Synthesis and Ring-opening Polymerizations of Cyclic Carbonates Derived from Carbon Dioxide/Diol Reactions

You-hua Chen; Jia-bao Wang; Xin Hu; Ning Zhu

doi:10.11777/j.issn1000-3304.2026.26111

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Synthesis and Ring-opening Polymerizations of Cyclic Carbonates Derived from Carbon Dioxide/Diol Reactions

更新时间：2026-07-23

- Synthesis and Ring-opening Polymerizations of Cyclic Carbonates Derived from Carbon Dioxide/Diol Reactions
- Acta Polymerica Sinica Pages: 1-19(2026)
- 作者机构：
  
  1.南京工业大学，生物与制药工程学院材料化学工程国家重点实验室，南京 211800
  2.南京工业大学，材料科学与工程学院，南京 211800
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2026.26111
  CLC：
- CSTR：32057.14.GFZXB.2026.7657
- Received：14 April 2026，
  
  Accepted：15 June 2026，
  
  Online First：23 July 2026，
- 稿件说明：
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陈有华, 王家宝, 胡欣, 朱宁. 基于二氧化碳/二醇反应环碳酸酯的合成与开环聚合. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26111.

Chen, Y. H.; Wang, J. B.; Hu, X.; Zhu, N. Synthesis and ring-opening polymerizations of cyclic carbonates derived from carbon dioxide/diol reactions. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26111.
陈有华, 王家宝, 胡欣, 朱宁. 基于二氧化碳/二醇反应环碳酸酯的合成与开环聚合. 高分子学报, doi: 10.11777/j.issn1000-3304.2026.26111. DOI： CSTR： 32057.14.GFZXB.2026.7657.

Chen, Y. H.; Wang, J. B.; Hu, X.; Zhu, N. Synthesis and ring-opening polymerizations of cyclic carbonates derived from carbon dioxide/diol reactions. Acta Polymerica Sinica (in Chinese), doi: 10.11777/j.issn1000-3304.2026.26111. DOI： CSTR： 32057.14.GFZXB.2026.7657.

摘要

二氧化碳(CO

)转化为高附加值精细化学品和高分子材料，已成为高分子化学和绿色化学等领域的研究热点. 其中，CO

与二醇反应合成环碳酸酯是重要的方向之一，通过环碳酸酯的催化可控开环聚合可以制备不同结构和性能的聚碳酸酯材料. 本综述以1

3-二醇衍生物、1

4-二醇衍生物、1

5-二醇衍生物与CO

反应分类，介绍了六元环、七元环和八元环碳酸酯单体的合成与开环聚合研究进展，并且对相关领域所面临的机遇与挑战进行了探讨和展望.

Abstract

The high-value utilization of carbon dioxide (CO

) for the conversion into fine chemicals and polymer materials have been paid much attention in polymer science and green chemistry. Among them

the reaction of CO

with diols to produce cyclic carbonates

represents an important direction. Through the catalytic controlled ring-opening polymerizations of cyclic carbonates

polycarbonates with different structures and properties can be prepared. This review focuses on synthesis and ring-opening polymerizations of cyclic carbonates derived from CO

/diol reactions. The reactions of CO

with 1

3-diol derivatives

4-diol derivatives

and 1

5-diol derivatives were summarized in order with the target products of six-membered

seven-membered

and eight-membered cyclic carbonates. Catalytic ring-opening polymerizations of these obtained cyclic carbonates into polycarbonates were highlighted. Moreover

the challenges and opportunities in the related fields were discussed.

关键词

Keywords

references

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