 138 ( 45 ), 51327 . doi: 10.1002/app.51327 http://dx.doi.org/10.1002/app.51327

Yuan C. C. ; Li D. Z. ; Yuan X. Y. ; Liu L. ; Huang Y. D. Preparation of semi-aliphatic polyimide for organic-solvent-free sizing agent in CF/PEEK composites . Compos. Sci. Technol. , 2021 , 201 , 108490 . doi: 10.1016/j.compscitech.2020.108490 http://dx.doi.org/10.1016/j.compscitech.2020.108490

Xing Y. ; Zhang D. J. ; Wang C. B. ; Ni H. J. ; Li J. ; Chen X. B. Research progress in carbon fiber sizing agents for PEEK composites . J. Mater. Eng , 2022 , 50 ( 8 ), 70 - 81 .

Yu C. ; Luo J. P. ; Zeng X. P. ; Wang D. W. ; Wang W. ; Wu J. Y. Research progress of polyamide-amine dendrimer modified separation membrane in water treatment . Polym. Bull , 2024 , 37 ( 6 ), 766 - 775 .

Miao Y. ; Chen Q. H. ; Li Y. G. ; Zhuo D. X. ; Wang R. Tribological properties of carbon nanotube/polymer composites: a mini-review . Front. Mater. , 2023 , 10 , 1129676 . doi: 10.3389/fmats.2023.1129676 http://dx.doi.org/10.3389/fmats.2023.1129676

梁琦 , 杨群 , 王黎明 , 代正伟 . 温敏型聚酰胺-胺型树状聚合物的研究进展 . 功能材料 , 2020 , 51 ( 4 ), 4054 - 4060 . doi: 10.3969/j.issn.1001-9731.2020.04.009 http://dx.doi.org/10.3969/j.issn.1001-9731.2020.04.009

Gao B. ; Zhang R. L. ; Gao F. C. ; He M. S. ; Wang C. G. ; Liu L. ; Zhao L. F. ; Cui H. Z. Interfacial microstructure and enhanced mechanical properties of carbon fiber composites caused by growing generation 1-4 dendritic poly(amidoamine) on a fiber surface . Langmuir , 2016 , 32 ( 33 ), 8339 - 8349 . doi: 10.1021/acs.langmuir.6b01485 http://dx.doi.org/10.1021/acs.langmuir.6b01485

Zhao M. ; Meng L. H. ; Ma L. C. ; Wu G. S. ; Xie F. ; Ma L. N. ; Wang W. ; Jiang B. ; Huang Y. D. Stepwise growth of melamine-based dendrimers onto carbon fibers and the effects on interfacial properties of epoxy composites . Compos. Sci. Technol. , 2017 , 138 , 144 - 150 . doi: 10.1016/j.compscitech.2016.11.013 http://dx.doi.org/10.1016/j.compscitech.2016.11.013

唐鸣津 , 王艺璇 , 杨晓萱 , 薛键鑫 , 王露露 , 王帅 , 宋晨飞 , 陆焕焕 , 张永振 , 李杰 , 逄显娟 . 增强体表面改性对碳纤维/聚醚醚酮复合材料摩擦磨损性能的影响 . 高分子学报 , 2025 , 56 ( 4 ), 653 - 667 .

Tang M. J. ; Wang Y. X. ; Yang X. X. ; Xue J. X. ; Wang L. L. ; Wang S. ; Li J. ; Song C. F. ; Lu H. H. ; Pang X. J. ; Chen B. B. ; Zhang Y. Z. The synergistic effects of modified carbon fiber and multiwalled carbon nanotubes on the tribological properties of polyetheretherketone composites . ACS Appl. Polym. Mater. , 2025 , 7 ( 17 ), 11248 - 11261 . doi: 10.1021/acsapm.5c01764 http://dx.doi.org/10.1021/acsapm.5c01764

Li Y. C. ; Li H. F. ; Dong J. X. ; Chen Z. ; Zhao J. K. ; Huan X. H. ; Jia X. L. ; Ge L. ; Yang X. P. ; Zu L. ; Geng H. B. ; Chen X. P. ; Li T. M. ; Ding W. H. Revisiting the sequential evolution of sizing agents in CFRP manufacturing to guide cross-scale synergistic optimization of interphase gradient and infiltration . Compos. Part B Eng. , 2024 , 287 , 111825 . doi: 10.1016/j.compositesb.2024.111825 http://dx.doi.org/10.1016/j.compositesb.2024.111825

Liu H. S. ; Zhao Y. ; Li N. ; Li S. ; Li X. K. ; Liu Z. W. ; Cheng S. ; Wang K. ; Du S. Y. Effect of polyetherimide sizing on surface properties of carbon fiber and interfacial strength of carbon fiber/polyetheretherketone composites . Polym. Compos. , 2021 , 42 ( 2 ), 931 - 943 . doi: 10.1002/pc.25876 http://dx.doi.org/10.1002/pc.25876

Ansari M. S. ; Zafar S. ; Pathak H. A comprehensive review of surface modification techniques for carbon fibers for enhanced performance of resulting composites . Results Surf. Interfaces , 2023 , 12 , 100141 . doi: 10.1016/j.rsurfi.2023.100141 http://dx.doi.org/10.1016/j.rsurfi.2023.100141

Zhang N. ; Said A. ; Wischke C. ; Kral V. ; Brodwolf R. ; Volz P. ; Boreham A. ; Gerecke C. ; Li W. Z. ; Neffe A. T. ; Kleuser B. ; Alexiev U. ; Lendlein A. ; Schäfer-Korting M. Poly[acrylonitrile- co -( N -vinyl pyrrolidone) ] nanoparticles-composition-dependent skin penetration enhancement of a dye probe and biocompatibility . Eur. J. Pharm. Biopharm. , 2017 , 116 , 66 - 75 . doi: 10.1016/j.ejpb.2016.10.019 http://dx.doi.org/10.1016/j.ejpb.2016.10.019

Gao B. ; Zhang R. L. ; He M. S. ; Wang C. G. ; Liu L. ; Zhao L. F. ; Wen Z. J. ; Ding Z. P. Interfacial microstructure and mechanical properties of carbon fiber composites by fiber surface modification with poly(amidoamine)/polyhedral oligomeric silsesquioxane . Compos. Part A Appl. Sci. Manuf. , 2016 , 90 , 653 - 661 . doi: 10.1016/j.compositesa.2016.08.036 http://dx.doi.org/10.1016/j.compositesa.2016.08.036

Peng X. C. ; Wu Y. F. ; Wei Z. M. Research progress on the surface modification of carbon fiber . RSC Adv. , 2024 , 14 ( 6 ), 4043 - 4064 . doi: 10.1039/d3ra08577e http://dx.doi.org/10.1039/d3ra08577e

Tang M. J. ; Lu H. H. ; Pang X. J. ; Wang Y. X. ; Yang X. X. ; Xue J. X. ; Wang L. L. ; Wang S. ; Song C. F. ; Zhang Y. Z. ; Li J. Enhanced interfacial and tribological properties of polyether ether ketone composites by the addition of modified carbon fibers . Polym. Compos. , 2025 , 46 ( 18 ), 17123 - 17141 . doi: 10.1002/pc.70100 http://dx.doi.org/10.1002/pc.70100

Akbari S. ; Bahi A. ; Farahani A. ; Milani A. S. ; Ko F. Fabrication and characterization of lignin/dendrimer electrospun blended fiber mats . Molecules , 2021 , 26 ( 3 ), 518 . doi: 10.3390/molecules26030518 http://dx.doi.org/10.3390/molecules26030518

Athulya Wickramasingha Y. ; Dharmasiri B. ; Randall J. D. ; Yin Y. T. ; Andersson G. G. ; Nepal D. ; Newman B. ; Stojcevski F. ; Eyckens D. J. ; Henderson L. C. Surface modification of carbon fiber as a protective strategy against thermal degradation . Compos. Part A Appl. Sci. Manuf. , 2022 , 153 , 106740 . doi: 10.1016/j.compositesa.2021.106740 http://dx.doi.org/10.1016/j.compositesa.2021.106740

Roosta A. ; Zendehboudi S. ; Rezaei N. Estimating contact angle of pure and mixed liquids on smooth solid surfaces using dispersive-to-attractive surface energy ratio from PCP-SAFT model . Chem. Eng. Sci. , 2024 , 300 , 120607 . doi: 10.1016/j.ces.2024.120607 http://dx.doi.org/10.1016/j.ces.2024.120607

Duan Z. Q. ; Li W. D. ; Liu H. S. ; Shen P. F. ; Yang H. Z. ; Zhong X. Y. ; Bao J. W. Synergetic improvement of interfacial performance and impact resistance of carbon fiber-reinforced epoxy composite via continuous electrochemical oxidation . Polymers , 2025 , 17 ( 8 ), 1007 . doi: 10.3390/polym17081007 http://dx.doi.org/10.3390/polym17081007

Bai Y. G. ; Qian H. X. ; Cao X. L. ; Wen F. Y. ; He Y. S. ; Ma J. R. ; Cheng L. ; Wang Y. F. ; Tan H. Y. ; Gu Y. X. ; Lian P. B. ; Chen R. ; Mu J. X. Three-dimensional thermal network structured GnPs&MWCNTs@PBO/PEEK composites integrating high thermal conductivity and electromagnetic shielding . J. Mater. Chem. A , 2024 , 12 ( 36 ), 24633 - 24646 . doi: 10.1039/D4TA03002H http://dx.doi.org/10.1039/D4TA03002H

Li W. ; Li Z. ; Zhang Z. N. Tribological behavior of the carbon fiber-reinforced epoxy resin matrix composite with orderly arranged carbon nanotubes . Tribol. Int. , 2025 , 201 , 110246 . doi: 10.1016/j.triboint.2024.110246 http://dx.doi.org/10.1016/j.triboint.2024.110246

Hassan E. A. M. ; Yang L. L. ; Elagib T. H. H. ; Ge D. T. ; Lv X. W. ; Zhou J. F. ; Yu M. H. ; Zhu S. Synergistic effect of hydrogen bonding and π-π stacking in interface of CF/PEEK composites . Compos. Part B Eng. , 2019 , 171 , 70 - 77 . doi: 10.1016/j.compositesb.2019.04.015 http://dx.doi.org/10.1016/j.compositesb.2019.04.015

Li Y. Z. ; Xu N. ; Lyu H. X. ; Jiang N. Y. ; Zhang H. Y. ; Zhou N. ; Zhang D. X. Enhanced mechanical and tribological properties of carbon fiber/PEEK composites by hydroxylated boron nitride nanosheets and polyetherimide sizing agents . Compos. Sci. Technol. , 2023 , 232 , 109851 . doi: 10.1016/j.compscitech.2022.109851 http://dx.doi.org/10.1016/j.compscitech.2022.109851

Liu M. ; Zhang Z. Z. ; He Y. H. ; Liao C. Y. ; Yang M. M. ; Chu F. J. ; Jiang W. ; Yuan J. Y. ; Liu W. M. Enhanced interfacial and tribological properties of fabric liner by constructing a MXene/HNTs/PAMAM hierarchical coating . Polym. Compos. , 2024 , 45 ( 9 ), 7879 - 7892 . doi: 10.1002/pc.28310 http://dx.doi.org/10.1002/pc.28310

Chen B. B. ; Li X. F. ; Yang J. ; Huang H. ; Peng W. X. ; Li C. S. ; Zhang Z. Z. Enhancement of the tribological properties of carbon fiber/epoxy composite by grafting carbon nanotubes onto fibers . RSC Adv. , 2016 , 6 ( 55 ), 49387 - 49394 . doi: 10.1039/c6ra05081f http://dx.doi.org/10.1039/c6ra05081f

Sahu R. ; Ponnusami S. A. ; Weimer C. ; Harursampath D. Interface engineering of carbon fiber composites using CNT: a review . Polym. Compos. , 2024 , 45 ( 1 ), 9 - 42 . doi: 10.1002/pc.27772 http://dx.doi.org/10.1002/pc.27772

Chen Y. ; Tao J. ; Li S. ; Khashab N. M. Compositing polyetherimide with polyfluorene wrapped carbon nanotubes for enhanced interfacial interaction and conductivity . ACS Appl. Mater. Interfaces , 2014 , 6 ( 12 ), 9013 - 9022 . doi: 10.1021/am4054805 http://dx.doi.org/10.1021/am4054805

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Study on Thermally Conductive Carbon Fiber/Phthalonitrile Composites

Study on the Introduction of Carbon Nanotubes into Carbon Fiber Reinforced Heterocyclic Phthalazinone Biphenyl Poly(aryl ether sulfone ketone) Composite Interlaminar Regions via Two-step Solution Impregnation and Their Interlaminar Toughening Effect

Study on the Regulation of Porous Structure and Tribological Behavior of Fluorinated Crosslinked Polyimide

Effect of Interface Modification on Mechanical Properties and Friction and Wear Properties of Carbon Fiber/Polyetheretherketone Composites

Research Progress in Polymers for Humanoid Robots

Related Author

Lu-lu Wang

Jian-xin Xue

Jie Li

Huan-huan Lu

Shuai Wang

Jian Liu

Chen-fei Song

Xian-juan Pang

Related Institution

School of Chemistry and Chemical Engineering, Henan University of Science and Technology

National United Engineering Laboratory for Advanced Bearing Tribology, Henan University of Science and Technology

School of Materials Science and Engineering, Beihang University

Institute of Chemistry, Chinese Academy of Sciences

School of Materials Science and Engineering, Dalian University of Technology

AI问答

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802046899号
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰