STUDY ON THE PREPARATION AND PORE STRUCTURES OF COPOLYMER OF TRIALLYL CYANURATE AND METHYL ACRYLATE

ZHANG Geng-yi; GUO Xian-quan; ZHANG Quan-xing; HE Bing-lin

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STUDY ON THE PREPARATION AND PORE STRUCTURES OF COPOLYMER OF TRIALLYL CYANURATE AND METHYL ACRYLATE

Research Article | 更新时间：2021-03-19

- STUDY ON THE PREPARATION AND PORE STRUCTURES OF COPOLYMER OF TRIALLYL CYANURATE AND METHYL ACRYLATE
- Acta Polymerica Sinica Issue 2, Pages: 208-213(1989)
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- Published：20 April 1989，
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ZHANG Geng-yi, GUO Xian-quan, ZHANG Quan-xing, HE Bing-lin. STUDY ON THE PREPARATION AND PORE STRUCTURES OF COPOLYMER OF TRIALLYL CYANURATE AND METHYL ACRYLATE. [J]. Acta Polymerica Sinica (2):208-213(1989)
DOI：

ZHANG Geng-yi, GUO Xian-quan, ZHANG Quan-xing, HE Bing-lin. STUDY ON THE PREPARATION AND PORE STRUCTURES OF COPOLYMER OF TRIALLYL CYANURATE AND METHYL ACRYLATE. [J]. Acta Polymerica Sinica (2):208-213(1989) DOI：

摘要

氰尿酸三烯丙酯(TAC)与丙烯酸甲酯(MA)在致孔剂如环己烷、正丁醚或甲苯-汽油(200~#)存在下

用悬浮聚合得到一系列大孔共聚物。对这些共聚物孔结构的研究表明

它们的平均孔径达10000—80000(?)

同时研完了致孔剂的分子结构和用量对共聚物孔结构的影响

并初步讨论特大孔共聚物形成的机理。

Abstract

Copolymer is prepared by the suspension copolymerization of triallyl cyanurate (TAC) and methyl acrylate (MA) in the presence of diluents such as cyclohexane

n-butyl ether

or toluene-gasoline (200#). The pore-structure parameters of the copolymer beads were determined. The study of pore structure shows that average pore radius is 10000-80000 A. The effects of molecular structure and amounts of the diluents on the pore structure of the beads were studied. The mechanism of forming super-macropore was disscued preliminarily.

关键词

氰尿酸三烯丙酯异氰尿酸三烯丙酯丙烯酸甲酯特大孔

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