SYNTHESIS AND CHARACTERIZATION OF POLY(ARYL ETHER KETONE) FROM 1-METHYL-4,5-BIS (CHLOROBENZOYL) CYCLOHEXENE AND 4-(3,5 DIMETHYL-4-HYDROXYPHENYL)-2,3-PHTHAZIN-1-ONE

WANG Lijiang; JIAN Xigao; LIU Yanjun; WANG Jinyan

doi:null

您当前的位置：

首页 >

文章列表页 >

SYNTHESIS AND CHARACTERIZATION OF POLY(ARYL ETHER KETONE) FROM 1-METHYL-4,5-BIS (CHLOROBENZOYL) CYCLOHEXENE AND 4-(3,5 DIMETHYL-4-HYDROXYPHENYL)-2,3-PHTHAZIN-1-ONE

Research Article | 更新时间：2021-03-19

- SYNTHESIS AND CHARACTERIZATION OF POLY(ARYL ETHER KETONE) FROM 1-METHYL-4,5-BIS (CHLOROBENZOYL) CYCLOHEXENE AND 4-(3,5 DIMETHYL-4-HYDROXYPHENYL)-2,3-PHTHAZIN-1-ONE
- Acta Polymerica Sinica Issue 6, Pages: 676-680(2000)
- 作者机构：
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：20 December 2000，
扫描看全文
WANG Lijiang, JIAN Xigao, LIU Yanjun, WANG Jinyan. SYNTHESIS AND CHARACTERIZATION OF POLY(ARYL ETHER KETONE) FROM 1-METHYL-4,5-BIS (CHLOROBENZOYL) CYCLOHEXENE AND 4-(3,5 DIMETHYL-4-HYDROXYPHENYL)-2,3-PHTHAZIN-1-ONE. [J]. Acta Polymerica Sinica (6):676-680(2000)
DOI：

WANG Lijiang, JIAN Xigao, LIU Yanjun, WANG Jinyan. SYNTHESIS AND CHARACTERIZATION OF POLY(ARYL ETHER KETONE) FROM 1-METHYL-4,5-BIS (CHLOROBENZOYL) CYCLOHEXENE AND 4-(3,5 DIMETHYL-4-HYDROXYPHENYL)-2,3-PHTHAZIN-1-ONE. [J]. Acta Polymerica Sinica (6):676-680(2000) DOI：

摘要

合成了一种新型聚合单体 1 甲基 4

5 二 (4 氯代苯甲酰基 )环己烯

并与 4 (3

5 二甲基 4 羟基苯基 ) 2

3 二氮杂萘 1 酮单体经亲核取代反应

成功地合成了含环己烯结构的杂环联苯型聚醚酮聚合物 .用FT IR、1H NMR、DSC、X 射线衍射等方法对聚合物进行了表征

并研究了聚合物的溶解性能 .结果表明

聚合物是一种具有较高的玻璃化温度的可溶性无规共聚物 .聚合物含有不饱和双键结构

是一种反应性高分子

Abstract

A novel bischloride monomer containing cyclohexene moieties [1-methyl-4

5-bis(chlorobenzoyl)cyclohexene] was successfully prepared.The compound is white plane crystally

b.p.126～127℃

it was studied by FT IR

1H NMR and MSD.Consequently a novel poly(aryl ether ketone)containing the of cyclohexene and phthalazinone moieties polymer was prepared by the nucelophilic displacement reaction of 1-methyl-4

5-bis(4-chlorobenzoyl)cyclohexene and-4-(3

5-dimethyl-4-hydroxyphenyl)-2

3-phthalazin-1-one.The polymer was studied by FT-IR

1H-NMR

DSC

X-ray diffraction.It has been proved that it was a amorphous polastics with high glass temperature (Tg=216.1℃).It was soluble in some solvents at room temperature.It was also intermediate product of cross-linked copolymer and grafted copolymer.

关键词

聚芳醚酮环己烯结构杂环聚合物反应性高分子合成

Keywords

references

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

SYNTHESIS AND CHARACTERIZATION OF POLY(ARYL ETHER)S CONTAINING CYCLOHEXENE AND PHTHALAZINONE MOIETIES

SYNTHESIS AND CHARACTERIZATION OF POLY(ETHER KETONE KETONE) CONTAINING THE PHTHALAZINONE MOIETY

SYNTHESIS AND CHARACTERIZATION OF A NOVEL EPOXY-TERMINATED POLY(ARYL ETHER KETONE)

SYNTHESIS AND CRYSTALLIZATION OF A NOVEL POLY (ETHER KETONE ETHER KETONE KETONE) CONTAINING META-PHENYLENE LINKAGE: PEKEKK(T/I)

SYNTHESIS AND CHARACTERIZATION OF PHOSPHORUS-CONTAINING LIQUID CRYSTALLINE COPOLYESTERS BASED ON BIPHENYL-4,4'-DICARBOXYLIC ACID

Related Author

No data

Related Institution

Center for Degradable and Flame-Retardant Polymeric Materials, College of Chemistry, State Key Laboratory of Polymer Materials Engineering, National Engineering Laboratory of Eco-Friendly Polymeric Materials Sichuan, Sichuan University

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰