CHENG Shu-yao, TIAN Bing-shou, YU Hui. AN EMP IRICAL METHOD OF CORRECTION IN THE EXPERIMENT OF GPC COUPLED WITH VISCOMETER. [J]. Acta Polymerica Sinica (5):325-330(1988)
DOI:
CHENG Shu-yao, TIAN Bing-shou, YU Hui. AN EMP IRICAL METHOD OF CORRECTION IN THE EXPERIMENT OF GPC COUPLED WITH VISCOMETER. [J]. Acta Polymerica Sinica (5):325-330(1988)DOI:
AN EMP IRICAL METHOD OF CORRECTION IN THE EXPERIMENT OF GPC COUPLED WITH VISCOMETER
A simple empirical correction method for the intrinsic viscosity in the experiment of GPC combined with viscometer has been presented in this paper. The values of [η] remain unchanged. It is only necessary to correct the values of corresponding elution volume Vi. For linear GPC columns
an empirical correction equation was proposed as follows:where tgθ is the slope of uncorrected straight line in a plot of log [η] vs V
Vi and Vi
corr are the uncorrected and corrected elution volume for count i respectively;Si+1 Si-1 and Si represent corresonding area in chromatogram for count i+1.i-1.and i.This correction method is tested and verified by the broad sample and standard sample of polystyrene as well as the unfractionated and the fractionated samples of poly (vinylchloride) and chlorinated polyethylene. The results are satisfactory.
THE ERROR ANALYSIS OF THE METHOD FOR ESTIMATION WEIGHT AVERAGE MOLECULAR WEIGHT OF POLYMER SAMPLE FROM THE INTRINSIC VISCOSITY AND GPC CHROMATOGRAM OF NORMAL DISTRIBUTION SHAPE
STUDY ON LONG CHAIN BRANCHING IN POLYBUTADIENES BY GPC COUPLED WITH CAPILARY VISCOMETER