ATOM TRANSFER RADICAL POLYMERIZATION OF METHYL METHACRYLATECATALYZED BY IRON+Ⅱ CHLORIDE/β-ALA SCHIFF BASE SYSTEM

LI Yongsheng; LIU Wenguang; YAO Kangde; WANG Guochang; LI Hexian

doi:null

您当前的位置：

首页 >

文章列表页 >

ATOM TRANSFER RADICAL POLYMERIZATION OF METHYL METHACRYLATECATALYZED BY IRON+Ⅱ CHLORIDE/β-ALA SCHIFF BASE SYSTEM

Research Bulletin | 更新时间：2021-03-19

- ATOM TRANSFER RADICAL POLYMERIZATION OF METHYL METHACRYLATECATALYZED BY IRON+Ⅱ CHLORIDE/β-ALA SCHIFF BASE SYSTEM
- Acta Polymerica Sinica Issue 5, Pages: 770-772(2004)
- 作者机构：
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：20 October 2004，
扫描看全文
LI Yongsheng, LIU Wenguang, YAO Kangde, WANG Guochang, LI Hexian. ATOM TRANSFER RADICAL POLYMERIZATION OF METHYL METHACRYLATECATALYZED BY IRON+Ⅱ CHLORIDE/β-ALA SCHIFF BASE SYSTEM. [J]. Acta Polymerica Sinica (5):770-772(2004)
DOI：

LI Yongsheng, LIU Wenguang, YAO Kangde, WANG Guochang, LI Hexian. ATOM TRANSFER RADICAL POLYMERIZATION OF METHYL METHACRYLATECATALYZED BY IRON+Ⅱ CHLORIDE/β-ALA SCHIFF BASE SYSTEM. [J]. Acta Polymerica Sinica (5):770-772(2004) DOI：

摘要

Abstract

A new catalyst

iron(Ⅱ) chelate of the schiff base derived from β-Ala and picoline

was successfully used for atom transfel radical polymerization．The reaction was carried out at 90℃ in bulk with ethyl 2-bromo-2-ethylpropionate as the initiator．The molecular weight of the resulting polymer increases with increasing monomer conversion．The molecular weight distribution is not narrow(PDI=1.5～1.7)

and the value of molecular weight detected is in good accordance with the calculated. The molecular weight distribution is 1.13 with the addition of 10％ DMF.

关键词

甲基丙烯酸甲酯原子转移自由基聚合β-丙氨酸席夫碱

Keywords

references

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

MECHANISTIC STUDY OF CATALYTIC OXIDATIVE COPOLYMERIZATION OF 2-(N,N-DIMETHYLAMINO)ETHYL METHACRYLATE AND METHYL METHACRYLATE

“LIVING" RADICAL POLYMERIZATION OF METHYL METHACRYLATE IN[mim][HCOO] IONIC LIQUID SYSTEM

ATOM TRANSFER RADICAL SUSPENSION POLYMERIZATION OF METHYL METHACRYLATE

STUDIES ON THE ATOM TRANSFER RADICAL COPOLYMERIZATION OF VINYL MONOMER AND VINYL MONOMER CONTAINING NITROXIDE GROUP

EFFECT OF MONOMER POLYMERIZATION SEQUENCE ON THE SYNTHESIS OF POLY(METHYL METHACRYLATE-b-STYRENE) BY ATOM TRANSFER RADICAL POLYMERIZATION

Related Author

No data

Related Institution

Department of Applied Chemistry,School of Science,Northwestern Polytechnical University

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰