STIMULI-RESPONSE OF HYDROPHILIC-HYDROPHOBIC SEMI-IPN HYDROGELS UNDER DC ELECTRIC FIELD
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Research Article|更新时间:2021-03-19
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STIMULI-RESPONSE OF HYDROPHILIC-HYDROPHOBIC SEMI-IPN HYDROGELS UNDER DC ELECTRIC FIELD
Acta Polymerica SinicaIssue 1, Pages: 25-29(2002)
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Published:20 February 2002,
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ZHANG Jianhe, YANG Yajiang. STIMULI-RESPONSE OF HYDROPHILIC-HYDROPHOBIC SEMI-IPN HYDROGELS UNDER DC ELECTRIC FIELD. [J]. Acta Polymerica Sinica (1):25-29(2002)
DOI:
ZHANG Jianhe, YANG Yajiang. STIMULI-RESPONSE OF HYDROPHILIC-HYDROPHOBIC SEMI-IPN HYDROGELS UNDER DC ELECTRIC FIELD. [J]. Acta Polymerica Sinica (1):25-29(2002)DOI:
STIMULI-RESPONSE OF HYDROPHILIC-HYDROPHOBIC SEMI-IPN HYDROGELS UNDER DC ELECTRIC FIELD
The stimuli-response of hydrophilic-hydrophobic semi-IPN hydrogels consisted of polyacrylic acid (PAAc)/poly (N-dodecyl-4-vinyl pyridinium bromide) (QPVPD) under DC electric field was investigated.The QPVPD chains were entangled with the PAAc polymer network and were fixed in the semi-IPN hydrogels.Under the contact electric fields
the deswelling of the gel was observed in the anode side of the gel
which was attributed to the hydrophobic interaction.Under the non-contact electric field
the gel bars bend toward the cathode side in a weak alkaline solution (pH=9)
but toward anode side in a weak acidic solution (pH=4).These properties of the gel are related to both the change of hydrophilic interaction and hydrophobic interaction.