STUDY ON UV-CURING POLY (αH, αH, ωH- PERFLUOROALKOXYPROPYLMETHYLSILOXANE)

ZHUO Ren-xi; FAN Chang-lie; LIU Zhen-hua; LOU Xia; FU Jie

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STUDY ON UV-CURING POLY (αH, αH, ωH- PERFLUOROALKOXYPROPYLMETHYLSILOXANE)

Research Article | 更新时间：2021-03-19

- STUDY ON UV-CURING POLY (αH, αH, ωH- PERFLUOROALKOXYPROPYLMETHYLSILOXANE)
- Acta Polymerica Sinica Issue 5, Pages: 368-374(1988)
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- Published：20 October 1988，
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ZHUO Ren-xi, FAN Chang-lie, LIU Zhen-hua, LOU Xia, FU Jie. STUDY ON UV-CURING POLY (αH, αH, ωH- PERFLUOROALKOXYPROPYLMETHYLSILOXANE). [J]. Acta Polymerica Sinica (5):368-374(1988)
DOI：

ZHUO Ren-xi, FAN Chang-lie, LIU Zhen-hua, LOU Xia, FU Jie. STUDY ON UV-CURING POLY (αH, αH, ωH- PERFLUOROALKOXYPROPYLMETHYLSILOXANE). [J]. Acta Polymerica Sinica (5):368-374(1988) DOI：

摘要

本文报道几种紫外光敏有机硅单体:(γ-甲基丙烯酰氧)丙基甲基二甲氧基硅烷

7-四(γ-甲基丙烯酰氧丙基)四甲基环四硅氧烷和1

3-双(甲基丙烯酰氧甲基)-1

3-四甲基二硅氧烷的合成

以及它们与αH

αH

ωH-全氟烷氧丙基甲基环四硅氧烷的开环共聚反应

制备了一系列新型光敏聚多氟烷氧丙基甲基硅氧烷.并初步研究了在紫外光辐照下

这类光敏聚多氟烷氧丙基甲基硅氧烷的化学结构对固化速度的影响.

Abstract

In this paper

wereport the preparation of three UV-sensitive organosilicon monomers

(Y-methacryloxy) propylmethyldimethoxyl-silane

3>5

7-tera(γ-methacryloxypropyl) terame-thylcyclotera-siloxane

and 1

3-di(methacryloy netyl)-1

3-tetramethyldisiloxane. By the co-polymerization of these monomers with αH

αH

ωH-perfluoroalkoxypropylmethylecyclotera-siloxanes

we synthesized a series of new UV-sensitive αH

αH

ωH-perfluoroalkoxypropyl-lysiloxanes

and studied the influence of the chemical structure of these polyorganosiloxanes on curing speed uuder UV radiation.

关键词

光敏聚硅氧烷紫外光固化氟烷基环硅氧烷甲基丙烯酸氧丙基环硅氧烷红烷基聚硅氧烷

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