ZHAN Maosheng, NARISAWA Ikuo. THE EFFECT OF SPHERULIE CRYSTAL ON PROPERTIES OF TENSILE FRACTURE OF NYLON 6 AND NYLON 6 ALLOY. [J]. Acta Polymerica Sinica (3):317-323(1998)
DOI:
ZHAN Maosheng, NARISAWA Ikuo. THE EFFECT OF SPHERULIE CRYSTAL ON PROPERTIES OF TENSILE FRACTURE OF NYLON 6 AND NYLON 6 ALLOY. [J]. Acta Polymerica Sinica (3):317-323(1998)DOI:
THE EFFECT OF SPHERULIE CRYSTAL ON PROPERTIES OF TENSILE FRACTURE OF NYLON 6 AND NYLON 6 ALLOY
The work disscussed the effect of structure of spherulite on properties of pure nylon 6 and Nylon 6/TPAE/Compatibilizer alloy by the experiment of changing the cooling velocity when shaping.First
melts of pure nylon 6 and Nylon 6/TPAE/Compatibilizer alloy were cooled rapidly and slowly on the condition of 4℃ water and 23℃ air respectively.Second
they were made into specimens.Then
specimens were carried on observation of structure of spherulite and dispersioin morphology and analyses of absorbing heat
meanwhile by PLM
SEM and DSC
carried on the experiment of tensile fracture and interface tearing. The results show;(1) Dispersion particles are well-distributed between interface and interior of spherulite or between lameller crystals.(2)The size of spherulit is greatly is greatly different when pure nylong 6 is cooled rapidly in 4℃ water.But that of spherulite is well-distributed when it is cooled slowly in 23℃ air.The comparison of them shows the latter speciment's size of spherulite is large and fracture strength is high
with decreasing deformation and energy of tensile fracture.(3) The size of spherulite is small but differs greatly when Nylon6/TPAE/A8200 alloy was cooled rapidly in 4℃ water
but that of spherulite is large and well-distributed in 23℃ air.The comparison of them shows the latter specimen's size of spherulite is large and fracture strength is high
with increasing the deformation and energy and energy of tensile fracture.(4) On the same cooling condition
the change trend of size of soherulite of pure nylon 6 and nylon 6/TPAE/Compatibilizer alloy is same
but that of properties of tensile freacture is oppsite.This a because slow cooling contributes to not only the formation of large spherulite but also the enhancement of adhesion strength of interface between the dispersed phase TPAE and successive phase nylon 6.On the other hand
the dispersion of tiny TPAE particle in the interface and interior of nylon 6 spherulite strengthens the deformation ability of spherulite
and enhances the strength deformation and energy of tenssile fracture. Pure nylon 6 has not these specific properties.Therefore
though the size of spherulite is one of factors which influence fracture properties of nylon6
the interface of spherulite
non-crystal stucture between lamellar crysrals
voiding of tiny elastic and adhesion strength of phase interface are main factors which influence fracture properties of nylon 6.