SYNTHESIS OF BDIE·[Zn-(O-iPr)2] CATALYST AND COPOLYMERIZATION OF CO2 AND CYCLOHEXENE OXIDE

YOU Jinxiu; CUI Qi; ZHANG Min; LIU Baohua; CHEN Liban; ZHANG Songwei

doi:null

您当前的位置：

首页 >

文章列表页 >

SYNTHESIS OF BDIE·[Zn-(O-iPr)2] CATALYST AND COPOLYMERIZATION OF CO2 AND CYCLOHEXENE OXIDE

Rapid Communications | 更新时间：2021-03-19

- SYNTHESIS OF BDIE·[Zn-(O-iPr)2] CATALYST AND COPOLYMERIZATION OF CO2 AND CYCLOHEXENE OXIDE
- Acta Polymerica Sinica Issue 4, Pages: 481-483(2005)
- 作者机构：
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：20 August 2005，
扫描看全文
YOU Jinxiu, CUI Qi, ZHANG Min, LIU Baohua, CHEN Liban, ZHANG Songwei. SYNTHESIS OF BDIE·[Zn-(O-iPr)2] CATALYST AND COPOLYMERIZATION OF CO2 AND CYCLOHEXENE OXIDE. [J]. Acta Polymerica Sinica (4):481-483(2005)
DOI：

YOU Jinxiu, CUI Qi, ZHANG Min, LIU Baohua, CHEN Liban, ZHANG Songwei. SYNTHESIS OF BDIE·[Zn-(O-iPr)2] CATALYST AND COPOLYMERIZATION OF CO2 AND CYCLOHEXENE OXIDE. [J]. Acta Polymerica Sinica (4):481-483(2005) DOI：

摘要

Abstract

A novel α-diimine Zn catalyst for copolymerization of carbon dioxide and eyelohexene oxide was synthesized with 2

6-diisopropylaniline

glyoxal

diethylzinc and isopropanol．The precursor N

N’-bi(2

6-diis-opmpylphenyl) ethyldiimine (BDIE) was characterized by 1H-NMR and proved to be an α-diimine．The copolymerization of carbon dioxide and cyclohexene oxide was investigated by changing feeding processes with two catalysts including α-diimine and β-diimine zinc compounds．Catalytic efficiency for the eopolymerization was enhanced up to 1.17×105g polymedmol cat by appilcation of batch polymerizations in which monomers were fed in batch.

关键词

二氧化碳氧化环己烯共聚催化剂加料方式

Keywords

references

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

COPOLYMERIZATION OF CO2 AND CYCLOHEXENE OXIDE USING AGING BDIE·[Zn-Al] CATALYST

Studies of the Copolymerization of Carbon Dioxide and Cyclohexene Oxide with Salen Al(OiPr) Catalyst and Effects of Reaction Consitions

SALENAl(OPr) CATALYST FOR THE COPOLYMERIZATION OF CO2 AND CYCLOHEXENE OXIDE

COPOLYMERIZATION OF CO2 AND CYCLOHEXENE OXIDE USING A BDIE·[Zn-Al] CATALYST

COPOLYMERIZATION OF CARBON DISULFIDE AND CYCLOHEXENE OXIDE WITH A DOUBLE-METAL CYANIDE COMPLEX CATALYST

Related Author

No data

Related Institution

北京分子科学国家研究中心高分子化学与物理教育部重点实验室北京大学化学与分子工程学院

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰