THE STUDY ON THE PROPERTIES OF ADSORPTION OF VB12 BY PHENOLIC RESIN ADSORBENT
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Research Article|更新时间:2021-03-19
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THE STUDY ON THE PROPERTIES OF ADSORPTION OF VB12 BY PHENOLIC RESIN ADSORBENT
Acta Polymerica SinicaIssue 1, Pages: 64-69(2004)
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Published:20 February 2004,
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WANG Zhong, SHI Zuoqing, SHI Rongfu, FAN Yunge, YANG Yizhong. THE STUDY ON THE PROPERTIES OF ADSORPTION OF VB12 BY PHENOLIC RESIN ADSORBENT. [J]. Acta Polymerica Sinica (1):64-69(2004)
DOI:
WANG Zhong, SHI Zuoqing, SHI Rongfu, FAN Yunge, YANG Yizhong. THE STUDY ON THE PROPERTIES OF ADSORPTION OF VB12 BY PHENOLIC RESIN ADSORBENT. [J]. Acta Polymerica Sinica (1):64-69(2004)DOI:
THE STUDY ON THE PROPERTIES OF ADSORPTION OF VB12 BY PHENOLIC RESIN ADSORBENT
The adsorption of VB12 was studied by usingthree phenolic resin adsorbents:JDW-1
JDW-2
preparedin the laboratory and a commercial product Duolite S-761 under static and dymanic conditions.The experimental results show that JDW-1 is superior to Duolite S-761 in adsorption of VB12(the saturation adsorption capacity of JDW-1 for VB12 is 84 mg/g dried resin).A semi-empirical rate equation adequately fits the sorption rate data of VB12 in the initial period.till about 43%~69% of the equilibrium adsorption.The equilibrium adsorption date for phenolic resin adsorbents/VB12 systems showed good agreement with the Langmuir isotherm equation.The correlation coefficients are larger than 0.99 The adsorption of VB12 therefore is monomolecular adsorption.Experiments of stripping VB12 from JDW-2 resin with 80% aqueous methoanol showed that 92.20%and 95.93% of the adsorbed VB12 were removed at 4.2 and 6.4 bed volumes
respectively
(the desorption rate was 1.1 BV/h).It implies that phenolic resin adsorbents own excellent desorption performance
and it is good to use 80% aqueous methanol as desorption solvent for stripping VBl2 from JDW-2