Using 2-phenoxyethanol as initial material

a novel phenolic type polymeric bisazacrown pseudo ether PACE were synthesized by methods of first polymerization then functionalization and Na+ template-guided．Series synthetic reactions were studied using FTIR spectra method for tracking monitor．A best experimental formula of phend-aldehyde crosslinking reaction using monomer phenoxyethanol and a better conditions of series substitution reactions on the phenolic aldehyde parent polymer were achieved．FTIR spectra data of polymers of a series were achieved also．Polymeric static adsorption properties for normal metallic ions were tested．The results showed that the polymer has good adsorption properties for K+

Na+

Hg2+

Cd2+

Fe3+

Pb2+

Cu2+ and the capacities of adsorption were 1.43

0.98

1.84

0.68

0.79

0.61 and 0.57 mmol／g-r

respectively．By FTIR spectra method

a preliminary discussion on adsorption mechanism was given in this paper．The results showed not only —CH2OCH22—and PhOCH2—and —CH2NCH2—

could chelate metalion

but also —CH2OH did to a certain extent in the above mentioned complexes．There is slow oxidation-reduction in the adsorption of Hg2+ on PACE and the —CH2OH in the polymer PACE was oxidized to —COOH and Hg2+ were reduced to Hg2+2．