Shear-induced crystallization behavior of isotactic polypropylene (iPP) was investigated using a rotational rheometry covering a shear rate range of 1.2×10-4~1 s-1 and temperatures between 135℃ and 145℃.As the specimen was sheared at a constant rate
the viscosity and normal force were constant at first
then started to increase sharply after a certain time.At higher shear rates the transition of the normal force occurred considerably earlier than that of the viscosity
and at medium shear rates the two transition times were coincident.However at extremely low shear rates the data of normal force became noisy and only the data of viscosity was reliable.It was suggested that the earlier time in transitions for the normal force and viscosity was used to define an onset time (ton)which characterized the crystallization process.Furthermore
it is proposed that the plot of ton versus shear rate can be converted into a temperature-invariant curve by dividing the y axis by quiescent onset time ton
FOURIER-TRANSFORM RHEOLOGY STUDIES ON THE CRYSTALLIZATION OFISOTACTIC POLYPROPYLENE IN NON-LINEAR LARGE STRAIN OSCILLATION SHEAR FIELDS
DISPERSION AND CRYSTALLIZATION BEHAVIOR OF POLYPROPYLENE NANCOMPOSITES WITH NUCLEATING AGENT MODIFIED MULTIWALL CARBON NANOTUBES
EFFECT OF NEMATIC LIQUID CRYSTALLINE COPOLYMER AS A β-FORM NUCLEATOR ON CRYSTALLIZATION STRUCTURE AND THERMAL PROPERTIES OF ISOTACTIC POLYPROPYLENE
STUDIES ON STRUCTURE EVOLUTION OF LDPE DURING CROSSLINKING PROCESS BY RHEOLOGICAL TESTS
STUDY ON CORRELATION BETWEEN RHEOLOGICAL AND CONDUCTIVEBEHAVIOR THROUGH SIMULTANEOUS MEASUREMENTS DURINGISOTHERMAL CRYSTALLIZATION FOR CARBON BLACKFILLED ISOTACTIC POLYPROPYLENE
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Key Laboratory for Ultrafine Materials of Ministry of Education, East China University of Science and Technology