Macropemus hypercmssllnked resins with high specific area and rigid framework could possibly still retain considerable specific area after being loaded with polar groups．Excellent resins with high specific area and high functional selectivity could be obtained by aminating macroporous hypercrosslinked resins A series of aminated adsorption resins have been prepared by loading different amidocyanogen groups on maeroporous hypercmsslinked polystyrene．The sorption of phenol and aniline on the synthesized resins in aqueous and nonaqueous solutions was investigated The result showed the selectivity of phenol in both systems increased with alkalescence increasing of the loaded amination In n-hexane solutions．phenol and aniline may form hydrogen bond with the hydrogen acceptor of the adsorbent．In aqueous solutions

the study on the adsorption of phenol from water has indicated that the interaction was a synergy of hydrongen bending and hydrophobie interaction．The study of dynamic adsorption of phenol and aniline in water onto a pre-aminated resin(Rfl8) and a quaternary ammonium resin (Rs6) showed that for Rfl8

phenol leaked out first at 147 bed volume(BV)．The content of effluent solution rose fast and saturated at 212 BV．Aniline leaked out at 184 BV and the content of effluent solution lose slowly．For Rs6

aniline leaked out first (17BV) and the content of effluent solution saturated fast (47 BV)．Phenol leaked out at 44 BV and the coateat of effluent solution also lose fast

and reached saturation at 79 BV.So in the range of 17～44 BV

aniline could be obtained.