The crystallization process of uniaxially oriented poly(ethylene terephthalate)(PET)was investigated by using DSC with a constant heating rate.The cold crystallization thermograms of uniaxially oriented PET exhibit multiple-overlapping peaks.This phenomenon was also confirmed by the isothermal DSC studies. A new method was proposed to obtain the crystallization kinetic parameters of polymers from the complicated DSC curves. The result indicated that the theoretical curve calculated from the new method shows a better agreement with the experimental data than that from the other methods.The crystallization process of uniaxially oriented PET was analyzed by using a model that involved three different crystallization mechanisms depending on different temperature ranges. The whole crystallization process of uniaxially oriented PET consists of three sub-processes. Crystallization mechanism was explained based on the change of the Avrami exponent and mass fraction of every sub-process with draw ratio.
CRYSTALLIZATION BEHAVIOR OF POLY(BUTYLENE DODECANEDIOATE) AND COPOLYESTER
NON-ISOTHERMAL CRYSTALLIZATION BEHAVIOR OF POLYPROPYLENE GRAFTED POLYURETHANE
NON-ISOTHERMAL CRYSTALLIZATION BEHAVIOR OF MALEIC ANHYDRIDE GRAFT POLYPROPYLENE AND ITSIONOMERS
KINETICS OF NONISOTHERMAL CRYSTALLIZATION OF ORIENTED POLY (ETHYLENE TEREPHTHALATE) FIBERS
KINETICS OF NON-ISOTHERMAL CRYSTALLIZATION OF PET——DERIVING THE PARAMETERS CHARACTERIZING CRYSTALLIZATION KINETICS FROM DSC CURVES WITH SEVERAL HEATING OR COOLING RATES