STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP XII Synthesis and Photopolymerization of a Novel Functional Monomers-Np-acryloyl-N'-Phenylpiperazines and Its Uses as a Component of Redox Initiation

CHEN Shuang-ji; LI Fu-mian

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STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP XII Synthesis and Photopolymerization of a Novel Functional Monomers-Np-acryloyl-N'-Phenylpiperazines and Its Uses as a Component of Redox Initiation

Research Bulletin | 更新时间：2021-03-19

- STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP XII Synthesis and Photopolymerization of a Novel Functional Monomers-Np-acryloyl-N'-Phenylpiperazines and Its Uses as a Component of Redox Initiation
- Acta Polymerica Sinica Issue 4, Pages: 503-508(1989)
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- Published：20 August 1989，
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CHEN Shuang-ji, LI Fu-mian. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP XII Synthesis and Photopolymerization of a Novel Functional Monomers-Np-acryloyl-N'-Phenylpiperazines and Its Uses as a Component of Redox Initiation. [J]. Acta Polymerica Sinica (4):503-508(1989)
DOI：

CHEN Shuang-ji, LI Fu-mian. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP XII Synthesis and Photopolymerization of a Novel Functional Monomers-Np-acryloyl-N'-Phenylpiperazines and Its Uses as a Component of Redox Initiation. [J]. Acta Polymerica Sinica (4):503-508(1989) DOI：

摘要

Abstract

N-acryloyl-N'-phenylpiperazine (APP) and N-methacryloyl-N'-phenylpiperazine (MPP) were synthesized by the reaction of N-phenylpiperazine with corresponding acryloyl chlorides. The solution of these polymers display the fluorescence phenomenon

but these monomers do not. APP and MPP can be photopolymerized under the UV irradiation. The rate equation of MMA polymerization initiated by APP and BPO is given as RP = [APP]0.5 [BPO]0.5 [MMA] . The redox initiation system would be formed by the. combination of APP and BPO.APP not only initiates the polymerization of MMA

but also incorporates into the MMA polym-er chains.

关键词

含胺基功能性单体N-丙烯酰-N′-苯基哌嗪N-甲基丙烯酰-N′-苯基哌嗪荧光光聚合可聚合芳香叔胺

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